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Directed placement of suspended carbon nanotubes for nanometer-scale assembly

Larry A. Nagahara、Islamshah Amlani、Justin Lewenstein 等 4 位作者2002-05-20Applied Physics Letters

Single-wall carbon nanotubes (SWNTs) suspended in an aqueous solution have been placed selectively between two metal electrodes separated by a few tens of nanometers. After the initial patterning of the metal electrodes by electron beam lithography, no further fine-line lithography steps are necessary to achieve direc…

Electrochemical Analysis and ApplicationsCarbon Nanotubes in CompositesNanopore and Nanochannel Transport Studies

On the determination of the molecular static first hyperpolarisability: how reliable are literature data?

Santo Di Bella2002-05-20New Journal of Chemistry

The shortcomings of the two-level model in extrapolating the molecular static first hyperpolarisability, β0, are discussed in the context of literature data. However, except for some spurious β0 data, in many other cases, the reported β0 values can be considered reasonably reliable due to a balancing of effects.

Solid-state spectroscopy and crystallographyNonlinear Optical Materials ResearchChemical synthesis and pharmacological studies

On-chip vacuum microtriode using carbon nanotube field emitters

Christopher A. Bower、Wei Zhu、D. Shalom 等 7 位作者2002-05-20Applied Physics Letters

We show a fully integrated, on-chip, vacuum microtriode fabricated via silicon micromachining processes using carbon nanotubes as field emitters. The triode is constructed laterally on a silicon surface using microelectromechanical systems (MEMS) design and fabrication principles. The technique incorporates high-perfo…

Advanced MEMS and NEMS TechnologiesCarbon Nanotubes in CompositesMechanical and Optical Resonators

Room-temperature homogeneous nucleation synthesis and thermal stability of nanometer single crystal CeO2

Xueyun Zhou、W. Huebner、Harlan U. Anderson2002-05-20Applied Physics Letters

Nanometer (about 4∼5 nm) CeO2 single crystals were first synthesized by room-temperature homogeneous nucleation; the size was determined by electron microscopy and specific surfaced area of the particles. Modeling revealed that the surface energy of as-synthesized nanometer single crystals was in the range of 2.8–3.7…

nanoparticles nucleation surface interactionsCatalysis and Oxidation ReactionsCatalytic Processes in Materials Science

Molecular precursors for (nano) materials — a one step strategy

Michael Veith2002-05-20Journal of the Chemical Society Dalton Transactions

The use of molecular Single Source Precursors (SSP) containing all elements necessary for the formation of the final solid material in CVD (Chemical Vapor Deposition) or sol–gel routes is classified with respect to the control of the reaction. Three different cases have been distinguished: In SSP-I the stoichiometric…

Mesoporous Materials and CatalysisCatalytic Processes in Materials ScienceCopper-based nanomaterials and applications

Electrodeposition of patterned CdSe nanocrystal films using thermally charged nanocrystals

Mohammad A. Islam、Irving P. Herman2002-05-20Applied Physics Letters

A dc electric field is used to attract charged CdSe nanocrystals in hexane to rapidly form very smooth, robust, large-area, several micron-thick films of equal thickness on both electrodes. This deposition on both electrodes implies there are both positively and negatively thermally charged dots, unlike conventional e…

Electrophoretic Deposition in Materials ScienceQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Driving Forces and Boundary Conditions in Continuum Dislocation Mechanics

Amit Acharya2002-05-20arXiv

As a guide to constitutive specification, driving forces for dislocation velocity and nucleation rates are derived for a field theory of dislocation mechanics. A condition of closure for the theory in the form of a boundary condition for dislocation density is also derived. Kinematical features of dislocation evolutio…

Materials Science

Transport critical current of Solenoidal MgB2/Cu Coils Fabricated Using a Wind-Reaction In-situ Technique

S. Soltanian、J. Horvat、X. L. Wang 等 5 位作者2002-05-20arXiv

In this letter, we report the results of transport Jc of solenoid coils upto 100 turns fabricated with Cu-sheathed MgB2 wires using a wind-reaction in-situ technique. Despite the low density of single core and some reaction between Mg and Cu-sheath, our results demonstrate the decrease in transport Jc with increasing…

Materials ScienceSuperconductivity

Interconnection of carbon nanotubes by chemical functionalization

Po‐Wen Chiu、Georg S. Duesberg、Urszula Dettlaff‐Weglikowska 等 4 位作者2002-05-20Applied Physics Letters

Intermolecular carbon nanotube junctions were formed by coupling chemically functionalized nanotubes with molecular linkers. An end-to-side or end-to-end heterojunction can be formed by reacting chloride terminated nanotubes with aliphatic diamine. The chemically modified nanotube mats were characterized by Raman spec…

Mechanical and Optical ResonatorsForce Microscopy Techniques and ApplicationsCarbon Nanotubes in Composites

On a Method for Multiscale Solid Mechanics

Amit Acharya2002-05-20arXiv

Given a fine-scale physical theory characterized by an evolutionary system of equations and a set of quantities, defined from the variables of the fine theory, that serve as a coarse representation of the fine scale phenomena, a systematic method for developing an evolutionary set of equations for the coarse quantitie…

cond-mat.stat-mechMaterials Science

Thermoelectric properties of the Bi- and Na-substituted Ca3Co4O9 system

Gaojie Xu、Ryoji Funahashi、Masahiro Shikano 等 5 位作者2002-05-20Applied Physics Letters

Bi- and Na-substituted Ca3Co4O9 polycrystalline samples have been prepared using a hot-pressing technique and their thermoelectric properties were carefully studied in air from room temperature to 1000 K. The substitutions of Bi3+ and Na+ for Ca2+, as well as Bi3+ and Na+ double substitution, cause both the electrical…

Thermal Expansion and Ionic ConductivityAdvanced Thermoelectric Materials and DevicesPhysics of Superconductivity and Magnetism

Microrheology of polyethylene oxide using diffusing wave spectroscopy and single scattering

Bivash Dasgupta、Shang-You Tee、John C. Crocker 等 5 位作者2002-05-20OpenAlex

Experiments investigating the local viscoelastic properties of a simple uncross-linked flexible polymer are performed on polyethylene oxide solutions in the semidilute regime using polystyrene beads of varying sizes and surface chemistry as probes. We measure the thermal motions of the beads to obtain the elastic and…

Rheology and Fluid Dynamics StudiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Vertical scaling of carbon nanotube field-effect transistors using top gate electrodes

Shalom J. Wind、Joerg Appenzeller、Richard Martel 等 5 位作者2002-05-20OpenAlex

We have fabricated single-wall carbon nanotube field-effect transistors (CNFETs) in a conventional metal–oxide–semiconductor field-effect transistor (MOSFET) structure, with gate electrodes above the conduction channel separated from the channel by a thin dielectric. These top gate devices exhibit excellent electrical…

Advancements in Semiconductor Devices and Circuit DesignCarbon Nanotubes in CompositesGraphene research and applications

Substrate effects in the magneto-optical second-harmonic generation from first principles: Fe/Cu(001)

Torsten Andersen、W. Huebner2002-05-19arXiv

We compute the nonlinear optical response of an Fe monolayer placed on top of 1 to 4 monolayers of Cu(001). Our calculation is based on ab initio eigenstates of the slab, which are obtained within the full-potential linearized augmented plane-wave method. The ground-state spin-polarized electronic structure is converg…

Materials Sciencephysics.opticsMesoscale and Nanoscale Physics

Steering effect on the shape of islands for homoepitaxial growth of Cu on Cu(100)

Jikeun Seo、S. -M. Kwon、H. -Y. Kim 等 4 位作者2002-05-19arXiv

The steering effect on the growth of islands is investigated by combining molecular dynamics (MD) and kinetic Monte Carlo (KMC) simulations. Dynamics of depositing atoms and kinetics of atoms on a substrate are realized by MD and KMC, respectively. The reported experimental results on the asymmetric island growth [van…

Materials ScienceSoft Condensed Matter

Analytical kinetics of clustering processes with cooperative action of aggregation and fragmentation

Vladimir M. Dubovik、Arkadi G. Galperin、Viktor S. Richvitsky 等 4 位作者2002-05-19arXiv

Some models of clustering processes are formulated and analytically solved employing generating functions methods. Those models include events which result from combined action of the coagulation and fragmentation processes. Fragmentation processes of two kinds, so-called similar and arbitrary, ones, are brought forwa…

math.PRMaterials Sciencemath.MPmath-phcond-mat.stat-mech

Electronic states in ideal free standing films

Shang Yuan Ren2002-05-19arXiv

Exact and general results on the electronic states in ideal free standing films are presented. In many interesting cases, such as in FCC (001) films and in FCC (110) films, the energies of most electronic states in the film can be analytically obained from the corresponding energy band structure of the bulk. This appr…

Materials Science

Selective Alteration of Polymer Surfaces by Thermal Cleavage of Fluorinated Side Chains

Alexander Böker、Thomas Herweg、Karsten Reihs2002-05-18Macromolecules

We have synthesized a series of fluorinated side chain block copolymers based on either a hydroborated polystyrene- b -polyisoprene or a poly(methyl methacrylate)- b -poly(2-hydroxyethyl methacrylate) backbone. Through polymer-analogous reactions, perfluorinated ester, fluorinated urethane, and fluorinated carbonate s…

Adhesion, Friction, and Surface InteractionsNanofabrication and Lithography TechniquesSurface Modification and Superhydrophobicity

A New, Facile Synthesis of 1,4,7,10-Tetraazacyclododecane: Cyclen

Phillip S. Athey、Garry E. Kiefer2002-05-18The Journal of Organic Chemistry

This report outlines a new and efficient synthesis of cyclen (1,4,7,10-tetraazacyclododecane, 1) utilizing bis-imidazoline, 6 (1,1'-ethylenedi-2-imidazoline), with 1,2-dibromoethane. General conditions were developed, allowing for the simple, three-step synthesis of 1 at the multigram scale with an isolated overall yi…

Lanthanide and Transition Metal ComplexesRadiopharmaceutical Chemistry and ApplicationsSupramolecular Chemistry and Complexes

Dissolution of Kestelek's Colemanite Containing Clay Minerals in Water Saturated with Sulfur Dioxide

Özkan Küçük、M. Muhtar Kocakerìm、Ahmet Yartaşı 等 4 位作者2002-05-18Industrial & Engineering Chemistry Research

Colemanite is one of the most important underground riches of Turkey, having approximately 60% of the world boron deposits, and it has a large portion in the deposits. When colemanite having a 2CaO·3B 2 O 3 ·5H 2 O formula is mined naturally, it contains various clay minerals. During boric acid production by a sulfuri…

Calcium Carbonate Crystallization and Inhibition