Materials Literature
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A study of the core-electron X-ray photoelectron (X-p.e.) spectra of the f0 compounds La2O3, LaMO3(M = Fe and Co), CeO2, and BaCeO3 is described. Results on the chelate species [La(tmhd)3] and [Ce(tmhd)4](tmhd = 2,2,6,6-tetramethylheptane-3,5-dionato) are included for comparison. Special precautions have been taken to…
An equation derived by Ritland relating the cooling rate and fictive temperature for glasses without memory is extended to those with memory, i.e. those which exhibit a spectrum of relaxation times. Provided that the spectrum of relaxation times is temperature‐independent, the limiting fictive temperature, T′ f , obta…
Expressions are presented for the moisture distribution and the mois ture content as a function of time of one dimensional homogeneous and composite materials exposed either on one side or on both sides to humid air or to water. The results apply during both moisture absorption and desorption when the moisture content…
The review is devoted to the properties of 7,7,8,8-tetracyanoquinodimethane, one of the strongest of the known organic π acids. Data concerning the methods of synthesis of 7,7,8,8-tetracyanoquinodimethane and its analogues and the physicochemical properties of compounds of this series are surveyed. The addition, subst…
We have deduced from measurements of the neutron elastic cross section that below the N\'eel temperature (${T}_{\mathrm{N}}$) the oxygen atoms in U${\mathrm{O}}_{2}$ are shifted from their ideal fluorite positions. We find quantitative agreement with experiment by assuming a rearrangement (internal shear deformation w…
On the basis of an analysis of data on a large number of compounds exhibiting displacive phase transitions, it is observed (with no known exceptions) that the transition temperature decreases with hydrostatic pressure for those transitions associated with soft zone-center optic phonons and increases for those transiti…
Reflectivity spectra from the basal planes of crystals of 2H-NbSe 2 , 2H-TaSe 2 , 2H-TaS 2 and 1T-TaS 2 have been measured in the energy range 25 meV to 14 eV at room temperature and liquid nitrogen temperature. Using extrapolations of the experimental data to 0 eV and 30 eV, a Kramers-Kronig analysis of the data has…
The velocity of longitudinal and transverse ultrasonic waves has been measured for an Fe50.5Rh49.5 alloy on both sides of the antiferromagnetic-ferromagnetic transition. From these measurements the variation of Young's modulus, shear modulus, and Poisson's ratio with temperature and magnetic field has been calculated.…
The deformation behaviour of tantalum-rhenium, tantalum-niobium, electronbeam melted tantalum, and ultra high vacuum annealed tantalum is studied at temperatures 77 to 293 K. The slip geometry, morphology, and yield stress is determined as function of orientation, temperature, and mode of deformation. Alloying is obse…
Germanium was reacted with N2O, O2, NO2, and NO in a flow system, which produced GeO. Chemiluminescence was observed from three electronic band systems of GeO: A 1Π→X 1Σ+ in the uv, a 3Σ+→X 1Σ+ in the blue, and b 3Π1→X 1Σ+ (a previously unreported system) in the near uv. Vibrational constants and Te values have been o…
The structure of the paraelectric phase of RbHSO 4 has been determined by X-ray and neutron diffraction at T = 23 °C. The structure consists of two crystallographically independent molecules in the asymmetric unit. Each of the independent sulphate tetrahedra is linked to a translationally equivalent sulphate by acentr…
The chemisorption of atomic hydrogen on the silicon (111) 7 \ifmmode\times\else\texttimes\fi{} 7 surface has been studied using ionneutralization spectroscopy and ultraviolet-photoemission spectroscopy with the help of low-energy electron diffraction and work-function measurement. Both spectroscopies showed that the d…
ZnS diodes emitting a stable and bright blue light with forward biases above 5 V are investigated. The external quantum efficiency for the diode is as high as 5×10−4 at room temperature. The presence of a thin high-resistivity ZnS layer on the low-resistivity ZnS is essential for the present diode. The fairly high eff…
A simple statistical model for coalescence of islands in discontinuous films is formulated. It predicts log-normal size distributions, which appears to be well corroborated by experiments.
We report neutron-scattering measurements on highly supercooled liquid gallium droplets showing a vanishing quasi-elastic frequency width as the temperature is reduced. The width tends towards zero at a temperature within 1 standard deviation of the value ${T}_{L}=150\ifmmode\pm\else\textpm\fi{}1$ K at which gallium i…
The resonance excitation of surface plasmons, detected by the scattered-light method, is used in a number of experiments on Ag, Au, and Cu films. These include (i) the determination of optical constants, (ii) the use of a multilayered structure allowing sequential excitation of plasmons on both surfaces of a film, (ii…
X-ray photoelectron spectra of colored WO3 films, thermodynamic analysis of galvanic behavior of the tungstic oxide cathode, plus other new lines of evidence, clearly establish the previously uncertain mechanism of the electro-optic effect in amorphous WO3, viz., a simultaneous injection of electrons and positive ions…
The extensional velocity and internal friction are measured in a series of partially melted alloys having different volume fractions of fluid and different dihedral angles. The acoustic properties change discontinuously when melt forms: the velocity decreases while Q−1 usually, but not invariably, increases. The prese…
A significant proportion of the soluble protein of the organic matrix of mollusk shells is composed of a repeating sequence of aspartic acid separated by either glycine or serine. This regularly spaced, negatively charged aspartic acid may function as a template upon which mineralization occurs.
An application of Willis's anharmonic theory has been made to improve the earlier calculations of the Debye-Waller factors of (X-iron and sodium reported in Part I, and to estimate the effect of including anharmonic. terms in the crystal potential. The calculations have been compared with the existing experimental dat…