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A study of the decomposition behaviour of 12-tungstophosphate heteropolyacid in solution

Zhirong Zhu、Ruan Tain、Colin Rhodes2003-10-01Canadian Journal of Chemistry

In this paper, the decomposition of H 3 PW 12 O 40 in aqueous solution or in mixed solutions of water–ethanol or water–acetone is investigated by potentiometric titration and 31 P NMR. Identification of the products from H 3 PW 12 O 40 decomposition over a pH range of 1–12 was achieved using preparation high performan…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Strain relaxation in the epitaxy of La2/3Sr1/3MnO3grown by pulsed-laser deposition on SrTiO3(001)

Jean‐Luc Maurice、F. Pailloux、A. Barthélémy 等 8 位作者2003-10-01The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

With a Curie point at 370 K, the half-metal (La0.7Sr0.3)MnO3 (LSMO) is one of the most interesting candidates for electronic devices based on tunnel magnetoresistance. SrTiO3 (STO) is up to now the best substrate for the epitaxy of suitable thin films of LSMO. The pseudocubic unit cell of rhombohedral LSMO has a param…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Preparation of Crosslinked Chitosan/Silk Fibroin Blend Films for Drug Delivery System

Ratana Rujiravanit、Sopon Kruaykitanon、Alexander M. Jamieson 等 4 位作者2003-10-01Macromolecular Bioscience

Abstract Crosslinked chitosan/silk fibroin blend films were prepared by a solution casting technique using glutaraldehyde as crosslinking agent. Drug release characteristics of the blend films with various blend compositions were investigated. Theophylline, diclofenac sodium, amoxicillin trihydrate, and salicylic acid…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Principles of Surface Physics

Friedhelm Bechstedt2003-10-01Materials Today

Friedhelm Bechstedt Springer-Verlag (2003), 346 pp. ISBN: 3-540-00635-4 $89.95 / $56 / €79.95

Surface Modification and Superhydrophobicity

Dispersion and Solubilization of Carbon Nanotubes

Kefu Fu、Ya‐Ping Sun2003-10-01Journal of Nanoscience and Nanotechnology

Carbon nanotubes are generally insoluble in any solvents, resulting in their poor processability for many proposed potential applications. Several strategies have been developed to introduce carbon nanotubes into solvent systems, including dispersion and suspension under special experimental conditions and the chemica…

Carbon Nanotubes in CompositesZeolite Catalysis and SynthesisNanotechnology research and applications

Comparison of Laboratory Methodologies to Evaluate Corrosion Inhibitors for Oil and Gas Pipelines

Sankara Papavinasam、R. Winston Revie、Michael Attard 等 5 位作者2003-10-01CORROSION

Experiments were carried out using a loop in three fields (gassy-oil, oily-gas, and oil-transmission pipes) under 17 operating conditions, using six inhibitors (three continuous and three batch). Laboratory experiments were carried out under field conditions using the same inhibitors at the same concentrations. Four t…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsStructural Integrity and Reliability Analysis

(Bi 1/2 Na 1/2 )TiO 3 –Ba(Cu 1/2 W 1/2 )O 3 Lead‐Free Piezoelectric Ceramics

Xiaoxing Wang、H. L. W. Chan、C. L. Choy2003-10-01Journal of the American Ceramic Society

(Bi 1/2 Na 1/2 )TiO 3 with 0–6 mol% Ba(Cu 1/2 W 1/2 )O 3 (BNT‐BCW), a new member of the BNT‐based group, has been prepared following the conventional mixed oxide route. The compacted bodies were sintered at 1130°C for 2 h to get dense ceramics. The addition of BCW into BNT ceramics facilitated the poling process becau…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Effect of Ultrasound on Adsorption and Desorption Processes

Marc Breitbach、Dieter Bathen、H. Schmidt‐Traub2003-10-01Industrial & Engineering Chemistry Research

The following paper is aimed at finding the effects of ultrasound on adsorption/desorption processes. Experiments concerning the ultrasonic power input indicate that particles absorb ultrasonic energy effectively if they are in resonance with the ultrasound. The ultrasonic energy is dissipated into heat. Hence, desorp…

Ultrasound and Cavitation Phenomenananoparticles nucleation surface interactionsIndustrial Gas Emission Control

Absorption and Emission Spectra of Ce3+ in Elpasolite Lattices

Peter A. Tanner、Chris S. K. Mak、Norman M. Edelstein 等 8 位作者2003-10-01Journal of the American Chemical Society

The experimental determination of the electronic energy levels for Ce(3+) in some chloroelpasolite hosts for both the ground 4f(1) and the excited 5d(1) configurations is described. High-resolution f-f absorption and f-(2)T(2g) d absorption and emission spectra have been recorded at low temperatures for Ce(3+) diluted…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesRadioactive element chemistry and processing

Controlling molecular conformation of regenerated wild silk fibroin by aqueous ethanol treatment

Mingzhong Li、Tao Wei、Shigenori Kuga 等 4 位作者2003-10-01Polymers for Advanced Technologies

Abstract Regenerated Antheraea pernyi silk fibroin film was prepared by dissolution of native silk fiber in aqueous lithium thiocyanate. The influence of aqueous ethanol treatment of the dried regenerated film on molecular conformation was studied by X‐ray diffraction, infrared spectroscopy, differential scanning calo…

RNA Interference and Gene DeliveryCell Adhesion Molecules ResearchSilk-based biomaterials and applications

Improved Efficacy of Stem Cell Labeling for Magnetic Resonance Imaging Studies by the Use of Cationic Liposomes

Ewout J. van den Bos、Anja Wagner、Heiko Mahrholdt 等 8 位作者2003-10-01Cell Transplantation

Labeling stem cells with FDA-approved superparamagnetic iron oxide particles makes it possible to track cells in vivo with magnetic resonance imaging (MRI), but high intracellular levels of iron can cause free radical formation and cytotoxicity. We hypothesized that the use of cationic liposomes would increase labelin…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryMicrofluidic and Bio-sensing Technologies

A Covalent Tetrathiafulvalene–Tetracyanoquinodimethane Diad: Extremely Low HOMO–LUMO Gap, Thermoexcited Electron Transfer, and High‐Quality Langmuir–Blodgett Films

Dmitrii F. Perepichka、Martin R. Bryce、Christopher Pearson 等 6 位作者2003-10-01Angewandte Chemie International Edition

Nearly 30 years after theoretical prediction, a stable and well-characterized compound that covalently links tetrathiafulvalene and tetracyanoquinodimethane fragments has been synthesized (1, see scheme). The extremely low HOMO–LUMO gap of 1 (0.17 eV) allows the first observation of thermoexcited electron transfer in…

Perovskite Materials and ApplicationsPorphyrin and Phthalocyanine ChemistryOrganic and Molecular Conductors Research

Computation of very fast transient overvoltages in transformer windings

Marjan Popov、L. van der Sluis、G.C. Paap 等 4 位作者2003-10-01IEEE Transactions on Power Delivery

The paper deals with the computation of very fast transient overvoltages (VFTOs) in transformer windings. For this purpose, an algorithm is developed. The applied algorithm uses a hybrid model which is a combination of the multi-conductor transmission line model (MTLM) and the single-transmission line model (STLM). By…

Lightning and Electromagnetic PhenomenaMagnetic Properties and ApplicationsElectromagnetic Simulation and Numerical Methods

Fracture behavior of core‐shell rubber–modified clay‐epoxy nanocomposites

K. T. Gam、Masahiro Miyamoto、Riichi Nishimura 等 4 位作者2003-10-01Polymer Engineering and Science

Abstract Morphology and fracture mechanisms in two nanoclay‐filled epoxy systems were investigated using both microscopy and spectroscopy tools. Clay exfoliation was achieved using a series of sample preparation steps, and confirmed using wide angle X‐ray diffraction (XRD) and transmission electron microscopy (TEM) te…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesTribology and Wear Analysis

Raman spectroscopy of some natural hydrotalcites with sulphate and carbonate in the interlayer

Ray L. Frost、Matt L. Weier、J. Theo Kloprogge2003-10-01Journal of Raman Spectroscopy

Abstract The structures of a series of nickel‐ and magnesium‐based hydrotalcites were explored using Raman microscopy. These natural hydrotalcites are based upon sulphate or carbonate being the counter anion in the interlayer. Variation in the position of the sulphate stretching vibrations occurs and is mineral depend…

Layered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and MaterialsMagnesium Oxide Properties and Applications

Transmission and reflection properties of composite double negative metamaterials in free space

Ekmel Özbay、Koray Aydın、Ertugrul Cubukcu 等 4 位作者2003-10-01IEEE Transactions on Antennas and Propagation

We report free space transmission and the first reflection measurements of a composite double negative (DNG) metamaterial, also known as a left-handed material (LHM). The metamaterial composes of the split-ring-resonators and discontinuous thin wires. Very high transmission values of the metamaterial are observed with…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Comparison of Velocity Profiles for Different Flow Chamber Designs Used in Studies of Microbial Adhesion to Surfaces

Dewi P Bakker、Arjan van der Plaats、G.J. Verkerke 等 5 位作者2003-10-01Applied and Environmental Microbiology

Flow chambers are commonly used to study microbial adhesion to surfaces under environmentally relevant hydrodynamic conditions. The parallel plate flow chamber (PPFC) is the most common design, and mass transport occurs through slow convective diffusion. In this study, we analyzed four different PPFCs to determine whe…

Surface Modification and SuperhydrophobicityMicrofluidic and Bio-sensing TechnologiesInhalation and Respiratory Drug Delivery

The Plumber's Nightmare: 1 A New Morphology in Block Copolymer−Ceramic Nanocomposites and Mesoporous Aluminosilicates

Adam C. Finnefrock、Ralph Ulrich、Gilman E. S. Toombes 等 5 位作者2003-10-01Journal of the American Chemical Society

A novel cubic bicontinuous morphology is found in polymer-ceramic nanocomposites and mesoporous aluminosilicates that are derived by an amphiphilic diblock copolymer, poly(isoprene-b-ethylene oxide) (PI-b-PEO), used as a structure-directing agent for an inorganic aluminosilicate. Small-angle X-ray scattering (SAXS) wa…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisBlock Copolymer Self-Assembly

Generalized constitutive relations for metamaterials based on the quasi-static lorentz theory

Akira Ishimaru、Seungwoo Lee、Yasuo Kuga 等 4 位作者2003-10-01IEEE Transactions on Antennas and Propagation

This paper presents a method of calculating the elements of the generalized matrix representation of the macroscopic constitutive relations for a three-dimensional (3-D) array of non-magnetic inclusions with arbitrary shape. The derivation is based on the quasi-static Lorentz theory and the inclusions are represented…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Preparation of Degradable Porous Structures Based on 1,3-Trimethylene Carbonate and D,L-Lactide (Co)polymers for Heart Tissue Engineering

Ana Paula Pêgo、B. Siebum、Marja J.A. van Luyn 等 7 位作者2003-10-01Tissue Engineering

Biodegradable porous scaffolds for heart tissue engineering were prepared from amorphous elastomeric (co)polymers of 1,3-trimethylene carbonate (TMC) and D,L-lactide (DLLA). Leaching of salt from compression-molded polymer-salt composites allowed the preparation of highly porous structures in a reproducible fashion. B…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine