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A highly stable sodium solid-state electrolyte based on a dodeca/deca-borate equimolar mixture

Léo Duchêne、Ruben‐Simon Kühnel、Daniel Rentsch 等 6 位作者2017-01-01Chemical Communications

at 20 °C, excellent thermal stability up to 300 °C, and a large electrochemical stability window of 3 V including stability towards sodium metal anodes, all essential prerequisites for a stable room-temperature 3 V all-solid-state sodium-ion battery.

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Long wavelength excitable near-infrared fluorescent nanoparticles with aggregation-induced emission characteristics for image-guided tumor resection

Bin Liu、Chao Chen、Shenglu Ji 等 7 位作者2017-01-01Chemical Science

toxicity results demonstrate that the synthesized AIE NPs are biocompatible. Finally, the synthesized AIE NPs have been successfully used for image-guided tumor resection with a high tumor-to-normal tissue signal ratio of 7.2.

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsNanocluster Synthesis and Applications

High dielectric constant conjugated materials for organic photovoltaics

Jeroen Brebels、Jean Manca、Laurence Lutsen 等 5 位作者2017-01-01Journal of Materials Chemistry A

Efforts to increase the relative permittivities of organic semiconducting materials and their effect on organic solar cell performance are evaluated.

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Honey Mediated Green Synthesis of Nanoparticles: New Era of Safe Nanotechnology

Eranga R. Balasooriya、Chanika D. Jayasinghe、Uthpala A. Jayawardena 等 6 位作者2017-01-01Journal of Nanomaterials

With the advent of nanotechnology, many related industries rapidly developed over the recent past. Generally, top-down and bottom-up approaches are the two major processes used to synthesize nanoparticles; most of these require high temperatures, vacuum conditions, and harsh/toxic chemicals. As a consequence, adverse…

Nanoparticles: synthesis and applicationsBee Products Chemical AnalysisLaser-Ablation Synthesis of Nanoparticles

Single-electrode triboelectric nanogenerators based on sponge-like porous PTFE thin films for mechanical energy harvesting and self-powered electronics

Meng Wang、Nan Zhang、Yingjie Tang 等 10 位作者2017-01-01Journal of Materials Chemistry A

A single-electrode triboelectric nanogenerator (S-TENG) based on sponge-like porous polytetrafluoroethylene (PTFE) thin films was developed.

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Kinetically controlled synthesis of two-dimensional Zr/Hf metal–organic framework nanosheets via a modulated hydrothermal approach

Zhigang Hu、E.M. Mahdi、Yongwu Peng 等 9 位作者2017-01-01Journal of Materials Chemistry A

We describe a surfactant-free bottom-up synthesis of 2D stable MOF nanosheets, NUS-8(Zr or Hf), via the modulated hydrothermal (MHT) approach. These 2D NUS-8 nanosheets demonstrate several prevailing advantages including superior chemical/thermal stabilities and enzyme-specific catalytic activities toward thioether ox…

Metal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMXene and MAX Phase Materials

Graphene oxide/core–shell structured metal–organic framework nano-sandwiches and their derived cobalt/N-doped carbon nanosheets for oxygen reduction reactions

Jing Wei、Yaoxin Hu、Yan Liang 等 9 位作者2017-01-01Journal of Materials Chemistry A

A metal–organic framework (MOF) seed-mediated deposition route is developed to synthesize graphene oxide/core–shell structured MOF nano-sandwiches.

Electrocatalysts for Energy ConversionMetal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials Science

Chemical Weathering of Layered Ni-Rich Oxide Electrode Materials: Evidence for Cation Exchange

Ilya A. Shkrob、James A. Gilbert、Patrick J. Phillips 等 7 位作者2017-01-01Journal of The Electrochemical Society

Lithiated ternary oxides containing nickel, cobalt, and manganese are intercalation compounds that are used as positive electrodes in high-energy lithium-ion batteries. These oxides undergo changes, when they are stored in humid air or exposed to moisture, that adversely affect their electrochemical performance. There…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

MnO 2 /MnCo 2 O 4 /Ni heterostructure with quadruple hierarchy: a bifunctional electrode architecture for overall urea oxidation

Changlong Xiao、Shu-Ni Li、Xinyi Zhang 等 4 位作者2017-01-01Journal of Materials Chemistry A

A bifunctional core–shell structured MnO 2 /MnCo 2 O 4 /Ni electrode with quadruple-hierarchy has been developed for highly efficient overall urea electrolysis.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Halogen bonding, chalcogen bonding, pnictogen bonding, tetrel bonding: origins, current status and discussion

Lee Brammer2017-01-01Faraday Discussions

The role of the closing lecture in a Faraday Discussion is to summarise the contributions made to the Discussion over the course of the meeting and in so doing capture the main themes that have arisen. This article is based upon my Closing Remarks Lecture at the 203 rd Faraday Discussion meeting on Halogen Bonding in…

Crystallography and molecular interactionsCrystallization and Solubility StudiesChemical Thermodynamics and Molecular Structure

Multi-responsive actuators based on a graphene oxide composite: intelligent robot and bioinspired applications

Luzhuo Chen、Mingcen Weng、Peidi Zhou 等 6 位作者2017-01-01Nanoscale

when driven by near infrared (NIR) light. The great actuation outperforms most other carbon-based actuators. Then, an intelligent robot based on the GO/BOPP composite is fabricated, which can switch between the protection mode and weightlifting mode with different external stimuli. Inspired from plant tendrils, a bioi…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics

Two-dimensional nanomaterials for photocatalytic CO 2 reduction to solar fuels

Yong Chen、Gan Jia、Yingfei Hu 等 7 位作者2017-01-01Sustainable Energy & Fuels

In this study, we summarize a series of typical 2D nanomaterials for photocatalytic CO 2 conversion. Furthermore, based on the characteristics of 2D materials and the current status of research on photocatalytic CO 2 reduction, the challenges and opportunities of 2D materials as prospective photocatalysts for CO 2 red…

Advanced Photocatalysis TechniquesCO2 Reduction Techniques and CatalystsCovalent Organic Framework Applications

Nematic liquid crystal materials as a morphology regulator for ternary small molecule solar cells with power conversion efficiency exceeding 10%

Miao Zhang、Fujun Zhang、Qiaoshi An 等 8 位作者2017-01-01Journal of Materials Chemistry A

Highly efficient ternary SMSCs with a PCE of 10.05% are reported by employing the nematic liquid crystal small molecule BTR as the second donor and morphology regulator.

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsPorphyrin and Phthalocyanine Chemistry

Do grain boundaries dominate non-radiative recombination in CH 3 NH 3 PbI 3 perovskite thin films?

Mengjin Yang、Yining Zeng、Zhen Li 等 7 位作者2017-01-01Physical Chemistry Chemical Physics

We examine grain boundaries (GBs) with respect to non-GB regions in high-quality perovskite films using fluorescence-lifetime imaging. We show that recombination happens in the non-GB regions and that GBs are not transparent to photogenerated carriers.

Perovskite Materials and ApplicationsChalcogenide Semiconductor Thin FilmsSolid-state spectroscopy and crystallography

One-pass selective conversion of syngas to para -xylene

Peipei Zhang、Li Tan、Guohui Yang 等 4 位作者2017-01-01Chemical Science

We presented a promising hybrid catalyst, named Cr/Zn–Zn/Z5@S1, to effectively realize the one-pass selective conversion of syngas to para -xylene.

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysts for Methane Reforming

Hollowing out MOFs: hierarchical micro- and mesoporous MOFs with tailorable porosity via selective acid etching

Jaehyoung Koo、In‐Chul Hwang、Xiujun Yu 等 6 位作者2017-01-01Chemical Science

a selective acid etching process. The process is controlled by the size-selective diffusion of acid molecules through the MOF windows. This method enables the fine-tuning of the porosity of hierarchical MOFs, allowing for the generation of well-defined mesopores with high mesopore volume. Because of the size-selective…

Metal-Organic Frameworks: Synthesis and ApplicationsNanoplatforms for cancer theranosticsMXene and MAX Phase Materials