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Microphase structure of interpenetrating polymeric networks based on polyurethane and polyurethane ionomer

Yu.S. Lipatov、В.В. Шилов、V. A. Bogdanovich 等 5 位作者1987-01-01Journal of Polymer Science Part B Polymer Physics

Abstract Interpenetrating polymer networks based on polyurethane and polyurethane ionomer were studied using wide‐angle and small‐angle X‐ray diffraction. The polyurethane network is a multiblock polymer based on the trimethylolpropane adduct with 2,4‐toluene‐diisocyanate and poly(propylene oxide tetrahydrofuran) copo…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Geochemistry of silica-rich brines from Lake Natron (Tanzania). Géochimie des saumures riches en silice du lac Natron (Tanzanie)

Bertrand Fritz、Marie-Paul Zins-Pawlas、Moncef Gueddari1987-01-01Sciences Géologiques Bulletin

A computer program has been developed for calculating the activity coefficients of aqueous silica species. This program allows to the testing of the saturation states of silicate minerals in solutions concentrated by evaporation, particularly in alkaline brines. This has been done first for water samples from the Lake…

Clay minerals and soil interactionsDiatoms and Algae ResearchGeochemistry and Geologic Mapping

Egg Albumen as a Source of Foam Polypeptide in Beer

Charles W. Bamforth、Roy Cope1987-01-01Journal of the American Society of Brewing Chemists

Egg white (albumen) can be used to improve the foam characteristics of beers. Hydrolysis increases the foam potential of albumen to a level considerably superior to that of beer polypeptides and commercial whipping proteins from soy beans and also removes any tendency to cause hazes in pasteurized beer. It appears, ho…

Proteins in Food SystemsPickering emulsions and particle stabilization

Formation of Deformation Bands and Work Hardening of FCC Crystals

Jin-ichi Takamura1987-01-01Transactions of the Japan Institute of Metals

Explication a partir de differentes discussions du mecanisme de durcissement par deformation lors de la formation des bandes de deformation, ces bandes etant reliees a la structure de dislocations et au systeme de glissement

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsAdvanced materials and composites

The surface treatment and adhesive bonding of polyetheretherketone. Part II. Surface characterization

J. R. G. Evans、R. Bulpett、M. Ghezel1987-01-01Journal of Adhesion Science and Technology

A range of surface treatments including chromate and plasma etching, which are capable of producing both chemical modification and surface topography modification of polymer surfaces, were applied to polyetheretherketone. The resulting surfaces were characterized by X-ray photoelectron spectroscopy (XPS), scanning ele…

Corrosion Behavior and InhibitionSurface Modification and SuperhydrophobicitySilicone and Siloxane Chemistry

X-Ray crystal structure and properties of dibenzotetrathiafulvalenium trichlorodiethylstannate(IV)

Gen‐etsu Matsubayashi、Ryuichi Shimizu、Toshio Tanaka1987-01-01Journal of the Chemical Society Dalton Transactions

A single-crystal X-ray analysis of the salt [dbttf][SnEt2Cl3] has revealed that both the dibenzotetrathiafulvalenium radical cations, dbttf˙+, and the [SnEt2Cl3]– anions exist as dimers. The crystals are triclinic, space group P, with cell dimensions a= 12.795(3), b= 12.960(5), c= 7.463(1)Å, α= 95.86(3), β= 108.62(2),…

Crystal structures of chemical compoundsMagnetism in coordination complexesOrganic and Molecular Conductors Research

Phase Analysis Studies in the System Cu2O--Ta2O5.

Lena Jahnberg、Erling Fjær、Arne Karlsson 等 5 位作者1987-01-01Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry

Par chauffage de melanges Cu 2 O-Ta 2 O 5 sous vide entre 800 et 1100 o C, preparation de deux phases intermediaires de compositions tres proches; Cu 5 Ta 11 O 30 et Cu 3 Ta 7 O 19 . Structures de ces phases

Copper Interconnects and ReliabilityMicrowave Dielectric Ceramics SynthesisMetallurgical and Alloy Processes

Structural Refinements of ZrO<sub>2</sub> and HfO<sub>2</sub> Treated at 600°C⋅6GPa

Ryuji Suyama、Hiroyuki Horiuchi、Shōichi Kume1987-01-01Journal of the Ceramic Association Japan

The Rietveld refinements of crystal structure were undertaken on powder samples of ZrO2 and HfO2 quenched from 600°C⋅6GPa. The results on orthorhombic ZrO2 were consistent with those of a single crystal obtained under pressure. The compressibility of this phase was calculated as 4.65×10-3GPa-1. The results on HfO2 wer…

Semiconductor materials and devicesMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

Methylation of tin(II) and lead(II) in sediment by carbanion donors

Spyridon Rapsomankis、Olivier François Xavier Donard、James H. Weber1987-01-01Applied Organometallic Chemistry

Abstract A factorial experimental design determined separate and combined effects of MeCoB 12 (methylcobalamin) and Me 2 Co(N 4 ) + (a methylcobalamin model) on methylation of Sn(II) and Pb(II) in sediment matrices. Total methyltin yields ranged from 1.4% to 3.2%, and total methyllead yields varied from 0.037% to 0.11…

Corrosion Behavior and InhibitionChromium effects and bioremediationEnvironmental DNA in Biodiversity Studies

Importance of macrocyclic ring deformation in the facile aerial oxidation of phenolic porphyrins

Andrew J. Golder、Lionel R. Milgrom、Kevin B. Nolan 等 4 位作者1987-01-01Journal of the Chemical Society Chemical Communications

Unlike its metal-free precursor and NiII analogue, meso-tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)- porphyrinatopalladium(II) undergoes very little aerial oxidation in basified dichloromethane, owing to metal-enforced planarity of the porphyrin macrocycle, as shown by crystal structure determinations of the two complexe…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Etude de la transmission et de la rétrodiffusion d'électrons d'énergie 0,05 à 3 MeV dans le domaine de la diffusion multiple

G. Soum、A. Mousselli、F. Arnal 等 4 位作者1987-01-01Revue de Physique Appliquée

Le comportement des électrons dans la matière est d'un intérêt fondamental, notamment en microscopie à balayage, en microanalyse et en physique spatiale. Nous présentons dans cet article l'ensemble de nos résultats expérimentaux dans le domaine de la diffusion multiple pour un faisceau d'électrons monocinétiques tomba…

Advanced Chemical Physics StudiesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Studies of α relaxation process in spherulitic and nonspherulitic samples of isotactic polypropylene with different molecular ordering

M. Pluta、M. Κryszewski1987-01-01Acta Polymerica

Abstract Mechanical and rheo‐optical data have been obtained as a function of frequency at constant temperatures for two series of spherulitic and nonspherulitic samples of isotactic polypropylene having different ordering on molecular level. It was found that the structure differentation influence on the nature of th…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Bacterial Adherence on Fabrics by a Radioisotope Labeling Method

You‐Lo Hsieh、Debra A. Timm、J M Merry1987-01-01Textile Research Journal

A radioisotope labeling technique was used to quantify the adherence of Staphy lococcus aureus, Staphylococcus epidermidis, and Escherichia coli on eight fabrics. The extent of bacterial adherence depends on the bacterial type, the fiber content, and the contact condition. Staphylococci adhered more than Escherichia c…

Contact Dermatitis and AllergiesTextile materials and evaluationsAntimicrobial agents and applications

An optical study of the interfacial region of a surface-aligned nematic liquid crystal

John Nicholson1987-01-01Journal de physique

The optical reflectivity from the interfacial region of a nematic/solid wall boundary has been measured as a function of incident angle and temperature for 7CB. Considerable deviation from Fresnel reflectivity occurs for the E-ray whereas reflectivities for the 0-ray are similar to Fresnel. To fit the experimental dat…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPlant Reproductive Biology

Soils with Bx Horizons in the Upper Coastal Plains of South Carolina

B. R. Smith、Lindsay Callahan1987-01-01Soil Science Society of America Journal

Abstract Soils with firm, dense Bx horizons are extensive in the Upper Coastal Plains including the Sandhills of Georgia, North Carolina, and South Carolina. The Bx horizons are slightly brittle to brittle, but prisms with bleached, vertical faces are often weakly developed or absent. Three pedons of a series represen…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Synthesis and Liquid Crystal Properties of Compounds Incorporating Cyclobutane, Spiro[3.3]Heptane and Dispiro[3.1.3.1]Decane Rings

L. K. M. Chan、P. A. Gemmell、G. W. Gray 等 5 位作者1987-01-01Molecular crystals and liquid crystals

A number of esters of structure (I) incorporating the cyclobutane, spiro[3.3]heptane, or dispiro[3.1.3.1]decane rings has been prepared using a diethyl malonate synthesis. Strict comparison of the liquid crystal behaviour amongst the three classes containing a terminal cyano-substituent was not possible because both t…

Liquid Crystal Research AdvancementsPlant and animal studiesPlant biochemistry and biosynthesis

Aspect mécanique de la croissance des racines. I. - Mesure de la force de pénétration

N. Souty、C. Rode1987-01-01Agronomie

Dans un sol, milieu heterogene, une racine peut rencontrer des zones de resistance differente a la pentration qui font obstacle a son enfoncement et a son developpement. En laboratoire, nous avons modelise un tel obstacle par une lamelle d'acier sur laquelle est collee une jauge extensometrique. Nous pouvons ainsi det…

Diatoms and Algae ResearchPolymer-Based Agricultural EnhancementsBiocrusts and Microbial Ecology

Anti-Ulcer Activity ofTeucrium polium

Husni A.A. Twaij、Ammar A. Al-Badr、Ali Abul-Khail1987-01-01International Journal of Crude Drug Research

Aqueous extract of Teucrium polium was broadly used in folk medicine for treatment of gastric ulcer in Iraq and some Arab countries. In our laboratory the induction of gastric ulcer was done in starved rats by reserpine (20 mg/kg i.p.) or by stress. T. polium (150 mg/kg i.p.) as a crude extract produced 50% healing of…

Microbial Metabolites in Food BiotechnologyPhytochemistry and Bioactive CompoundsCynara cardunculus studies

Regulation of the enzymes at the branchpoint between the citric acid cycle and the glyoxylate bypass in Escherichia coli.

Hugh G. Nimmo、A C Borthwick、E.M.T. El-Mansi 等 6 位作者1987-01-01PubMed

During growth of Escherichia coli on acetate, the glyoxylate bypass supplies the precursors needed for biosynthesis. The glyoxylate bypass enzyme isocitrate lyase competes with the citric acid cycle enzyme isocitrate dehydrogenase for the available isocitrate. We have studied the control of metabolic flux at this bran…

Microbial Metabolic Engineering and BioproductionEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Origin of porosity in synthetic materials

Dale W. Schaefer、J. P. Wilcoxon、K. D. Keefer 等 7 位作者1987-01-01AIP conference proceedings

Several porous silicas have been studied in order to determine the origin of porosity in random porous media. The silica system offers a unique opportunity to study the origin of porous structures because a variety of different structures can be synthesized depending on precursor chemistry and physics. In solution‐gro…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisDiatoms and Algae Research