Materials Literature
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A microparticulate protein delivery system was developed using collagen, from the medusa Catostylus tagi, as a polymeric matrix. Collagen microparticles (CMPs) were produced by an emulsification-gelation-solvent extraction method and a high loading efficiency was found for the entrapment of lysozyme and α-lactalbumin.…
High-quality CdS and Cu(7)S(4) quantum dots (QDs) were synthesized with N,N-dibutylthiourea (DBTU) as an organic sulfur source. In this method, nucleation and growth reactions were controlled simply by the heating rate of the reaction. The mild oxidation conditions gave monodisperse CdS QDs exhibiting pure band-edge e…
Nonlinear transport properties are reported in the layered DyTe${}_{3}$ compound at a temperature below the charge-density-wave (CDW) transition ${T}_{P}=302$ K. Conductivity increases sharply above the threshold electric field. Under application of a rf field, Shapiro steps are clearly observed. These features demons…
The irradiation effects in graphene supported by SiO(2) substrate including defect production and implantation efficiency are investigated using the molecular dynamics (MD) method with empirical potentials. We show that the irradiation damage in supported graphene comes from two aspects: the direct damage induced by t…
We observe a strong twin-orientation dependent hardness and strain rate sensitivity (m) in nanotwin copper. A highest m value of 0.059 ± 0.004 and an activation volume (V) of ∼10b3 are measured when deformation is predominately vertical to twin boundaries (TBs), whereas a much smaller m and larger V are observed for t…
Quantum dots (QDs) are novel tools with multiple biological and medical applications because of their superior photoemission and photostability characteristics. However, leaching of toxic metals from QDs is of great concern. Therefore, for the successful application of QDs in bioscience, it is essential to understand…
The magnetic, elastic, and anelastic behavior of single-crystal KMnF${}_{3}$ have been investigated by superconducting quantum interference device (SQUID) magnetometry and resonant ultrasound spectroscopy (RUS) through the sequence of phase transitions: phase I, $Pm$$\overline{3}$$m$ $\ensuremath{\rightarrow}\phantom{…
Shape-tunable Ag nanoplates in alumina enable very strong SERS performances showing Raman enhancement factor >1 × 10(9), and allows for easy detection of analyte methylene blue having a concentration in the picomolar range. Raman enhancements have been systematically studied during the Ag nanoparticle-shape evolution…
Wood-derived cellulosic fibers prepared in different ways were successfully employed to absorb simulated crude oil, demonstrating their possible use as absorbents in the case of oil spills. When dry fibers were used, the highest sorption capacity (six parts of oil per unit mass of fiber) was shown by bleached softwood…
A versatile method for decorating magnetic nanobeads (being composite materials from polymers and superparamagnetic nanoparticles) with silver nanoparticles of 3-6 nm size is presented. Control over the silver nanoparticle coverage at the nanobead surface is achieved by changing the reaction parameters. Moreover, the…
BACKGROUND: Spider silk is one of the most versatile materials in nature with great strength and flexibility. Native and synthetically produced silk has been used in a wide range of applications including the construction of artificial tendons and as substrates for human cell growth. In the literature there are anecdo…
We use molecular dynamics simulations to compute junction thermal conductance of carbon nanotubes as a function of crossing angle and pressure, and conductivity of arrays and bundles consisting of multiple junctions as a function of pressure. Two types of arrays are investigated: crossbar structures consisting of alte…
Abstract A one‐step electrochemical process has been employed to synthesize composite films of polypyrrole/graphene (PPy/GR) by electrochemical polymerization on indium tin oxide (ITO) from an aqueous solution containing pyrrole monomer, graphene oxide (GO) nanosheets and sodium p ‐toluenesulfonate (NapTS). Thermograv…
Ru sitting comfortably: Ruthenium oxide nanoparticles show bienzyme-like activities, and are capable of catalyzing H(2)O(2) disproportionation at pH 7.0 and peroxidation at pH 4.0 in aqueous solutions (see scheme). Their specific activities are better than many natural catalases and peroxidases and far better than bif…
Because of their excellent electrical and optical properties, carbon nanotubes have been regarded as extremely promising candidates for high-performance electronic and optoelectronic applications. However, effective and efficient distinction and separation of metallic and semiconducting single-walled carbon nanotubes…
This study reported for the first time a novel microrobot that could continuously jump on the water surface without sinking, imitating the excellent aquatic locomotive behaviors of a water strider. The robot consisted of three supporting legs and two actuating legs made from superhydrophobic nickel foam and a driving…
Mesoporous silica nanoparticles (MSNs) are a versatile drug delivery system that can be used for loading of different guest molecules such as peptides, proteins, anticancer agents, and genetic material. MSNs are considered promising drug carriers due to their tuneable particle size, pore structure, and surface functio…
We demonstrate sequential assembly of chemically patchy colloids such that their valence differs from stage to stage to produce hierarchical structures. For proof of concept, we employ ACB triblock spheres suspended in water, with the C middle band electrostatically repulsive. In the first assembly stage, only A-A hyd…
We fabricated biomimetic hierarchical superhydrophobic surfaces using the Tobacco mosaic virus and investigated the role of each length scale during droplet impact by decomposing the micro and nanoscale components. We found that 10 μl water droplets rebounded at impact velocities greater than 4.3 m/s on the hierarchic…
Aligned poly( l -lactide) (PLLA) electrospun nanofibers of different molecular weights ( M w = 100K, 300K, and 700K) were collected using a rotating disk at take-up velocities of 63, 630, and 1890 m/min. Structural development within the spun fibers was examined. Enhanced crystallinities were observed within the fiber…