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p-tert-Butylcalix[6]arene symmetrically tetrasubstituted with pyridine pendant groups: synthesis, x-ray crystal structure, and conformational analysis by dynamic NMR spectroscopy and molecular mechanics calculations

Placido Neri、Mario C. Foti、George B. Ferguson 等 9 位作者1992-09-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTp-tert-Butylcalix[6]arene symmetrically tetrasubstituted with pyridine pendant groups: synthesis, x-ray crystal structure, and conformational analysis by dynamic NMR spectroscopy and molecular mechanics calculationsPlacido Neri, Mario Foti, George Ferguson, John F. Gallagher…

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Photoinitiated crosslinking of low-density polyethylene. 6. Spin-trapping ESR studies on radical intermediates

Baojun Qu、Yunhua Xu、Wenfang Shi 等 4 位作者1992-09-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoinitiated crosslinking of low-density polyethylene. 6. Spin-trapping ESR studies on radical intermediatesBaojun Qu, Yunhua Xu, Wenfang Shi, and Bengt RaanbyCite this: Macromolecules 1992, 25, 20, 5215–5219Publication Date (Print):September 1, 1992Publication History Pub…

Conducting polymers and applicationsPhotochemistry and Electron Transfer StudiesElectrochemical Analysis and Applications

Synthesis and characterization of tantalum(V) dicarbollide complexes

Roger Uhrhammer、Donna J. Crowther、Jeffrey D. Olson 等 5 位作者1992-09-01Organometallics

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and characterization of tantalum(V) dicarbollide complexesRoger Uhrhammer, Donna J. Crowther, Jeffrey D. Olson, Dale C. Swenson, and Richard F. JordanCite this: Organometallics 1992, 11, 9, 3098–3104Publication Date (Print):September 1, 1992Publication History Publ…

Organometallic Complex Synthesis and CatalysisAdvanced Electron Microscopy Techniques and ApplicationsMachine Learning in Materials Science

XPS study of the interface reactions between buffer layers for HTSC thin films and silicon

H. Behner、J. Wecker、Th. Matthée 等 4 位作者1992-09-01Surface and Interface Analysis

Abstract In this work we have studied the interface reactions during e‐beam evaporation of yttria‐stabilized zirconia (YSZ), yttria (Y 2 O 3 ) and Y on Si(100) substrates by means of x‐ray photoelectron spectroscopy (XPS). A deposition process was developed for the heteroepitaxial growth of YSZ and Y 2 O 3 . A high am…

ZnO doping and propertiesElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides

Iron-alumina nanocomposites prepared by ball milling

M. Pardavi‐Horváth、L. Takács1992-09-01IEEE Transactions on Magnetics

Small magnetic particles of iron embedded in an insulating alumina matrix have been prepared by ball milling, either by direct milling of a mixture of iron and alumina powders or indirectly by ball-milling enhanced displacement reaction between magnetite and aluminum metal. The average particle size could be reduced t…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties of Alloys

Nd(Fe,Mo)/sub 12/N/sub x/ compounds and magnets

M. Endoh、Keisuke Nakamura、H. Mikami1992-09-01IEEE Transactions on Magnetics

The Mo-substituted Nd(Fe,Mo)/sub 12/N/sub x/ compounds are investigated. The ThMn/sub 12/ crystal structure has been obtained for the RFe/sub 11/Mo composition by optimizing the solution treatment temperature, and the magnetic properties of RFe/sub 11/MoN/sub x/ have been measured. The NdFe/sub 11/MoN/sub x/ shows lar…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Neuartige Polyethercopolymere mit einer linearen Zentraleinheit und dendritischen Endgruppen

Ivan Gitsov、Karen L. Wooley、Jean M. J. Fréchet1992-09-01Angewandte Chemie

Aus hifunktionellen Polyethylenglycolen und dendritischen aromatischen Polyethern 1 mit Bromsubstituenten am Zentrum des Makromoleküls entstehen in einer quantitativ verlaufenden Reaktion Blockcopolymere. Diese bilden in Lösungsmitteln, in denen sich beide Blöcke sehr schlecht oder sich ein Block selektiv gut löst, Mi…

Advanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Investigations of the crystallization of polyethylene by means of simultaneous small‐angle and wide‐angle X‐ray scattering

M. Bark、H. G. Zachmann、Rufina G. Alamo 等 4 位作者1992-09-01Die Makromolekulare Chemie

Abstract The isothermal crystallization of linear polyethylene fractions was studied by means of simultaneous measurements of wide‐angle X‐ray scattering (WAXS) and small‐angle X‐ray scattering (SAXS) employing synchrotron radiation. From WAXS the overall degree of crystallinity x c was determined. From SAXS, the scat…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Identification, cloning and sequence analysis of the poly(3-hydroxyalkanoic acid) synthase gene of the Gram-positive bacteriumRhodococcus ruber

Ursula Pieper、Alexander Steinbà ⁄ chel1992-09-01FEMS Microbiology Letters

The first polyhydroxy acid (PHA) synthase gene (phbCRr) of a Gram-positive bacterium was cloned from a genomic library of Rhodococcus ruber in the broad-host-range plasmid vector pRK404. The hybrid plasmid harboring phbCRr allowed the expression of polyhydroxybutyric acid (PHB) synthase activity and restored ability o…

biodegradable polymer synthesis and propertiesEnzyme Structure and FunctionBiopolymer Synthesis and Applications

Preparation and Ferroelectric Properties of SBN:50 Ceramics

Subhash B. Deshpande、H.S. Potdar、Prakash D. Godbole 等 4 位作者1992-09-01Journal of the American Ceramic Society

Stoichiometric quantities of AR‐grade chemicals, e.g., Ba(NO 3 ) 2 , Sr(NO 3 ) 2 , and Nb 2 O 5 , were used to synthesize Sr 0.5 Ba 0.5 Nb 2 O 6 (SBN:50) by the solid‐state reaction route. The reaction mixture was characterized by DTA/TG/DTG to locate the formation temperature of SBN:50. X‐ray diffrction was used to i…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Syntheses and multinuclear NMR characterizations of .alpha.-[SiMo2W9O39]8- and .alpha.-[SiMo3-xVxW9O40](4+x)- (x = 1, 2) heteropolyoxometalates

Emmanuel Cadot、René Thouvenot、André Tézé 等 4 位作者1992-09-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSyntheses and multinuclear NMR characterizations of .alpha.-[SiMo2W9O39]8- and .alpha.-[SiMo3-xVxW9O40](4+x)- (x = 1, 2) heteropolyoxometalatesEmmanuel Cadot, Rene Thouvenot, Andre Teze, and Gilbert HerveCite this: Inorg. Chem. 1992, 31, 20, 4128–4133Publication Date (Print)…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Structures, bonding, and absorption spectra of amine-sulfur dioxide charge-transfer complexes

Ming Wah Wong、Kenneth B. Wiberg1992-09-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructures, bonding, and absorption spectra of amine-sulfur dioxide charge-transfer complexesMing Wah Wong and Kenneth B. WibergCite this: J. Am. Chem. Soc. 1992, 114, 19, 7527–7535Publication Date (Print):September 1, 1992Publication History Published online1 May 2002Publis…

Photochemistry and Electron Transfer StudiesOrganic and Molecular Conductors ResearchOrganic Chemistry Cycloaddition Reactions

Continuity in Phase Transition Behavior between Normal and Diffuse Phase Transitions in Complex Perovskite Compounds

Makoto Kuwabara、Seiji Takahashi、Koji Goda 等 5 位作者1992-09-01Japanese Journal of Applied Physics

The phase transition behavior in the systems of (1- x )Pb(Mg 1/3 Nb 2/3 )O 3 - x PbTiO 3 (PMN-PT) and 0.99Pb 1- y La 2 y /3 TiO 3 -0.01MnO 2 (PLT) relaxor ferroelectrics has been investigated to explore the nature of diffused phase transitions (DPT) in these materials. All the dielectric constant (ε)-temperature ( T )…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

A construction principle of the κ‐phase based on the efficient (OH)donor…Oanion structural functionality: The examples of κ‐(EDT–TTF(CH2OH))2X (X = ClO and ReO)

Philippe Blanchard、K. Boubekeur、Marc Sallé 等 11 位作者1992-09-01Advanced Materials

The search for κ‐phases of conducting and superconducting organic cation radical salts is difficult because it is not yet known which characteristics of the donor molecule are required for this structure to be generated. The figure shown the hydroxy‐methyl‐functionalized non‐centroxymmetrical donor EDT‐TTF(CH 2 OH), w…

Magnetism in coordination complexesCrystallography and molecular interactionsOrganic and Molecular Conductors Research

Magnetic penetration depth of κ-(BEDT-TTF)2Cu[N(CN)2]Br, determined from the reversible magnetization

Michael Lang、N. Toyota、T. Sasaki 等 4 位作者1992-09-01Physical review. B, Condensed matter

We present results of the dc magnetization of single-crystalline \ensuremath{\kappa}-(BEDT-TTF${)}_{2}$Cu[N(CN${)}_{2}$]Br. From the slope of the linear M(lnH) dependence of the reversible magnetization, the magnetic penetration depth \ensuremath{\lambda}(T) is estimated. At low temperatures, \ensuremath{\lambda}(T) s…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Switching mechanism and domain structure of bistable amorphous wires

M. Vázquez、C. Gómez‐Polo、D.X. Chen1992-09-01IEEE Transactions on Magnetics

Hysteresis loops and domain structure of as-cast Fe-rich and stress-annealed low magnetostrictive Co-rich bistable wires have been investigated as functions of the distance to the end of wires with different lengths. From the analysis of the changes of the squareness ratio and differential susceptibility at remanence,…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

pH dependence of kinetic parameters of pepsin, rhizopuspepsin, and their active-site hydrogen bond mutants.

Yen‐Ting Lin、Martin Fusek、Xinli Lin 等 6 位作者1992-09-01Journal of Biological Chemistry

The pH dependence of the kinetic parameters of pepsin, rhizopuspepsin, and their active-site hydrogen bond mutants has been determined. These data have permitted the calculation of two active-site ionization constants in the free enzymes (pKe1 and pK32) and in the enzyme-substrate complexes (pKes1 and pKes2). The pKe1…

Protein Structure and DynamicsDNA and Nucleic Acid ChemistryEnzyme Structure and Function

Atom-based modeling of amorphous 1,4-cis-polybutadiene

Yong Li、Wayne L. Mattice1992-09-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAtom-based modeling of amorphous 1,4-cis-polybutadieneYong Li and Wayne L. MatticeCite this: Macromolecules 1992, 25, 19, 4942–4947Publication Date (Print):September 1, 1992Publication History Published online1 May 2002Published inissue 1 September 1992https://pubs.acs.org/d…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Gas phase interstitial modification of rare-earth intermetallics

J. M. D. Coey、R. Skomski、S. Wirth1992-09-01IEEE Transactions on Magnetics

The gas-phase interstitial modification of rare-earth intermetallics is studied. Net reaction energies for nitrogen in Sm/sub 2/Fe/sub 17/ and Nd(Fe/sub 11/Tl) are U/sub 0/=-57 kJ/mole and U/sub 0/=-51 kJ/mole, respectively. The equilibrium nitrogen concentration is calculated as function of temperature and gas pressu…

Rare-earth and actinide compoundsMagnetic Properties of AlloysMetallurgical and Alloy Processes

Dielectric Properties of Two-Phase Mixture Ceramics Composed of Rutile and Its Compounds

Kiyoshi Haga、Tsuyoshi Ishii、Jin-ichi Mashiyama Jin-ichi Mashiyama 等 4 位作者1992-09-01Japanese Journal of Applied Physics

Dielectric properties of two-phase mixture systems including rutile (TiO 2 ) have been investigated. One of its binary compounds-MnTiO 3 , ZnTiO 3 , PbTiO 3 and Al 2 TiO 5 -was chosen as the second component. Dielectric constants ε r and their temperature coefficients τ e were first examined at 1 MHz. Dielectric prope…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis