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Effect of Heteroatoms in Ordered Microporous Carbons on Their Electrochemical Capacitance

Hiroyuki Itoi、Hirotomo Nishihara、Takashi Kyotani2016-10-28Langmuir

Micropores play a more important role in enhancing the electrochemical capacitance than mesopores and macropores; therefore, the effect of heteroatom doping into micropores on the electrochemical behavior is interesting. However, heteroatom doping into porous carbon materials would potentially change their pore struct…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvancements in Battery Materials

Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior

Ronghuan Zhang、Mark S. Senn、Michael A. Hayward2016-10-28Chemistry of Materials

The cooperative tilting distortions of n = 2 Ruddlesden–Popper oxides can be utilized to break the inversion symmetry of the host lattice and induce ferroelectric behavior. Unfortunately the desired a – a – c + /a – a – c + structural deformation is only stabilized in phases with extremely small structural tolerance f…

Multiferroics and related materialsFerroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materials

Evaluation of gene expression cassettes and production of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) with a fine modulated monomer composition by using it in Cupriavidus necator

Hisashi Arikawa、Keiji Matsumoto2016-10-28Microbial Cell Factories

Cupriavidus necator has attracted much attention as a platform for the production of polyhydroxyalkanoate (PHA) and other useful materials. Therefore, an appropriate modulation of gene expression is needed for producing the desired materials effectively. However, there is insufficient information on the genetic engine…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCollagen: Extraction and Characterization

Functional carbon nanodots for multiscale imaging and therapy

Fatemeh Ostadhossein、Dipanjan Pan2016-10-28Wiley Interdisciplinary Reviews Nanomedicine and Nanobiotechnology

As an emerging class of carbon nanomaterials, carbon dots (CDs) have garnered many researchers' interests in the past decade due to their excellent biocompatibility, replete surface functional groups, water dispersibility, and unique photoluminescence. These extraordinary properties have opened new avenues for their a…

Carbon and Quantum Dots ApplicationsGraphene and Nanomaterials ApplicationsNanocluster Synthesis and Applications

Sequential Solvent Exchange Method for Controlled Exfoliation of MoS2 Suitable for Phototransistor Fabrication

Foad Ghasemi、S. Mohajerzadeh2016-10-28ACS Applied Materials & Interfaces

In this study, flakes of molybdenum disulfide (MoS 2 ) with controlled size and thickness are prepared through sequential solvent exchange method by sonication in dimethylformamide (DMF) and N -methyl-2-pyrrolidone (NMP) solvents. While NMP acts more effectively in reducing the thickness of flakes, DMF shows better po…

2D Materials and ApplicationsNanowire Synthesis and ApplicationsChalcogenide Semiconductor Thin Films

Temperature‐Controlled Switchable Photochromism in Solid Materials

Alex Julià‐López、Jordi Hernando、Daniel Ruiz‐Molina 等 6 位作者2016-10-28Angewandte Chemie International Edition

A novel strategy to achieve thermally switchable photochromism in solid materials is reported, which relies on the preparation of polymeric core-shell capsules containing solutions of photochromic dyes in acidic phase-change materials. Upon changing the phase (solid or liquid) of the encapsulated medium, one of the tw…

Photochromic and Fluorescence ChemistryPolydiacetylene-based materials and applicationsPhotoreceptor and optogenetics research

Tuning Size and Size Distribution of Colloidal InAs Nanocrystals via Continuous Supply of Prenucleation Clusters on Nanocrystal Seeds

Sudarsan Tamang、Sunghee Lee、Hyekyoung Choi 等 4 位作者2016-10-28Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTTuning Size and Size Distribution of Colloidal InAs Nanocrystals via Continuous Supply of Prenucleation Clusters on Nanocrystal SeedsSudarsan Tamang†‡, Sunghee Lee†, Hyekyoung Choi†§, and Sohee Jeong*†§View Author Information† Department of Nanomechatronics, Korea Inst…

Copper-based nanomaterials and applicationsChalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And Properties

Programming Colloidal Crystal Habit with Anisotropic Nanoparticle Building Blocks and DNA Bonds

Matthew N. O’Brien、Haixin Lin、Martin Girard 等 5 位作者2016-10-28Journal of the American Chemical Society

Colloidal crystallization can be programmed using building blocks consisting of a nanoparticle core and DNA bonds to form materials with controlled crystal symmetry, lattice parameters, stoichiometry, and dimensionality. Despite this diversity of colloidal crystal structures, only spherical nanoparticles crystallized…

Quantum Dots Synthesis And PropertiesGold and Silver Nanoparticles Synthesis and ApplicationsPickering emulsions and particle stabilization

Self-Affine Graphene Metasurfaces for Tunable Broadband Absorption

Pin Chieh Wu、Nikitas Papasimakis、Din Ping Tsai2016-10-28Physical Review Applied

Metasurfaces (metamaterials of near-vanishing thickness) are of interest for engineering subwavelength structures with complex responses. Typically a graphene metasurface exhibits just one or two resonances and absorbs light in a narrow frequency band, but this study demonstrates tunable broadband absorption due to hi…

Plasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface TechnologiesMetamaterials and Metasurfaces Applications

Finite-Element Analysis of Polyhedra under Point and Line Forces in Second-Strain Gradient Elasticity

Jörg Christian Reiher、Ivan Giorgio、Albrecht Bertram2016-10-28Journal of Engineering Mechanics

In this paper, a finite-element implementation of linear second-strain gradient elasticity is introduced based on a Hellinger-Reissner variational principle in order to use standard finite-element methods. Displacement boundary conditions are applied to one or more vertices of different polyhedrons. As a result, a smo…

Nonlocal and gradient elasticity in micro/nano structuresNumerical methods in engineeringComposite Structure Analysis and Optimization

Redox-Sensitive Cerium Oxide Nanoparticles Protect Human Keratinocytes from Oxidative Stress Induced by Glutathione Depletion

Ragini Singh、Ajay Karakoti、William T. Self 等 5 位作者2016-10-28Langmuir

Cerium oxide nanoparticles (CeNPs) have gathered much attention in the biomedical field due to its unique antioxidant property. It can protect cells and tissues from oxidative stress induced damage due to its autoregenerative redox cycle. Our study explores the antioxidant and antigenotoxic behavior of PEGylated CeNPs…

Sulfur Compounds in BiologyNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Antimicrobial Activity of Silver Nanoparticles in Polycaprolactone Nanofibers against Gram-Positive and Gram-Negative Bacteria

Juan López-Esparza、León Francisco Espinosa-Cristóbal、Alejandro Donohué-Cornejo 等 4 位作者2016-10-28Industrial & Engineering Chemistry Research

Drug-resistance infections have increased extremely quickly in the past years, emerging as a serious health problem in the world. Novel and better antimicrobial agents are still being developed to control associated microorganisms. However, this still represents a great challenge for antimicrobial agents. The aim of t…

Graphene and Nanomaterials ApplicationsElectrospun Nanofibers in Biomedical ApplicationsNanoparticles: synthesis and applications

Hard X-rays as pump and probe of atomic motion in oxide glasses

B. Ruta、F. Zontone、Y. Chushkin 等 8 位作者2016-10-28arXiv

Nowadays powerful X-ray sources like synchrotrons and free-electron lasers are considered as ultimate tools for probing microscopic properties in materials. However, the correct interpretation of such experiments requires a good understanding on how the beam affects the properties of the sample, knowledge that is curr…

Soft Condensed MatterMaterials Sciencecond-mat.dis-nn

Tunneling magnetoresistance in trilayer structures composed of group-IV-based ferromagnetic semiconductor Ge1− xFex, MgO, and Fe

Yuki K. Wakabayashi、Kohei Okamoto、Yoshisuke Ban 等 6 位作者2016-10-28Applied Physics Express

Abstract The group-IV-based ferromagnetic semiconductor Ge 1− x Fe x (GeFe) is one of the most promising materials for efficient spin injectors and detectors for Si and Ge. In this study, we show the first successful observation of the tunneling magnetoresistance (TMR) in magnetic tunnel junctions (MTJs) containing a…

Heusler alloys: electronic and magnetic propertiesQuantum and electron transport phenomenaMagnetic properties of thin films

Assessing exchange-correlation functional performance for structure and property predictions of oxyfluoride compounds from first principles

Nenian Charles、James M. Rondinelli2016-10-28arXiv

Motivated by the resurgence of electronic and optical property design in ordered fluoride and oxyfluoride compounds, we present a density functional theory (DFT) study on 19 materials with structures, ranging from simple to complex, and variable oxygen-to-fluorine ratios. We focus on understanding the accuracy of the…

Materials Science

Quantum electrodynamic approach to the conductivity of gapped graphene

G. L. Klimchitskaya、V. M. Mostepanenko2016-10-28arXiv

The electrical conductivity of graphene with a nonzero mass-gap parameter is investigated starting from the first principles of quantum electrodynamics in (2+1)-dimensional space-time at any temperature. The formalism of the polarization tensor defined over the entire plane of complex frequency is used. At zero temper…

Mesoscale and Nanoscale Physicsquant-phMaterials Science

Asymmetric pentagonal metal meshes for flexible transparent electrodes and heaters

Daniel Lordan、Micheal Burke、Mary Manning 等 8 位作者2016-10-28arXiv

Metal meshes have emerged as an important class of flexible transparent electrodes. We report on the characteristics of a new class of asymmetric meshes, tiled using a recently-discovered family of pentagons. Micron-scale meshes were fabricated on flexible polyethylene terephthalate substrates via optical lithography,…

Mesoscale and Nanoscale PhysicsMaterials Science

Heavy going

Christopher Mudry2016-10-28arXiv

Chiral symmetry breaking is imaged in graphene which, through a mechanism analogous to mass generation in quantum electrodynamics, could provide a means for making it semiconducting.

Materials Science

Effects of crystal anisotropy on optical phonon resonances in midinfrared second harmonic response of SiC

Alexander Paarmann、Ilya Razdolski、Sandy Gewinner 等 5 位作者2016-10-28Physical review. B./Physical review. B

We study the effects of crystal anisotropy on optical phonon resonances in the second harmonic generation (SHG) from silicon carbide (SiC) in its reststrahl region. By comparing experiments and simulations for isotropic 3C-SiC and anisotropic 4H-SiC in two crystal cuts, we identify several pronounced effects in the no…

Silicon Carbide Semiconductor TechnologiesSilicon Nanostructures and PhotoluminescenceThin-Film Transistor Technologies