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Two-dimensional ferromagnetic intermolecular interactions in crystals of the p-cyanophenyl nitronyl nitroxide radical

Yuko Hosokoshi、Masafumi Tamura、Hiroshi Sawa 等 5 位作者1995-01-01Journal of Materials Chemistry

The crystal structure of the p-cyanophenyl nitronyl nitroxide [2-(4-cyanophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1-H-imidazol-1-oxyl 3-N-oxide, abbreviated as p-CNPNN] radical has been solved. It belongs to the orthorhombic system, space group Ic2a, with a= 10.482(2)Å, b= 26.615(5)Å, c=9.903(2)Å and Z= 8. The asymmetr…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Relationship between refractive index, optical electronegativities and electronic polarizability in alkali halides, III–V, II–VI group semiconductors

R.R. Reddy、Y. Nazeer Ahammed1995-01-01Crystal Research and Technology

Abstract Refractive indices have been evaluated from DUFFY'S optical electronegativities. The validity of the proposed empirical relation has been tested in the case of II–Vi, III–V compound semiconductors and alkali halides by comparing the calculated values of n with those in the literature. The estimated refractive…

Chalcogenide Semiconductor Thin FilmsSemiconductor materials and interfacesSolid-state spectroscopy and crystallography

Regulation of the P25 gene transcription in the silk gland of Bombyx

Pascale Nony、Jean‐Claude Prudhomme、Pierre Couble1995-01-01Biology of the Cell

The gene encoding the silk protein P25 is specifically transcribed in the posterior silkgland of Bombyx during larval intermoults and is repressed during moults. By performing in vitro DNA-protein interactions, at least five putative regulatory elements were localized in the 5' flanking region of the gene. The most pr…

Insect Resistance and GeneticsSilk-based biomaterials and applicationsSilkworms and Sericulture Research

New method for the measurement of line tensions at the solid/liquid/air three-phase contact line

Robert Aveyard、John H. Clint1995-01-01Journal of the Chemical Society Faraday Transactions

A recently reported method for the determination of contact angles of small monodisperse spherical particles with liquid/vapour interfaces has been extended for the measurement of line tensions of the solid/liquid/air contact line. The method involves compressing monolayers of particles on a liquid substrate in a Lang…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsParticle Dynamics in Fluid Flows

Corrosion of ceramics

Ronald A. McCauley1995-01-01M. Dekker eBooks

Fundamentals Introduction Corrosion by Liquids Corrosion by Gas Corrosion by Solid Surface Effects Acid/Base Effects Thermodynamics Kinetics Diffusion Summary of Important Concepts Additional Related Reading Exercises, Questions, and Problems References Methods of Corrosion Analysis Introduction Laboratory test vs. Fi…

Material Selection and PropertiesMaterials Engineering and ProcessingPigment Synthesis and Properties

Nitrogen-14 quadrupole resonance detection of RDX and HMX based explosives

J. A. S. Smith1995-01-01OpenAlex

Concerns the use of 14N signals in RDX and HMX. The principle is to subject the quadrupole nuclei to bursts of RF radiation and monitor the signals generated in the quiescent periods between pulses. These signals may be divided into two types: free induction decays (FID) and echoes. The first is the decaying signal ob…

Energetic Materials and CombustionAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Building block ligands for new molecular conductors: homobimetallic tetrathiafulvalene tetrathiolates and metal diselenolenes and ditellurolenes

Richard D. McCullough、J.A. Belot、Jyoti Seth 等 6 位作者1995-01-01Journal of Materials Chemistry

Important building block ligands such as 2-thioxo-1,3-dithiole-4,5-dithiolate (dmit) and ethene-1,2-dithiolate (thiolene) form metal complexes that have been found to exhibit metallic conductivity and superconductivity. The syntheses of three well defined building block ligands that can lead to new molecular conductor…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Metastable Phase Diagrams and Rapid Solidification Processing.

P. Gilgien、A. Zryd、W. Kurz1995-01-01ISIJ International

Efficient metallurgical and processing development requires ability to predict the solidification microstructure of products. Models were developed to calculate possible growth morphologies and phases in order to select the most efficient one for a given solidification condition. It is then possible to predict solidif…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgy and Material Forming

Dy-distribution in the grains of high-energy (Nd,Dy)-Fe-B magnets

M. Velicescu、P. Schrey、W. Rodewald1995-01-01IEEE Transactions on Magnetics

Sintered (Nd,Dy)-Fe-B-magnets were manufactured by adding low melting RE/sub 3/Co or RE/sub 3/Co/sub 2/ alloys (RE=Nd or/and Dy) to basic alloys with compositions close to the Nd/sub 2/Fe/sub 14/B stoichiometry. The remanent polarizations and the coercivities of sintered and annealed magnets with about 2 wt.% Dy range…

Magnetic Properties and ApplicationsMagnetic Properties of AlloysSuperconducting Materials and Applications

Molecular modelling for copper(II) centres

Veronica J. Burton、Robert J. Deeth1995-01-01Journal of the Chemical Society Chemical Communications

d-Electron stabilisation energies provide a general framework for extending conventional Molecular Mechanics to open-shell complexes; a single set of Force Field parameters successfully models both planar CuN4 and Jahn–Teller distorted, tetragonally elongated CuN6 amine complexes.

Metal-Organic Frameworks: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchMachine Learning in Materials Science

Reduction of Siliceous Manganese Ore by Graphite.

Oleg Ostrovski、Thomas Webb1995-01-01ISIJ International

Reduction of siliceous manganese ore containing 41.0 wt%Mn and 11.0 wt%SiO2 by graphite has been studied by the measurement of weight loss in argon atmosphere at 900, 1200 and 1400°C and following by X-ray diffraction and Microprobe analyses. The ore was sized to –150+53 μm and preliminary calcined at 1000°C in argon…

Metallurgical Processes and ThermodynamicsIron and Steelmaking ProcessesGraphite, nuclear technology, radiation studies

Thermal Oxidation of ZnS Modifications Sphalerite and Wurtzite

D. Schultze、U. Steinike、J. Kussin 等 4 位作者1995-01-01Crystal Research and Technology

Abstract The oxidation of phase pure ZnS in the wurtzite and sphalerite modification upon heating in an air flow has been studied by simultaneous thermogravimetry‐differential thermal analysis and in‐situ X‐ray diffraction at high temperature (high temperature camera and electron synchrotron). The oxidation of wurtzit…

Advanced ceramic materials synthesisMaterial Properties and Applications

Integral expressions of the derivatives of the small-angle scattering correlation function

S. Ciccariello1995-01-01Journal of Mathematical Physics

The integral expressions of the derivatives of the small-angle scattering correlation function are obtained in terms of the parametric equations of the interphase surfaces. For each derivative, its integral expression is the surface average of a loop integral of a vectorial field that is the only quantity depending on…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical Studiesnanoparticles nucleation surface interactions

The improvement in adhesion of polyurethane-polypropylene composites by short-time exposure of polypropylene to low and atmospheric pressure plasmas

Jörg F. Friedrich、Wolfgang E. S. Unger、Andreas Lippitz 等 8 位作者1995-01-01Journal of Adhesion Science and Technology

The surfaces of polymers, namely polypropylene, copolymers and blends, were exposed to low pressure oxygen and atmospheric pressure air plasmas to improve their adhesion to polyurethane adhesives. A correlation is attempted between lap shear strengths of polypropylene-polyurethane composites and the relevant XPS, AFM…

Surface Modification and SuperhydrophobicityDiamond and Carbon-based Materials ResearchHigh voltage insulation and dielectric phenomena

Application of Micromechanical Models to the Analysis of Ductile Fracture Under Dynamic Loading

D-H Sun、A Hönig、Wolfgang Böhme 等 4 位作者1995-01-01OpenAlex

Dynamic tensile tests and instrumented impact tests with Charpy-V-notch specimens and precracked Charpy specimens (SENB) are performed and simulated. Two strain-rate dependent micromechanical models based on the modified Gurson flow function are compared by simulating different dynamically loaded specimens. One purpos…

Metal Forming Simulation TechniquesMetallurgy and Material FormingHigh-Velocity Impact and Material Behavior

Direct torque control of induction motors

Ingo Lüdtke1995-01-01OpenAlex

A direct torque control system for a variable speed induction motor drive consists of two hysteresis comparators, a selection table, a flux and torque estimator, and a PID speed controller. With this control structure, the drive performance can be significantly improved when compared to field oriented control. In the…

Electric Motor Design and AnalysisSensorless Control of Electric MotorsMagnetic Properties and Applications

Annealing Effect on Phase Transition of Equiatomic FeRh Alloy

Makoto Takahashi、Ryuichiro Oshima1995-01-01Materials Transactions JIM

The effect of thermal treatment on the behavior of the transition of an Fe-50.5 at%Rh alloy between the anti-ferromagnetic and ferromagnetic phase was carefully investigated with electric resistivity measurements and transmission electron microscopy (TEM).The specimens were annealed near 1000 K after solution treatmen…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMagnetic Properties and Applications

Ceramic matrix composites (CMC)

Kiyohito Okamura1995-01-01Advanced Composite Materials

High-strength ceramic molds with heat resistance and oxidation resistance have been fabricated, and they are now applied to practical parts such as turbo rotors, bearings and machining tools. However, their fracture toughness and thermal shock resistance are poor and their reliability is also low. In order to improve…

Advanced ceramic materials synthesisAdvanced materials and compositesMetallurgical and Alloy Processes

Refiner Mechanical and Biomechanical Pulping of Jute

H. S. Sabharwal、Masood Akhtar、Robert A. Blanchette 等 4 位作者1995-01-01Holzforschung

Atmospheric refiner mechanical pulping of untreated, fungal and alkali treated jute bast has been explored in the present investigation. Hammermilled and cut jute bast strands were refined in a laboratory single disc refiner under atmospheric conditions. First stage refining was carried out to about 500 ml. CSF and se…

Advanced Cellulose Research StudiesLignin and Wood ChemistryPolysaccharides Composition and Applications