Materials Literature
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The solubilities of chloroquine diphosphate and 4,7-dichloroquinoline in water, ethanol, tetrahydrofuran, acetone, and acetonitrile were measured over the temperature range of (298.2 to 333.2) K. The solubilities of both analytes in different solvents increase smoothly with temperature. On the basis of the solubility…
Superconductivity in LaNiPO is disrupted by small $(\ensuremath{\sim}5%)$ amounts of nonstoichiometry on the lanthanum site, even though the electronic contribution to the heat capacity increases with increasing nonstoichiometry. All samples also exhibit specific-heat anomalies consistent with the presence of ferromag…
Abstract In this study, a novel flow‐based method is presented to place catalytic nanoparticles into a reactor by sol‐gelation of a porous ceramic consisting of Rh/ceria/zirconia nanoparticles, silica sand, ceramic binder, and a gelation agent. This method allows for the placement of a liquid precursor containing the…
Synchrotron X-ray, neutron powder diffraction, magnetic susceptibility, and electrical resistance measurements were used to investigate the Nd 1− x Ca x FeAsO series. The solubility of calcium is limited to 0 ≤ x ≤ 0.05. Within this interval, the iron arsenide layer contracts linearly in agreement with the hole doping…
Reciprocal space mapping (RSM) of the relaxor ferroelectric 0.91Pb(Zn1/3Nb2/3)O3−0.09PbTiO3 (PZN-9%PT) single crystals has been performed by using high-resolution synchrotron x-ray diffraction as a function of temperature. The PZN–9%PT crystal consists of tetragonal micro/nanotwin domains and undergoes a sequence of r…
Abstract The inhibiting effect of 1‐methyl‐3‐pyridine‐2‐yl‐thiourea (MPT) on the corrosion of stainless steel in 0.5 M H 2 SO 4 solution was investigated using weight loss and potentiostatic polarization techniques. The percentage inhibition efficiencies and surface coverage degrees increased with increasing additive…
An efficient synthesizing procedure of photoluminescent silicon nanocrystals is demonstrated by means of ultrasound assisted electrochemical octyltrichlorosilane reduction that produces octane terminated Si nanocrystals in a single step. The described procedure allows one to make Si nanocrystals with alkyl surface ter…
High-resolution low-frequency Raman scattering measurements from embedded AgAu nanoparticles unveil efficient scattering by harmonics of both the quadrupolar and the spherical modes. Comparing the experimental data with theoretical calculations that account for both the embedding medium and the resonant Raman process…
Abstract Using conventional methods to synthesize magnetic nanoparticles (NPs) with uniform size is a challenging task. Moreover, the degradation of magnetic NPs is an obstacle to practical applications. The fabrication of silica‐shielded magnetite NPs on carbon nitride nanotubes (CNNTs) provides a possible route to o…
Deposition of submonolayer coverages of 3,4,9,10-perylenetetracarboxylic diimide onto NaCl(001) results in the bimodal growth of coexisting square and needle-shaped islands. The epitaxy of each island type was determined from molecular and atomic resolution noncontact atomic force microscopy images. Postdeposition, th…
Polymer electrolyte is an important component in many multilayer devices such as batteries, fuel cells, and electrochromic devices. The effects of polymer electrolyte solidification on the ionic movement and device performance are presented based on near-infrared (IR) (860-2500 nm) electrochromic (EC) devices using th…
Single crystalline ZnO nanowires and nanorods were synthesized by a new sol−gel method carried out through formation of liposome−ZnO nanocomposites with or without hydrothermal reaction, respectively, and they were characterized to be hexagonal wurtzite structure by measurements of XRD patterns and SEM and TEM images.…
Abstract In this study, it was found that images scanned by a non‐contact optical instrument for topographic characterisation based on the principle of chromatic aberration give sufficient information to know the exact location of soil release polymer (SRP) deposition over fabrics. Through the comparison of reflected…
Abstract A facile approach for synthesis of hyperbranched polycarbosilane from AB 2 monomer via UV‐activated hydrosilylation is presented in this communication. The polymerization process was monitored using real‐time FTIR spectroscopy and the resulting hyperbranched polycarbosilanes were characterized using 1 H‐NMR,…
Micro-structures that mimic the extracellular substratum promote cell growth and differentiation, while the cellular reaction to a nanostructure is poorly defined. To evaluate the cellular response to a nanoscaled surface, NIH 3T3 cells were grown on nanodot arrays with dot diameters ranging from 10 to 200 nm. The nan…
This study discusses the photoalignment effect in a liquid-crystal (LC) film that is doped with nanoparticles and azo-dye. The vertical alignment induced by nanoparticles of polyhedral oligomeric silsesquioxanes can be changed into homogeneous alignment by the absorption of photoexcited azo-dye. An electrically tunabl…
We report the incorporation of various inorganic nanoparticles (NPs) (PbS, LaOF, LaF(3), and TiO(2), each capped by oleic acid, and CdSe/ZnS core/shell QDs capped by trioctylphosphine oxide) into vesicles (d = 70-150 nm) formed by a sample of poly(styrene-b-acrylic acid) (PS(404)-b-PAA(62), where the subscripts refer…
Structural, magnetic, and magnetotransport behaviors of ${\text{Fe}}_{2}{\text{V}}_{1\ensuremath{-}x}{\text{Cr}}_{x}\text{Al}$ Heusler-type alloys have been investigated in the present work. From the detailed analysis of data it is observed that increasing Cr content promotes site disorder of Fe and Al, which in turn…
Abstract Reaction of a rigid conjugated clamp‐like multi‐pyridineligand N , N ′‐bis(pyridin‐3‐yl)‐2,6‐pyridinedicarboxamide (H 2 L) with CuSO 4 · 5H 2 O or Cu(OAc) 2 resulted in the formation of two high‐nuclearity, discrete molecular copper(II) complexes, namely [Cu 10 (H 2 L) 5 (SO 4 ) 8 (μ 3 ‐OH) 4 (H 2 O) 2 ] · 4C…
Abstract The effect of microstructure modifiers, Sn and Ag, on the corrosion rate of commercial Pb–Ca alloy in H 2 SO 4 electrolyte was investigated by the potentiodynamic polarization and by the weight loss corrosion rate measurement at the open circuit potential. The effect of microstructure modification of the Pb–C…