Materials Literature
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Ectoine is a compatible solute and chemical chaperone widely used by members of the Bacteria and a few Archaea to fend-off the detrimental effects of high external osmolarity on cellular physiology and growth. Ectoine synthase (EctC) catalyzes the last step in ectoine production and mediates the ring closure of the su…
3D interconnected carbon nanotubes (CNTs) are synthesized using an industrially scalable spark plasma technique. At high electric field and elevated temperature under sufficient stress the nanotubes are welded together to form a solid block. The detailed spectroscopic and microscopic analyses show successful welding o…
Low-temperature specific heat has been measured in FeS superconductor with the transition temperature of 4.55 K. It is found that the low-temperature electronic specific heat ${C}_{e}/T$ can be fitted to a linear relation in the low-temperature region, but fails to be described by an exponential relation as expected b…
Energy transport in organic materials is dependent on the coherent migration of optically induced excited states. For instance, in active organic waveguides, the tight packing of dye molecules allows delocalization of excitons over a distance generally limited to at most several hundred nanometers. Here, we demonstrat…
Abstract A cationic iron(III) complex was active for the polymerization of various epoxides, whereas the analogous neutral iron(II) complex was inactive. Cyclohexene oxide polymerization could be “switched off” upon in situ reduction of the iron(III) catalyst and “switched on” upon in situ oxidation, which is orthogon…
We synthesized cuprous oxide (Cu 2 O) nanoparticles (NPs) with an average crystallite size of 8.8 nm in presence of Arka ( Calotropis gigantea ) leaves extract. The photo-bleaching activity of Cu 2 O NPs on the aqueous methylene blue (MB) dye was studied by illumination of visible light. In the absorption spectra, a d…
Magnetic nanoparticles (MNPs) can play a distinct role in magnetic drug delivery via their distribution to the targeted area. The preparation of such MNPs is a challenging multiplex task that requires the optimization of size, magnetic, and surface properties for the achievement of desirable target selectivity, along…
We prepared composites of a liquid crystalline material, 4-pentylphenyl 4-octyloxybenzoate (4PP4OB) and cadmium selenide quantum dots (CdSe-QDs) and investigated their thermodynamic, electro-optical and dielectric properties. The effect of QDs on transition temperature from isotropic to nematic and nematic to smectic…
We describe a microscope-based optical setup that allows us to perform space- and time-resolved measurements of the spectral reflectance of transparent substrates coated with ultrathin films. This technique is applied to investigate the behavior in water of thermosensitive polymer brushes made of poly(N-isopropylacryl…
Covalent organic frameworks (COFs), based on melamine and dibromoalkanes [Br(CH 2 ) n Br] with n = 2, 4, 6, and 8 for 1,2-dibromoethane, 1,4-dibromobutane, 1,6-bibromohexane and 1,8-dibromooctane as COF-1,2, COF-1,4, COF-1,6, COF-1,8, were synthesized in dimethyl sulfoxide at 150 °C. The COFs had distinct color depend…
Application of tissue-engineered vascular grafts (TEVGs) for the replacement of small-diameter arteries is limited due to thrombosis and intimal hyperplasia. Previous studies have attempted to address the limitations of TEVGs by developing scaffolds that mimic the composition (collagen and elastin) of native arteries…
The interaction between two porphyrin macrocycles, connected covalently through either a rigid ethylene or a flexible ethane bridge, in the metalloporphyrin dimers (M: 2H, Zn(2+)) have been investigated upon stepwise oxidations. Upon 1e-oxidation, two porphyrin macrocycles come closer and cofacial to each other while…
Phoenix sp. fiber-reinforced epoxy composites have been manufactured using compression molding technique. The effect of reinforcement volume content (0%, 10%, 20%, 30%, 40%, and 50%) and size (300 µm particles, 10 mm, 20 mm, and 30 mm fibers) on quasi-static and dynamic mechanical properties was investigated. Moreover…
Crystallization of colloids has extensively been studied for past few decades as models to study phase transition in general. Recently, complex crystal structures in multi-component colloids, including alloy and eutectic structures, have attracted considerable attention. However, the fabrication of 2D area-filling col…
Surface acoustic wave (SAW) devices have been utilized for the sensing of chemical and biological phenomena in microscale for the past few decades. In this study, SAW device was fabricated by electrospinning poly(vinylidenefluoride-co-trifluoroethylene) (P(VDF-TrFE)) incorporated with zinc oxide (ZnO) nanoparticles ov…
Flow-induced shish formation in semicrystalline polymers is an important phenomenon since shish can strongly influence final material properties. The formation, dissolution, and re-emergence of flow-induced shish were studied for a polyethylene system with a broad molecular weight distribution using time-resolved sync…
Nitric acid (HNO3)-treated carbon fiber (CF) rich in hydrophilic groups was applied as a cell-immobilized carrier for xylitol fermentation. Using scanning electron microscopy, we characterized the morphology of the HNO3-treated CF. Additionally, we evaluated the immobilized efficiency (IE) of Candida tropicalis and xy…
Abstract The structure–property correlations of silver nanoclusters (NCs) have rarely been studied, owing to the lack of appropriate materials and the instability of silver NCs. Herein, we show that substituting the central atom of the Ag 25 (SR) 18 NC with another metal atom (i.e. Pd, Pt, or Au) can influence the opt…
We report a facile strategy to grow supramolecular copolymers on Au surfaces by successively exposing a surface-anchored monomer to solutions of oppositely charged peptide comonomers. Charge regulation on the active chain end of the polymer sufficiently slows down the kinetics of the self-assembly process to produce k…
Interest in the synthesis of hybrid substrates for surface‐enhanced Raman scattering (SERS) has surged recently. Hereof, in the present work, a hybrid SERS substrate CuO : Mn/Ag heterojunction has been synthesised. To accomplish this, the nanostructred Ag island film and CuO : Mn nanoparticles are synthesised by vacuu…