Materials Literature
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Abstract Certain mixtures of TFE/CHCl 3 were found to be excellent solvents for aliphatic polyamides such as nylon‐6, nylon‐66, nylon‐11, nylon‐12, nylon‐69, nylon‐610, and nylon‐612. Intrinsic viscosities were measured and Mark–Houwink coefficients determined for nylon‐6/TFE/CHCl 3 , indicating TFE‐rich mixtures to b…
Results are presented which show that for environment-sensitive cracking the changes in environment composition or potential that may occur in pits, crevices, or cracks are probably as important as the stress concentration associated with such discontinuities. However, with some solutions, especially those in which th…
Computer simulation techniques based on generalized Mott-Littleton methods have been used to investigate defect structures in systems resulting from the incorporation of Mn2 +, Cd2+ and Pb2+ ions into NaCl, KC1 and KBr crystals. Two-body interionic potentials based on the simple shell model were used in the calculatio…
Abstract Recent developments in the phenomenon of growth rate dispersion are surveyed with a particular emphasis on its characterisation. Most of the characterisation work concerning growth rate dispersion has been carried out under negligible nucleation conditions in batch configurations. Analytical solutions to the…
The DREF-3 spinning method produces a yarn by wrapping a fibrous core with a fibrous sheath at production speeds up to 200 meters per minute. The comparative merits of this high-production spinning method to spin all-cotton yarns are inves tigated and reported. Two sets of cotton differing mainly in fiber length, stre…
Auxospore formation by a littoral marine diatom, identified as Navicula ulvacea, was followed by the production of vegetative cells which on the basis of valve morphology would be placed in a different species, N. subinflatoides. As circumstantial evidence indicated that paedogamy was occurring, which would exclude th…
Previous solid state analyses of sintering in Ti 4+ ‐doped‐commercial alumina are shown to be in error because a liquid phase exists in the appropriate region of the Al 2 O 3 −TiO 3 −Na 2 Ophase diagram at least by 1350 ° C, a temperature lower than that at which “solid state” studies were conducted. It is suggested t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDissolution of poly(tetrafluoroethylene)Paul Smith and K. H. GardnerCite this: Macromolecules 1985, 18, 6, 1222–1228Publication Date (Print):June 1, 1985Publication History Published online1 May 2002Published inissue 1 June 1985https://pubs.acs.org/doi/10.1021/ma00148a031htt…
Abstract not Available.
Temperature dependences of birefringence and optical activity in KLiSO4 are studied and used for analysis of symmetries of the phases in temperature region 150-300 K. Monoclinic (class 2) and triclinic (class 1) symmetries were found for phases IV and V. Kinetics of the phase transitions is discussed
Resolution aux RX de la structure du sulfate de cuivre Pentahydrate: M r =249,68 triclinique, P1, a=6,1224, b=10,7223, c=5,9681 A, α=82,35, β=107,33, γ=102,60, V=364,02(3) A 3 , Z=2, D x =2,278 Mg m −3 , M 0 Kα, λ=0,71069 A, μ=3,419 mm −1 , F(000)=254,0, T=298 K, R=0,039 pour 7667 reflexions. Les parametres structurau…
Abstract Die Darstellung der Verbindungen InGaSe 2 und InGaTe 2 wird beschrieben. Röntgenographische Strukturuntersuchungen an den schwarzen, metallisch glänzenden Einkristallen bei verschiedenen Temperaturen zeigen, daß beide Verbindungen im TlSe‐Typ kristallisieren (InGaSe 2 : a = 805,1(1) pm, c = 631,7(4) pm; InGaT…
Conventional and new techniques for making high-frequency B versus H loop and core-loss measurements on magnetic cores are presented and compared. Potential sources of measurement errors and their magnitudes are discussed along with circuits suitable for high-frequency sine-wave or square-wave core excitation. The uti…
Abstract Enhancement factor calculations based on the electromagnetic model of surface‐enhanced Raman scattering (SERS) are presented for a series of metals. The specific dependence of SERS on the excitation and vibrational frequencies, and the aspectratio of spheroidal particles, are discussed. It is suggested that t…
The singlet–triplet splitting (2J=EST) is calculated in bis-[bromo-(N,N-diethylaminoethanolato)copper(II)], belonging to the group of alkoxo-bridged copper(II) dimers, by a recently proposed ab initio method. The singlet–triplet splitting energy is obtained by a perturbation expansion closely related to Anderson’s for…
Gamma-ray exposure buildup factors are calculated using a discrete ordinates direct integration code, PALLAS-PL, SP-Br, for water, concrete, iron, and lead for point isotropic sources. These data include the effects of secondary photon sources arising from Compton scattering, bremsstrahlung, and annihilation. Comparis…
We have made a systematic theoretical survey of the competition between ferroelastic and ferroelectric instabilities in the family of halide-based perovskites of formula ${\mathrm{ABX}}_{3}$, where A is an alkali-metal ion, B is a Be, Mg, or Ca ion, and X is a halide ion. Initially we surveyed the whole series of such…
Abstract Atomic ratio determinations in a series of pure inorganic compounds have been derived from XPS peak intensity measurements taken by area via the so‐called ‘first principles model’ (FPM) and the ‘elemental sensitivity factors’ (ESF) methods. The two methods show similar degrees of accuracy, with a typical erro…
Steps corresponding to (110), (211), (310), (222), and (321) facets in monocrystals of blue phase I (BP I) are described. We show that close to equilibrium, surfaces of BP I monocrystals contain facets and rounded parts on which a series of steps can be distinguished. During growth, the round parts are eliminated and…
Optical studies of LiKSO4 crystals were performed in polarized 11yh.t within the temperature range from 300 up to 1000 K. The observations confirmed the existence of two phase transitions at about 700 and 940 K respectively. The high-temperature phase between 700 and 940 K was found to be ferroelastic.