Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe tetranuclear trianion [Fe4Te4(SC6H5)4]3-: crystal and molecular structure and magnetic propertiesPierluigi Barbaro, Alessandro Bencini, Ivano Bertini, Fabrizio Briganti, and Stefano MidolliniCite this: J. Am. Chem. Soc. 1990, 112, 20, 7238–7246Publication Date (Print):Se…
A new spectrometer design is presented in which the angular dispersion with respect to wave number is nearly constant. The spectrometer is a type of grism, a series combination of grating and prism, in which the constant parts of the dispersion terms add to one another but the slopes of the dispersions tend to cancel…
Abstract The preparation of green rusts from sulphate solutions and representative Mössbauer spectra are described. As the samples oxidized readily, attention focused on the Mössbauer parameters at liquid nitrogen and helium temperatures. The spectra recorded at 77 K could be fitted satisfactorily with one ferrous iro…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnetochemistry of the tetrahaloferrate(III) ions. 1. Crystal structure and magnetic ordering in bis[4-chloropyridinium tetrachloroferrate(III)]-4-chloropyridinium chloride and bis[4-bromopyridinium) tetrachloroferrate(III)]-4-bromopyridinium chlorideJalal A. Zora, K. R. Se…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTX-ray diffraction study of the electronic ground state of (meso-tetraphenylporphinato)iron(II)Naiyin Li, Zhengwei Su, Philip Coppens, and John LandrumCite this: J. Am. Chem. Soc. 1990, 112, 20, 7294–7298Publication Date (Print):September 1, 1990Publication History Published…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudies of the anionic polymerization of phenylvinylsulfoxide and its copolymer with styreneRustom S. Kanga, Thieo E. Hogen-Esch, E. Randrianalimanana, A. Soum, and M. FontanilleCite this: Macromolecules 1990, 23, 19, 4235–4240Publication Date (Print):September 1, 1990Public…
Activated carbon (AC) is an increasingly important electrode material for such applications as electrosorption, electrosynthesis, and electrical energy storage. An accurate description of the potential distribution within the electrode is essential to understanding the overall process behavior in all of these applicat…
Abstract The kinetics of clay formation in buried paleosols developed from late Quaternary rhyolitic tephra layers near Rotorua, New Zealand, can be described in terms of a combination of parabolic and linear kinetics, reflecting the hydration of glass, and the formation of clay minerals, respectively. Such a model is…
Strain softening, no matter how small, is usually accompanied by localization of the softening deformation field. Inside the zone of localization, a decrease in stress is accompanied by an increase in strain; outside the zone the strain decreases. One way to describe this phenomenon is to use a nonlocal theory of plas…
Fluxes of trivalent lanthanide ions across cellulose triacetate membranes were determined by using hinokitiol (HIPT) and flavonol (HFL) as carriers. The transport of the lanthanides was coupled to a flow of hydrogen ions. The effects of added anion and the pH in the source phase, and the plasticizer incorporated in th…
Chemical deposition of PbS from aqueous solutions has been studied using a reaction of PbS ( NO 3 ) 2 and CS ( NH 2 ) 2 with excess NaOH . The growth rate was measured as a function of temperature and concentrations of NaOH and CS ( NH 2 ) 2 using glass substrates. It is found that the incubation time depends on tempe…
Abstract 71 Ga and 27 Al NMR and clay mineral pillaring studies were used to investigate the hydrolysis of Al(H 2 O) –Ga(H 2 O) solutions, mixed in an Al:Ga mole ratio of 12:1, and confirmed the formation of the previously proposed GaO 4 Al 12 (OH) 24 (H 2 O) polyoxycation. This species has been found to be formed in…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, structure, and properties of a trinuclear and a mononuclear nickel(II) complex of N,N'-dimethyl-N,N'-bis(.beta.-mercaptoethyl)ethylenediamineMary A. Turner, Willem L. Driessen, and Jan ReedijkCite this: Inorg. Chem. 1990, 29, 18, 3331–3335Publication Date (Print):…
Manganese introduced in BaTiO3 as a substituant of titanium is able to trap the electrons produced during a sintering under a very low oxygen pressure. However it strongly modifies the vibrational and electronic properties of the pure compound. This paper is a short summary of the experimental results obtained by impe…
Raman spectroscopy has been used to monitor the changes induced in glassy carbon as a result of irradiation with H, He, C, N, Si, and Xe ions. The Raman spectrum of unirradiated glassy carbon consists of an intrinsic graphite peak at 1590 cm−1 (the a peak) and a disorder-induced D peak at 1350 cm−1. The G peak positio…
The hygroscopicity of theophylline anhydrate has been investigated by gas adsorption and hydration kinetic methods. Type 1 theophylline anhydrate was obtained by recystallization from distilled water at 95 degrees C, and type II was obtained by dehydration of theophylline monohydrate. The X-ray diffraction pattern of…
A new wet process was developed for preparing a V 2 O 5 thin film for use in an electrochromic display device. V 2 O 5 powder was dissolved into a mixed solution of benzyl alcohol and iso-butanol to obtain a vanadium solution, which was then spin-coated on an ITO glass followed by a heat treatment at temperatures abov…
The pressure-temperature phase diagram of the quasi-one-dimensional molecular superconductor TTF [Ni(dmit${)}_{2}$${]}_{2}$ has been carefully determined by ac resistivity measurements up to 14 kbar. Increasing pressures induce electronic phase transitions between a high-temperature metal and successive, metallic or s…
Films of copper oxide were readily deposited electrochemically on conductive surfaces from alkaline solutions containing copper (I, II) cyanide. The resulting electrodes showed catalytic activity for the anodic oxidation of CN − to CNO − in alkaline media. The half‐wave potential was p H dependent, indicating the invo…
Abstract The high‐temperature dispersions occurring in some poly (styrene‐co‐alkali methacrylate) ionomers are investigated by dynamic mechanical thermal analysis as a function of ion content. The heights and areas of the loss modulus peaks associated with these dispersions suggest that the ionic “cluster” phase becom…