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Promotive Effect of SO2 on the Activity of a Deactivated Commercial Selective Catalytic Reduction Catalyst: An in situ DRIFT Study

Yanke Yu、Jinxiu Wang、Jinsheng Chen 等 6 位作者2014-09-30Industrial & Engineering Chemistry Research

The deposition of K can lead to deactivation of commercial V 2 O 5 –WO 3 /TiO 2 selective catalytic reduction (SCR) catalyst while the presence of SO 2 largely increases the activity of K-poisoned catalyst. For revealing the mechanism of the SO 2 effect on the SCR reaction, the K-poisoned catalyst was prepared by impr…

Industrial Gas Emission ControlCatalysis and Oxidation ReactionsCatalytic Processes in Materials Science

Effects of Crystal Orientation on Cellulose Nanocrystals–Cellulose Acetate Nanocomposite Fibers Prepared by Dry Spinning

Si Chen、Greg Schueneman、R. Byron Pipes 等 5 位作者2014-09-30Biomacromolecules

This work presents the development of dry spun cellulose acetate (CA) fibers using cellulose nanocrystals (CNCs) as reinforcements. Increasing amounts of CNCs were dispersed into CA fibers in efforts to improve the tensile strength and elastic modulus of the fiber. A systematic characterization of dispersion of CNCs i…

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsNatural Fiber Reinforced Composites

Investigation of the anisotropic electron g factor as a probe of the electronic structure of GaBi$_{x}$As$_{1-x}$/GaAs epilayers

Christopher A. Broderick、Simone Mazzucato、Hélène Carrère 等 12 位作者2014-09-30arXiv

The electron Landé g factor ($g^{*}$) is investigated both experimentally and theoretically in a series of GaBi$_{x}$As$_{1-x}$/GaAs strained epitaxial layers, for bismuth compositions up to $x = 3.8$%. We measure $g^{*}$ via time-resolved photoluminescence spectroscopy, which we use to analyze the spin quantum beats…

Materials Science

Possible Existence of Partially Disordered Sm Ions in Magnetically Ordered State of Ising Magnet SmPt2Si2: a Single Crystal Study

Kengo Fushiya、Tatsuma D. Matsuda、Ryuji Higashinaka 等 5 位作者2014-09-30arXiv

We have succeeded in growing single crystals of SmPt2Si2 and have performed electrical resistivity, magnetization and specific heat measurements. The magnetic susceptibility shows that SmPt2Si2 is an Ising magnet with the crystalline-electric-field ground state of Jz=+-3/2. We have found the existence of two magnetica…

Materials ScienceStrongly Correlated Electrons

Quantitative Temperature Dependence of Longitudinal Spin Seebeck Effect at High Temperatures

Ken-ichi Uchida、Takashi Kikkawa、Asuka Miura 等 5 位作者2014-09-30arXiv

This article reports temperature-dependent measurements of longitudinal spin Seebeck effects (LSSEs) in Pt/Y$_3$Fe$_5$O$_{12}$ (YIG)/Pt systems in a high temperature range from room temperature to above the Curie temperature of YIG. The experimental results show that the magnitude of the LSSE voltage in the Pt/YIG/Pt…

Materials ScienceMesoscale and Nanoscale Physics

Novel Phase-Transition Materials Coupled with Switchable Dielectric, Magnetic, and Optical Properties: [(CH3)4P][FeCl4] and [(CH3)4P][FeBr4]

Ping‐Ping Shi、Qiong Ye、Qiang Li 等 7 位作者2014-09-30Chemistry of Materials

Two inorganic–organic hybrid compounds with zero-dimensional crystal structures, tetramethylphosphonium tetrachloroferrate(III) (compound 1, [(CH 3 ) 4 P][FeCl 4 ]) and tetramethylphosphonium tetrabromoferrate(III) (compound 2, [(CH 3 ) 4 P][FeBr 4 ]), are discovered as multifunctional materials exhibiting simultaneou…

Perovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyCrystal Structures and Properties

Effects of pharmaceutical PEGylation on drug metabolism and its clinical concerns

Xingwang Zhang、Feng Yang、Zhiguo Ma 等 4 位作者2014-09-30Expert Opinion on Drug Metabolism & Toxicology

INTRODUCTION: PEGylation refers to covalent conjugation of one or more polyethylene glycol chains to a drug molecule. It also refers to formulation of a drug into PEGylated drug-delivery vehicles in pharmacy. It is well-known that PEGylation can greatly influence the pharmacokinetics and pharmacodynamics of drugs. ARE…

Nanoparticle-Based Drug DeliveryCancer Research and TreatmentAdvanced Drug Delivery Systems

Smart conducting polymer composites having zero temperature coefficient of resistance

Kunmo Chu、Sung-Chul Lee、Sang-Eui Lee 等 6 位作者2014-09-30Nanoscale

Zero temperature coefficient of resistance (TCR) is essential for the precise control of temperature in heating element and sensor applications. Many studies have focused on developing zero-TCR systems with inorganic compounds; however, very few have dealt with developing zero-TCR systems with polymeric materials. Com…

Dielectric materials and actuatorsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Joule Heating Characteristics of Emulsion‐Templated Graphene Aerogels

Robert Menzel、Suelen Barg、Miriam Miranda 等 10 位作者2014-09-30Advanced Functional Materials

The Joule heating properties of an ultralight nanocarbon aerogel are investigated with a view to potential applications as energy‐efficient, local gas heater, and other systems. Thermally reduced graphene oxide (rGO) aerogels (10 mg cm −3 ) with defined shape are produced via emulsion‐templating. Relevant material pro…

Aerogels and thermal insulationGraphene research and applicationsSupercapacitor Materials and Fabrication

Ni-based nanoalloys: Towards thermally stable highly magnetic materials

Dennis Palagin、Jonathan P. K. Doye2014-09-30arXiv

Molecular dynamics simulations and density functional theory calculations have been used to demonstrate the possibility of preserving high spin states of the magnetic cores within Ni-based core-shell bimetallic nanoalloys over a wide range of temperatures. We show that, unlike the case of Ni-Al clusters, Ni-Ag cluster…

Materials Science

Efficient ab initio schemes for finding thermodynamically stable and metastable atomic structures: Benchmark of cascade genetic algorithms

Saswata Bhattacharya、Sergey V. Levchenko、Luca M. Ghiringhelli 等 4 位作者2014-09-30arXiv

A first-principles based methodology for efficiently and accurately finding thermodynamically stable and metastable atomic structures is introduced and benchmarked. The approach is demonstrated for gas-phase metal-oxide clusters in thermodynamic equilibrium with a reactive (oxygen) atmosphere at finite pressure and te…

Materials Science

Quantum phase transitions in the noncommutative Dirac Oscillator

O. Panella、P. Roy2014-09-30arXiv

We study the (2+1) dimensional Dirac oscillator in a homogeneous magnetic field in the non-commutative plane. It is shown that the effect of non-commutativity is twofold: $i$) momentum non commuting coordinates simply shift the critical value ($B_{\text{cr}}$) of the magnetic field at which the well known left-right c…

Materials Sciencehep-thquant-ph

Spin-phonon and magnetostriction phenomena in CaMn7O12 helimagnet probed by Raman spectroscopy

A. Nonatoa、B. A. Souza、A. P. Ayala 等 8 位作者2014-09-30arXiv

In this letter we investigated the temperature-dependent Raman spectra of CaMn7O12 helimagnet from room temperature down to 10 K. The temperature dependence of the Raman mode parameters show remarkable anomalies for both antiferromagnetic and incommensurate transitions that this compound undergoes at low temperatures.…

Materials Science

Some formulae for evaluation of the polariton and plasmon frequencies, in materials

Voicu Dolocan、Andrei Dolocan、Voicu Octavian Dolocan2014-09-30arXiv

We present new relations for calculation of phonon polaritons, plasmons and plasmon polaritons frequencies, which differ from the standard relations. So, we study the frequency of phonon polaritons in a two dimensional lattice with applications to CuO2 lattice. Next, we evaluate plasmon frequencies in graphene and in…

Mesoscale and Nanoscale PhysicsMaterials Science

Cation Substitution Dependent Bimodal Photoluminescence in Whitlockite Structural Ca3–xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) Solid Solution Phosphors

Haipeng Ji、Zhaohui Huang、Zhiguo Xia 等 6 位作者2014-09-30Inorganic Chemistry

Cation substitution dependent tunable bimodal photoluminescence behavior was observed in the Ca3-xSrx(PO4)2:Eu(2+) (0 ≤ x ≤ 2) solid solution phosphors. The Rietveld refinements verified the phase purity and whitlockite type crystal structure of the solid solutions. The tunable photoluminescence evolution was studied…

Luminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics SynthesisAdvanced Photocatalysis Techniques

Wafer Scale Synthesis and High Resolution Structural Characterization of Atomically Thin MoS2 Layers

Aaron George、Zafer Mutlu、Robert Ionescu 等 10 位作者2014-09-30Advanced Functional Materials

Synthesis of atomically thin MoS 2 layers and its derivatives with large‐area uniformity is an essential step to exploit the advanced properties of MoS 2 for their possible applications in electronic and optoelectronic devices. In this work, a facile method is reported for the continuous synthesis of atomically thin M…

MXene and MAX Phase MaterialsChalcogenide Semiconductor Thin Films2D Materials and Applications

Color-Tunable Mirrors Based on Electrically Regulated Bandwidth Broadening in Polymer-Stabilized Cholesteric Liquid Crystals

Kyung Min Lee、Vincent P. Tondiglia、Michael E. McConney 等 6 位作者2014-09-30ACS Photonics

We report on the preparation of color-tunable mirrors based on electrically regulated bandwidth broadening of the circularly polarized reflection of polymer-stabilized cholesteric liquid crystals (PSCLCs). A number of improvements relating to the practical implementation of these materials are detailed including color…

Optical Polarization and EllipsometryPhotonic and Optical DevicesLiquid Crystal Research Advancements

Quasi-Freestanding Monolayer Heterostructure of Graphene and Hexagonal Boron Nitride on Ir(111) with a Zigzag Boundary

Mengxi Liu、Yuanchang Li、Pengcheng Chen 等 13 位作者2014-09-30Nano Letters

In-plane heterostructure of hexagonal boron nitride and graphene (h-BN-G) has become a focus of graphene research owing to its tunable bandgap and intriguing properties. We report herein the synthesis of a quasi-freestanding h-BN-G monolayer heterostructure on a weakly coupled Ir(111) substrate, where graphene and h-B…

Graphene research and applicationsSurface and Thin Film PhenomenaQuantum and electron transport phenomena

Optically Modulated Multiband Terahertz Perfect Absorber

Hüseyin R. Seren、George R. Keiser、Lingyue Cao 等 10 位作者2014-09-30Advanced Optical Materials

Development of tunable, dynamic, and broad bandwidth metamaterial designs is a keystone objective for metamaterials research, necessary for the future viability of metamaterial optics and devices across the electromagnetic spectrum. Yet, overcoming the inherently localized, narrow bandwidth, and static response of res…

Terahertz technology and applicationsPlasmonic and Surface Plasmon ResearchMetamaterials and Metasurfaces Applications

Beating the Abbe Diffraction Limit in Confocal Microscopy via Nonclassical Photon Statistics

D. Gatto Monticone、K. G. Katamadze、P. Traina 等 10 位作者2014-09-30Physical Review Letters

We experimentally demonstrate quantum enhanced resolution in confocal fluorescence microscopy exploiting the nonclassical photon statistics of single nitrogen-vacancy color centers in diamond. By developing a general model of superresolution based on the direct sampling of the kth-order autocorrelation function of the…

Diamond and Carbon-based Materials ResearchMechanical and Optical ResonatorsForce Microscopy Techniques and Applications