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Enhanced Redox Transformation Efficiency in Unconjugated Electroactive Polymer/Carbon Nanotube Hybrids

Xianwen Mao、Esther H. Yan、Gregory C. Rutledge 等 4 位作者2016-01-05Chemistry of Materials

The mechanism for the redox activity of electroactive polymers (EAPs) with unconjugated backbones (e.g., polyvinylferrocene, PVFc) is fundamentally different from that of intrinsically conducting polymers. Here we investigate, for the first time, the redox transformation efficiency (RTE) of unconjugated EAPs with disc…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications

Pentafluorophenyl Ester-Functionalized Nanoparticles as a Versatile Platform for Selective and Covalent Inter-nanoparticle Coupling

Jimmy Lawrence、Todd Emrick2016-01-05ACS Applied Materials & Interfaces

Preparing chemically selective nanoparticle (NP) building blocks to make robust structures from different NP compositions often requires complex hetero-bifunctional ligand pairs that have limited scalability and versatility. Here we describe pentafluorophenyl ester-functionalized nanoparticles (PFP-NPs) as versatile b…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Effect of Composition and Impurities on the Phosphorescence of Green-Emitting Alkaline Earth Aluminate Phosphor

Doory Kim、Han-Eol Kim、Chang‐Hong Kim2016-01-05PLoS ONE

Recent improvements to SrAl2O4:Eu2+, Dy3+ phosphors have enabled the use of luminescent hosts with a stable crystal structure and high physical and chemical stability, thus overcoming the bottleneck in the applicability of ZnS:Cu phosphors. However, enhancement of afterglow lifetime and brightness in SrAl2O4:Eu2+, Dy3…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsAmmonia Synthesis and Nitrogen Reduction

Bonding Scheme, Hydride Character, and Magnetic Paths of (HPO3)2– Versus (SeO3)2– Building Units in Solids

Vadim M. Kovrugin、Elijah E. Gordon、Esra E. Kasapbasi 等 9 位作者2016-01-05The Journal of Physical Chemistry C

The abilities of the (HPO 3 ) 2– and (SeO 3 ) 2– anions as structure building units and as spin exchange paths between magnetic ions were investigated by preparing and analyzing the isostructural Fe 2 (SeO 3 ) 3 and Fe 2 (HPO 3 ) 3 . In both compounds, the face-sharing Fe 2 O 9 dimers are interconnected into chains by…

Glass properties and applicationsCrystal Structures and PropertiesChemical Synthesis and Characterization

Two-Dimensional, pH-Responsive Oligoglycine-Based Nanocarriers

Rosa Garriga、Izabela Jurewicz、Elena Romero 等 7 位作者2016-01-05ACS Applied Materials & Interfaces

The nanocarrier capabilities of atomically smooth two-dimensional sheets of a biantennary oligoglycine peptide C8H16(-CH2-NH-Gly5)2 (also called tectomers) are demonstrated. We show that the pH-controlled, rapid, and reversible assembly and disassembly of oligoglycine can be effectively used for controlled loading and…

Advanced biosensing and bioanalysis techniquesSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials

Carbon nanotube-based supercapacitors using low cost collectors

M. Amirhoseiny、Majid Zandi、Abolghasem Mosayyebi 等 4 位作者2016-01-05Modern Physics Letters B

In this work, electrochemical double layer supercapacitors were fabricated using multiwalled carbon nanotube (MWCNT) composite microfilm as electrode. To improve the electrochemical properties, MWCNTs were functionalized with −COOH by acid treatments. CNT/PVA films have been deposited on different current collectors b…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Comparison of heat transfer coefficient for different fabrics by vapor-compression system

Majid Joghatai、Dariush Semnani、Mohammad Reza Salimpour 等 5 位作者2016-01-05International Journal of Engineering & Technology

The selection of a suitable fabric layer is an important aspect in the development of a cooling garment. One of the essential ingredients in selecting fabric for cooling garments is high heat transfer coefficient. In this study five different type of knitting fabrics with similar woven pattern were selected. The fabri…

Thermoregulation and physiological responsesTextile materials and evaluationsThermal Radiation and Cooling Technologies

Synthesis of Fe3O4nanoparticles for biomedical applications

K. Onar、M. E. Yakıncı2016-01-05Journal of Physics Conference Series

Nano particles of Fe 3 O 4 with the range of 6.9 and 14.2 nm. By using chemical coprecipitation method. Particle size effect according to magnetic properties were investigated together with the constant reaction and crystallization temperature. According to calculations peaks were indexed as cubic Fe 3 O 4 for all sam…

Nanoparticle-Based Drug DeliveryMagnetic Properties and Synthesis of FerritesCharacterization and Applications of Magnetic Nanoparticles

Inner and Outer Coordination Shells of Mg2+ in CorA Selectivity Filter from Molecular Dynamics Simulations

Sunan Kitjaruwankul、Pattama Wapeesittipan、Panisak Boonamnaj 等 4 位作者2016-01-05The Journal of Physical Chemistry B

Structural data of CorA Mg(2+) channels show that the five Gly-Met-Asn (GMN) motifs at the periplasmic loop of the pentamer structure form a molecular scaffold serving as a selectivity filter. Unfortunately, knowledge about the cation selectivity of Mg(2+) channels remains limited. Since Mg(2+) in aqueous solution has…

High-pressure geophysics and materialsSolid-state spectroscopy and crystallographyInorganic Fluorides and Related Compounds

Low-temperature powder X-ray diffraction measurements in vacuum: analysis of the thermal displacement of copper

Nanna Wahlberg、Niels Bindzus、Sebastian Christensen 等 7 位作者2016-01-05Journal of Applied Crystallography

A serious limitation of the all-in-vacuum diffractometer reported by Straasø, Dippel, Becker & Als-Nielsen [ J. Synchrotron Rad. (2014), 21 , 119–126] has so far been the inability to cool samples to near-cryogenic temperatures during measurement. The problem is solved by placing the sample in a jet of helium gas…

Advanced materials and compositesX-ray Diffraction in CrystallographyPowder Metallurgy Techniques and Materials

Role of Yarn Tension in Weaving

Samir Kumar Neogi2016-01-05WPI Publishing eBooks

Role of Yarn Tension in Weaving deals exclusively with the various aspects of tension of warp and weft yarns during weaving and its preparatory processes. The ten chapters contain numerous illustrations so that the text can be understood easily and clearly. This book will be useful to students, mill personnel, and res…

Textile materials and evaluationsFashion and Cultural Textiles

Toxicokinetic Modeling Challenges for Aquatic Nanotoxicology

Wei‐Yu Chen2016-01-05Frontiers in Marine Science

Nanotoxicity has become of increasing concern since the rapid development of metal nanoparticles (NPs). Aquatic nanotoxicity depends on crucial qualitative and quantitative properties of nanomaterials that induce adverse effects on subcellular, tissue, and organ level. The dose-response effects of size-dependent metal…

Nanoparticles: synthesis and applicationsEnvironmental Toxicology and EcotoxicologyElectrochemical Analysis and Applications

Solubility of (S)-3-(Aminomethyl)-5-Methylhexanoic Acid in Pure and Binary Solvent Mixtures

Giuseppe Cogoni、Brian de Souza、Denise M. Croker 等 4 位作者2016-01-05Journal of Chemical & Engineering Data

The solubility of (S)-3-(aminomethyl)-5-methylhexanoic acid in both 2-propanol and water and methanol and water mixtures, as well as in pure solvents, is reported across the temperature range of 283.15–338.15 K, as determined gravimetrically under atmospheric conditions. The experimental data is correlated using the e…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsChemical Thermodynamics and Molecular Structure

Development of ethenetetrathiolate hybrid thermoelectric materials consisting of cellulose acetate and semiconductor nanomaterials

Hitoshi Asano、Naoko Sakura、Keisuke Oshima 等 5 位作者2016-01-05Japanese Journal of Applied Physics

Abstract We investigated novel organic/inorganic hybrid thermoelectric materials prepared using several metal-polymer complexes, binders (insulating polymers), and inorganic semiconductor nanomaterials. It was found that the three-component hybrid thermoelectric materials, which consisted of nanodispersed poly(nickel…

Perovskite Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesConducting polymers and applications

Synthesis and Characterization of Monodisperse Metallodielectric SiO2@Pt@SiO2Core–Shell–Shell Particles

Alexey M. Petrov、Hauke Lehmann、Maik Finsel 等 6 位作者2016-01-05Langmuir

Metallodielectric nanostructured core-shell-shell particles are particularly desirable for enabling novel types of optical components, including narrow-band absorbers, narrow-band photodetectors, and thermal emitters, as well as new types of sensors and catalysts. Here, we present a facile approach for the preparation…

Gold and Silver Nanoparticles Synthesis and ApplicationsCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Catalytic Removal of Volatile Organic Compounds

Jean‐François Lamonier2016-01-05Catalysts

The degradation of air quality by the release of volatile organic compounds (VOCs) into the air particularly harms human health and our environment. [...]

Catalytic Processes in Materials ScienceAir Quality Monitoring and ForecastingIndustrial Gas Emission Control

Optical Coatings as Mirrors for Optical Diagnostics

L. Marot、G. Arnoux、A. Huber 等 7 位作者2016-01-05Journal of Coating Science and Technology

The aim of this work was to provide a comprehensive insight concerning coated films which might be used for first mirrors in ITER. The influence of the mirror crystallite size has been addressed as well as the coating techniques to provide nanocrystalline films. Tests of coated mirrors both in laboratories and in toka…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsSurface Roughness and Optical Measurements

Axial, Helical, and Planar Chirality in Directly Linked Basket-Handle Porphyrin Arrays

Andreas C. Gehrold、Torsten Bruhn、Gerhard Bringmann2016-01-05The Journal of Organic Chemistry

The single-electron oxidative dimerization of basket-handle porphyrins (BHPs) with different coordinated metal ions [Cu(II), Ni(II), Pd(II), Zn(II)] yielded directly meso-meso linked dimers in excellent yields. The synthetic protocol is suited for coupling substrates with different meso-substituents (H, Br, aryl, alky…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Preparation, properties of In‐situ silica modified styrene‐butadiene rubber and its silica‐filled composites

Changjie Yin、Qiuyu Zhang、Jianxun Liu 等 5 位作者2016-01-05Polymer Composites

In this work, native emulsion polymerization styrene butadiene rubber (SBR) were first grafted by vinyltriethoxysilane (VTES) to SBR‐ g ‐VTES (VTES grafted SBR), second, the SBR‐ g ‐VTES were modified by different amount of TEOS (tetraethoxysilane) using in situ sol‐gel method, at the last, the extra silica was added…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingPolymer Nanocomposite Synthesis and Irradiation