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Temperature-induced structural changes in glassy, supercooled, and molten silica from 77 to 2150 K

Angelos G. Kalampounias、Spyros N. Yannopoulos、George Papatheodorou2005-12-30The Journal of Chemical Physics

In situ polarized and depolarized Raman spectra of glassy, supercooled, and molten SiO2 have been measured over the broad temperature range 77-2150 K in an effort to examine possible structural changes caused by temperature variation. A new experimental setup using a CO2 laser for heating the sample has been designed…

Material Dynamics and PropertiesGlass properties and applicationsMineralogy and Gemology Studies

Structure and Nanomechanical Characterization of Electrospun PS/Clay Nanocomposite Fibers

Yuan Ji、Bingquan Li、Shouren Ge 等 5 位作者2005-12-30Langmuir

Electrospinning has been emerging as one of the most efficient methods to fabricate polymer nanofibers. In this paper, PS/clay nanocomposite fibers with varying diameters were electrospun onto solid substrates. The fiber diameters were adjusted from 4 microm to 150 nm by changing the solution concentration. Scanning e…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Electric-field-induced nematic-cholesteric transition and three-dimensional director structures in homeotropic cells

Ivan I. Smalyukh、Bohdan Senyuk、Peter Palffy‐Muhoray 等 9 位作者2005-12-30Physical Review E

We study the phase diagram of director structures in cholesteric liquid crystals of negative dielectric anisotropy in homeotropic cells of thickness d which is smaller than the cholesteric pitch p. The basic control parameters are the frustration ratio d/p and the applied voltage U. Upon increasing U, the direct trans…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyOptical Polarization and Ellipsometry

A Tunable Anomalous Hall Effect in a Non-Ferromagnetic System

J. Cumings、L. S. Moore、H. T. Chou 等 7 位作者2005-12-30arXiv

We measure the low-field Hall resistivity of a magnetically-doped two-dimensional electron gas as a function of temperature and electrically-gated carrier density. Comparing these results with the carrier density extracted from Shubnikov-de Haas oscillations reveals an excess Hall resistivity that increases with decre…

Mesoscale and Nanoscale PhysicsMaterials Science

Two-dimensional tetramer-cuprate Na5RbCu4(AsO4)4Cl2: phase transitions and AFMorder as seen by 87Rb NMR

Raivo Stern、Ivo Heinmaa、Annika Kriisa 等 10 位作者2005-12-30arXiv

We report the Rb nuclear magnetic resonance (NMR) results in a recently synthesized Na5RbCu4(AsO4)Cl2. This complex novel two-dimensional (2D) cuprate is an unique magnetic material, which contains layers of coupled Cu4O4 tetramers. In zero applied magnetic field, it orders antiferromagnetically via a second-order low…

Materials ScienceStrongly Correlated Electrons

Polar phonons and intrinsic dielectric response of the ferromagnetic insulating spinelCdCr2S4from first principles

Craig J. Fennie、Karin M. Rabe2005-12-30Physical Review B

We have studied the dielectric properties of the ferromagnetic spinel $\mathrm{Cd}{\mathrm{Cr}}_{2}{\mathrm{S}}_{4}$ from first principles. Zone-center phonons and Born effective charges were calculated by frozen-phonon and Berry phase techniques within $\mathrm{LSDA}+U$. We find that all infrared-active phonons are q…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesAdvanced Condensed Matter Physics

Carbon 1s X-ray Photoemission Line Shape Analysis of Highly Oriented Pyrolytic Graphite: The Influence of Structural Damage on Peak Asymmetry

De‐Quan Yang、E. Sacher2005-12-30Langmuir

C 1s XPS spectra of various highly oriented pyrolytic graphite (HOPG) surfaces, untreated, as well as those treated by keV Ar+ beam bombardment and low-energy O2, N2, Ar, and H2O plasmas, have been systematically studied by comparing two XPS peak-fitting procedures. These procedures treat the spectrum as either (1) th…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Onsets of Tethered Chain Overcrowding and Highly Stretched Brush Regime via Crystalline−Amorphous Diblock Copolymers

Joseph X. Zheng、Huiming Xiong、William Y. Chen 等 10 位作者2005-12-30Macromolecules

Lamellar single crystals grown in dilute solutions can be used as templates for tethered chain analysis. Two series of diblock copolymers, poly(ethylene oxide)- block -polystyrene (PEO- b -PS) and poly( l -lactic acid)- block -polystyrene (PLLA- b -PS), were used as model templates to generate tethered PS blocks on th…

Polymer crystallization and propertiesPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Thermal conductance of metal-metal interfaces

Bryan C. Gundrum、David G. Cahill、R. S. Averback2005-12-30OpenAlex

The thermal conductance of interfaces between Al and Cu is measured in the temperature range $78<T<298\phantom{\rule{0.3em}{0ex}}\mathrm{K}$ using time-domain thermoreflectance. The samples are prepared by magnetron sputter deposition of a $100\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$ thick film of Al on top of la…

Thermal properties of materialsComposite Material MechanicsThermal Radiation and Cooling Technologies

Chiral 3D Architectures with Helical Channels Constructed from Polyoxometalate Clusters and Copper–Amino Acid Complexes

Haiyan An、Enbo Wang、Dong‐Rong Xiao 等 6 位作者2005-12-30OpenAlex

A twist to the right, or to the left: Both enantiomers of a new chiral material were synthesized by a rational approach, using enantiopure proline ligands, copper cations, and Keggin polyoxometalate anions as building blocks. The compounds have open-framework structures containing helical channels.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

A Polymer Composite Film with Reversible Responsive Behaviors

Xiaoying Lü、Juan Peng、Binyao Li 等 5 位作者2005-12-29Macromolecular Rapid Communications

Abstract Summary: A responsive polymer composite film was generated by the use of reversibly switchable surface morphology of polystyrene‐ block ‐poly(methyl methacrylate) (PS‐ b ‐PMMA) films in response to different block selective solvents on the rough isotactic poly(propylene) (i‐PP) substrate. The maximum differen…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsFluid Dynamics and Thin Films

Fabrication and characterization of surface‐conduction electron emitters for SED application

Keisuke Yamamoto、Takahiro Oguchi、K. R. A. Sasaki 等 6 位作者2005-12-29Journal of the Society for Information Display

Abstract— A surface‐conduction electron emitter (SCE) for next‐generation flat‐panel displays has been developed. PdO thin films (approximately 10 nm thick) produced by an ink‐jet process were used to form the surface‐conduction electron emitter. The films were electroformed and activated while a voltage was applied,…

Carbon Nanotubes in CompositesGraphene research and applicationsNanowire Synthesis and Applications

Effective ferromagnetic coupling between a superconductor and a ferromagnet inLaCaMnO∕Nbhybrids

Δ. Σταμόπουλος、N. Moutis、M. Pissas 等 4 位作者2005-12-29Physical Review B

In this work we present magnetization data on hybrids consisting of multilayers (MLs) of manganites ${[{\mathrm{La}}_{0.33}{\mathrm{Ca}}_{0.67}\mathrm{Mn}{\mathrm{O}}_{3}∕{\mathrm{La}}_{0.60}{\mathrm{Ca}}_{0.40}\mathrm{Mn}{\mathrm{O}}_{3}]}_{15}$ in contact with a low-${T}_{c}$ Nb superconductor (SC). Although a pure…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compounds

Orbital ordering in cubic LaMnO3from first principles calculations

Hand Zenia、G A Gehring、W. M. Temmerman2005-12-29New Journal of Physics

We report on first principles self-interaction corrected LSD (SIC-LSD) calculations of electronic structure of LaMnO 3 in the cubic phase. We found a strong tendency to localization of the Mn e g electron and to orbital ordering. We found the ground state to be orbitally ordered with a staggered order of x 2 − z 2 and…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Graft Polymerisation of Functional Acrylic Monomers onto Cotton Fibres Activated by Continuous Ar Plasma

Valter Castelvetro、Enrico Fatarella、Leopoldo Corsi 等 5 位作者2005-12-29Plasma Processes and Polymers

Abstract Summary: Continuous cold Ar plasmas were used to activate the mercerised cotton fabric towards surface‐initiated graft polymerisation of glycidyl methacrylate, 2‐hydroxyethyl methacrylate (HEMA) and 1,1,2,2‐tetrahydroperfluorodecyl methacrylate (XFDMA). Single and multi‐step processes, carried out either in t…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

A mode coupling theory description of the short- and long-time dynamics of nematogens in the isotropic phase

Jie Li、Hu Cang、Hans Christian Andersen 等 4 位作者2005-12-29The Journal of Chemical Physics

Optical heterodyne-detected optical Kerr effect (OHD-OKE) experimental data are pre-sented on nematogens 4-(trans-4-n-octylcyclohexyl)isothiocyanatobenzene (8-CHBT), and 4-(4-pentyl-cyclohexyl)-benzonitrile (5-PCH) in the isotropic phase. The 8-CHBT and 5-PCH data and previously published data on 4-pentyl-4-biphenylca…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation

SCF Theory of a Polymer Brush Immersed into a Multi‐Component Solvent

Victor M. Amoskov、T.M. Birshtein、Anna A. Mercurieva2005-12-29Macromolecular Theory and Simulations

Abstract Summary: Self‐consistent field (SCF) theory is developed for a polymer brush immersed into a multi‐component solvent. Thermodynamics of the plane inhomogeneous brush is mainly determined by thermodynamics of the basic system, i.e., a homogeneous solution of a polymer dissolved in a multi‐component solvent tha…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

Material Characterization of NiTi Based Memory Alloys Fabricated by the Laser Direct Metal Deposition Process

Kostyantyn Malukhin、Kornel F. Ehmann2005-12-29Journal of Manufacturing Science and Engineering

Shape memory alloys (SMAs) are used in a wide variety of applications including medical stents, couplings, actuators, jointless monolithic structures for actuation and manipulation, etc. Due to the SMA’s poor machinability it is advantageous to use rapid prototyping (RP) techniques for the manufacturing of SMA structu…

Shape Memory Alloy Transformations

Electrospinning of Hyaluronic Acid (HA) and HA/Gelatin Blends

Junxing Li、Aihua He、Charles C. Han 等 6 位作者2005-12-29Macromolecular Rapid Communications

Abstract Summary: In the present study, electrospinning of hyaluronic acid (HA) and hyaluronic acid/gelatin (HA‐GE) blends in N , N ‐dimethylformamide (DMF)/water‐mixed solvents have been investigated. When the volume ratio of DMF to water was in the range of 1.5–0.5, HA solutions could be electrospun into fibrous mem…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Coherence of Spin Qubits in Silicon

A. M. Tyryshkin、J. J. L. Morton、S. C. Benjamin 等 7 位作者2005-12-29arXiv

Given the effectiveness of semiconductor devices for classical computation one is naturally led to consider semiconductor systems for solid state quantum information processing. Semiconductors are particularly suitable where local control of electric fields and charge transport are required. Conventional semiconductor…

Mesoscale and Nanoscale PhysicsMaterials Science