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The staurolite enigma solved

Mohamed Amine Marzouki、B. Souvignier、M. Nespolo2014-05-16Acta Crystallographica Section A Foundations and Advances

Staurolite has been long considered an enigma because of its remarkable pseudosymmetry and the frequent twinning. Staurolite gives two twins whose occurrence frequency seems to contradict the condition of lattice restoration requested by the reticular theory of twinning, in that the more frequent one (Saint Andrews cr…

Crystal Structures and PropertiesClay minerals and soil interactionsMineralogy and Gemology Studies

Charged Dendrimers in Trivalent Salt Solutions under the Action of DC Electric Fields

Ashok Kumar Das、Pai‐Yi Hsiao2014-05-16The Journal of Physical Chemistry B

The structural properties and electrophoretic mobility of charged dendrimers in 3:1 electrolyte solutions subjected to direct current electric fields are studied using molecular dynamics simulations. The simulated dendrimer size is studied in zero fields and found to scale as R(g) ∼ N(0.29). The dendrimers exhibit sha…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresDendrimers and Hyperbranched Polymers

Methods for improving n-type photoconductivity of electrodeposited Cu2O thin films

K.D.R.N. Kalubowila、L.K.A.D.D.S. Gunawardhana、R.P. Wijesundera 等 4 位作者2014-05-16Semiconductor Science and Technology

Electrodeposition technique is very useful for depositing n-type Cu 2 O thin films on various substrates. However, most of the reported n-type Cu 2 O thin film electrodes exhibit not only n-type photoactivity but also p-type photoactivity in photoelectrochemical cells. In this study, current–voltage characteristics an…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Half-metallicity in graphitic C3N4 nanoribbons: An ab initio study

Jialing Zhang、Xue Gong、Bo Xu 等 6 位作者2014-05-16physica status solidi (b)

The stability, the electronic and the magnetic properties of the hydrogen-terminated zigzag graphitic C3N4 nanoribbons (ZCNNRs) were investigated by using first-principles computations. The semiconductor to half-metal transition could be realized by controlling the hydrogen content of the environment, which is indepen…

Advancements in Battery MaterialsGraphene research and applications2D Materials and Applications

Isothermal Cold Crystallization and Melting Behaviors of Poly(lactic acid)/Epoxy Vinyl Polyhedral Oligomeric Silsesquioxanes Nanocomposites

Tao Guo、Biaobing Wang2014-05-16Polymer-Plastics Technology and Engineering

Poly(l-lactic acid) (PLA)/epoxy vinyl polyhedral oligomeric silsesquioxane (EP-POSS) nanocomposites were prepared via melt blending. The isothermal cold crystallization and melting behavors of pure PLA and its nanocomposites were investigated using differential scanning calorimetry (DSC). The crystal growth model of P…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisSilicone and Siloxane Chemistry

Electronic structure of V2O3thin film prepared by RF magnetron sputtering using oxygen radical and V-metal

Yuichi Shimazu、Teppei Okumura、Atsushi Shimada 等 8 位作者2014-05-16Japanese Journal of Applied Physics

We have prepared V 2 O 3 thin films on Al 2 O 3 (0001) substrate by RF magnetron sputtering using oxygen radical and V-metal target, and studied their electronic structures by X-ray absorption spectroscopy (XAS) and X-ray photoemission spectroscopy (XPS). The as-deposited V 2 O 3 thin films deposited at 600 °C exhibit…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsElectronic and Structural Properties of Oxides

Stepwise angular spectrum method for curved surface diffraction

Chi-Young Hwang、Seungtaik Oh、Il-Kwon Jeong 等 4 位作者2014-05-16Optics Express

We present a method to calculate wave propagation between arbitrary curved surfaces using a staircase approximation approach. The entire curved surface is divided into multiple subregions and each curved subregion is approximated by a piecewise flat subplane allowing the application of conventional diffraction theory.…

Photonic Crystals and ApplicationsAdvanced Optical Imaging TechnologiesOptical Coatings and Gratings

Enhancing the Properties of Ti6Al4V as a Biomedical Material: A Review

V.E. Annamalai、S. Kavitha、Sarah Ann Ramji2014-05-16The Open Materials Science Journal

The alloy Ti 6 Al 4 V has evolved as a good biomedical material, by virtue of its bio-compatibility. In order to make implants out of this material, it has to be shaped and processed. Shaping this material by conventional manufacturing methods like machining, welding and brazing presents a huge challenge. This challen…

Bone Tissue Engineering MaterialsAdditive Manufacturing Materials and ProcessesTitanium Alloys Microstructure and Properties

In situ detection of salicylic acid binding sites in plant tissues

Jingwen Liu、Dayi Deng、Ying Yu 等 8 位作者2014-05-16Luminescence

The determination of hormone-binding sites in plants is essential in understanding the mechanisms behind hormone function. Salicylic acid (SA) is an important plant hormone that regulates responses to biotic and abiotic stresses. In order to label SA-binding sites in plant tissues, a quantum dots (QDs) probe functiona…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresPineapple and bromelain studies

Synthesis and thermal stability properties of boron‐doped silicone resin

Zhifeng Hao、Jin Zhang、Yahong Wu 等 5 位作者2014-05-16Journal of Applied Polymer Science

ABSTRACT In this article, a novel boron‐doped silicone resin (BSR) was synthesized by hydrolysis‐polycondensation method, with propyl‐triethoxysilane (PTES), dimethyl‐diethoxysilane (DMDES), and boric acid (BA) as starting materials, using absolute ethyl alcohol as solvent and hydrochloric acid as catalyst. The struct…

Advanced ceramic materials synthesisSynthesis and properties of polymersSilicone and Siloxane Chemistry

The effect of deposition energy of energetic atoms on the growth and structure of ultrathin amorphous carbon films studied by molecular dynamics simulations

N Wang、K. Komvopoulos2014-05-16Journal of Physics D Applied Physics

The growth and structure of ultrathin amorphous carbon films was investigated by molecular dynamics simulations. The second-generation reactive-empirical-bond-order potential was used to model atomic interactions. Films with different structures were simulated by varying the deposition energy of carbon atoms in the ra…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Electrical and Thermoelectric Properties of Functionalized Multiwalled Carbon Nanotube/Polyaniline Composites Prepared by Different Methods

A Sobha、Sunil K. Narayanankutty2014-05-16IEEE Transactions on Nanotechnology

Nanocomposites consisting of functionalized multiwalled carbon nanotubes and polyaniline (PANI) were prepared by traditional in-situ polymerization and dynamic interfacial polymerization methods. Morphological and structural analysis showed that synthesis by interfacial polymerization resulted in a well-ordered compos…

Advanced Thermoelectric Materials and DevicesConducting polymers and applicationsThermal properties of materials

Influence of a Nanometric Al2O3 Interlayer on the Thermal Conductance of an Al/(Si, Diamond) Interface

Christian Monachon、L. Weber2014-05-16Advanced Engineering Materials

Abstract The effect of an Al 2 O 3 interlayer on the thermal conductance of metal (Al)/non‐metal (diamond and silicon) interfaces is investigated using Time Domain ThermoReflectance (TDTR). Interlayers between 1.7 and 20 nm are deposited on oxygen‐terminated diamond and hydrogen‐terminated silicon substrates using ato…

Semiconductor materials and devicesThermal properties of materialsSemiconductor materials and interfaces

Theory of carrier transport in graphene double-layer structure with carrier imbalance

Kazuhiro Hosono、Katsunori Wakabayashi2014-05-16Japanese Journal of Applied Physics

The carrier mobility of a graphene double-layer system is evaluated on the basis of the Boltzmann transport theory. In this system, two graphene layers are separated by a dielectric barrier layer. We focus on the cases in which there is carrier imbalance between the two layers. It is found that the mobility can be imp…

Graphene research and applicationsThermal properties of materialsAdvanced Physical and Chemical Molecular Interactions

Interlayer Interaction in the UV Irradiated Defect Formation of Graphene

Gaku Imamura、Koichiro Saiki2014-05-16The Journal of Physical Chemistry C

We have investigated the UV-light-induced defect formation in single- and multilayer graphenes on a SiO 2 (300 nm)/Si substrate. Remarkable selectivity for the number of layers was observed; only a single layer graphene is damaged while a multilayer graphene is stable against UV irradiation. We also performed UV irrad…

Carbon Nanotubes in CompositesGraphene research and applicationsGraphene and Nanomaterials Applications

Characterization and cancer cell targeted imaging properties of human antivascular endothelial growth factor monoclonal antibody conjugated CdTe/ZnS quantum dots

Lili Pang、Jian Xu、Chang Shu 等 7 位作者2014-05-16Luminescence

High luminescence quantum yield water-soluble CdTe/ZnS core/shell quantum dots (QDs) stabilized with thioglycolic acid were synthesized. QDs were chemically coupled to fully humanized antivascular endothelial growth factor165 monoclonal antibodies to produce fluorescent probes. These probes can be used to assay the bi…

Quantum Dots Synthesis And PropertiesNanoplatforms for cancer theranosticsNanocluster Synthesis and Applications

A Systematic Design Method for CRLH Periodic Structures in the Microwave to Millimeter-Wave Range

Tomáš Zvolenský、Juha Ala‐Laurinaho、Constantin Simovski 等 4 位作者2014-05-16IEEE Transactions on Antennas and Propagation

Bloch analysis in conjunction with a full-wave simulation is used in order to design a composite right/left-handed (CRLH) transmission line (TL). We analyze the parasitic components introduced by loading elements and inter-cell coupling, and present details to the compensation required in order to maintain the balance…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Structure of Single‐Wall Carbon Nanotubes: A Graphene Helix

Jae‐Kap Lee、Sohyung Lee、Jin-Gyu Kim 等 8 位作者2014-05-16Small

Evidence is presented in this paper that certain single-wall carbon nanotubes are not seamless tubes, but rather adopt a graphene helix resulting from the spiral growth of a nano-graphene ribbon. The residual traces of the helices are confirmed by high-resolution transmission electron microscopy and atomic force micro…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

The unusually highTcin rare-earth-doped single crystalline CaFe2As2

Fengyan Wei、Bing Lv、Liangzi Deng 等 6 位作者2014-05-16The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

In rare-earth-doped single crystalline CaFe2As2, the mysterious small volume fraction which superconducts up to 49 K, much higher than the bulk Tc ~ 30 s K, has prompted a long search for a hidden variable that could enhance the Tc by more than 30% in iron-based superconductors of the same structure. Here we report a…

Corporate Taxation and AvoidanceIron-based superconductors research

Manufacture and Characterization of Biodegradable Nanocomposites Based on Nanoscale MgAl-Layered Double Hydroxide Modified withN,N′-(Pyromellitoyl)-bis-L-Isoleucine Diacid and Poly(vinyl alcohol)

Shadpour Mallakpour、Mohammad Dinari2014-05-16Polymer-Plastics Technology and Engineering

Bionanocomposite films of poly(vinyl alcohol) (PVA) with Mg-Al LDHs were prepared with different compositions by solution-intercalation method. N,N′-(Pyromellitoyl)-bis-L-isoleucine diacid was synthesized and it was used for organo-modification of chiral MgAl-LDH in distilled water. Hybrid films of PVA and modified ch…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesLayered Double Hydroxides Synthesis and Applications