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Stabilization of high oxidation states by strong electron-donating ligands. Crystal structure and properties of tetra-n-butylammonium o-phenylenebis(biuretato)cuprate(III)-chloroform, (n-C4H9)4NCu[o-C6H4(NCONHCONH)2].CHCl3

P. J. M. W. L. BIRKER1977-10-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStabilization of high oxidation states by strong electron-donating ligands. Crystal structure and properties of tetra-n-butylammonium o-phenylenebis(biuretato)cuprate(III)-chloroform, (n-C4H9)4NCu[o-C6H4(NCONHCONH)2].CHCl3Paul J. M. W. L. BirkerCite this: Inorg. Chem. 1977,…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Dislocation damping and hydrogen pinning in austenitic stainless steels

Andrej Atrens、N. F. Fiore、K. Miura1977-10-01Journal of Applied Physics

The room-temperature damping of three Fe-18Cr-Ni alloys was determined as a function of vibrational strain amplitude at 80 kHz. The data are consistent with the Granato-Lücke theory of dislocation damping. Values of Lc (distance between minor pins) measured are consistent with those obtained from a thermodynamic analy…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

Magnetic properties of oxygen-bridged binuclear chromium(III) complexes with 2,2'-bipyridine and 1,10-phenanthroline

Jens Josephsen、Erik B. Pedersen1977-10-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnetic properties of oxygen-bridged binuclear chromium(III) complexes with 2,2'-bipyridine and 1,10-phenanthrolineJens. Josephsen and Erik. PedersenCite this: Inorg. Chem. 1977, 16, 10, 2534–2538Publication Date (Print):October 1, 1977Publication History Published online1…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Ballistics of Transversely Impacted Fibers

David Roylance1977-10-01Textile Research Journal

The rate-independent theory of transverse impact of textile fibers is reviewed and cast in a form that provides convenient preliminary guidance to designers of impact-resistant textile structures. It is shown that energy-absorption rate increases monotonically with fiber modulus, but that decreased ductility at high m…

Mechanical Behavior of CompositesPolymer crystallization and propertiesTextile materials and evaluations

The physical metallurgy of superalloys and titanium alloys

C. Hammond、Jack Nutting1977-10-01Metal Science

The microstructures which may be obtained in superalloys and titanium alloys as a function of alloy chemistry and heat treatment and the contributions of the various phases to tensile, creep, fatigue, and fracture strength are described. The ways in which thermomechanical forming processes can affect the microstructur…

High Temperature Alloys and CreepIntermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and Properties

Scan Electron Micrographs of Kaolins Collected from Diverse Environments of Origin—IV. Georgia Kaolin and Kaolinizing Source Rocks

Walter Keller1977-10-01Clays and Clay Minerals

Abstract Scan electron micrographs (SEMs), are shown of three representative types of Georgia kaolin: ‘soft’, Cretaceous-age clay; ‘hard’, fine-grained clay; and ‘flint kaolin’. Sparta Granite and a thick deposit of its overlying saprolite are taken to serve as examples of probable source rock for Georgia kaolin. SEMs…

Soil and Unsaturated FlowClay minerals and soil interactionsGeochemistry and Geologic Mapping

Textile Yarns: Technology, Structure and Applications

Bhuvenesh C. Goswami1977-10-01Medical Entomology and Zoology

This material, designed as a textbook, is intended for scientists, engineers, and students of textile technology. Chapters: classification of yarns; raw materials; yarn structure; yarn specifications; Mist in yarns; mechanical properties of yarns; uniformity characteristics of yarns; yarns structure in relation to the…

Textile materials and evaluations

Food webs and the dimensionality of trophic niche space

Joel E. Cohen1977-10-01Proceedings of the National Academy of Sciences

If the trophic niche of a kind of organism is a connected region in niche space, then it is possible for trophic niche overlaps to be described in a one-dimensional niche space if and only if the trophic niche overlap graph is an interval graph. An analysis of 30 food webs, using the combinatorial theory of interval g…

Marine and coastal plant biologyDiatoms and Algae ResearchBiocrusts and Microbial Ecology

Criterion for craze nucleation in polycarbonate

Masaru Ishikawa、Ikuo Narisawa、Hiroyuki Ogawa1977-10-01Journal of Polymer Science Polymer Physics Edition

Abstract Plastic deformation and crazes were initiated in polycarbonate bars containing a round notch by three‐point bending. Morphological observations revealed that internal crazes are nucleated by a hydrostatic stress component caused by plastic constraint ahead of the fully developed plastic deformation zone. The…

Polymer crystallization and propertiesComposite Material MechanicsMaterial Properties and Processing

Shear‐induced β‐form crystallization in isotactic polypropylene

H. Dragaun、H. Hubeny、H. Muschik1977-10-01Journal of Polymer Science Polymer Physics Edition

Abstract Extruded, injection‐molded, unoriented crystallized specimens and capillary rheometer efflux strands of commercially stabilized polypropylene without nucleating agents were examined by optical microscopy and x‐ray diffraction to determine the conditions for β‐form crystallization as a function of the distance…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

High Oxide Ion Conduction in Sintered Oxide of the System Bi2 O 3 ‐ M 2 O 5

Takehiko Takahashi、H. Iwahara、Takao Esaka1977-10-01Journal of The Electrochemical Society

The electrical conduction in the sintered oxides of the systems Bi 2 O 3 ‐ M 2 O 5 ( M = V , Nb , or Ta ) has been investigated by measuring the conductivity and the ion transference number. The face‐centered cubic (fcc) phase in these systems was found to show a high oxide ion conduction, and this highly conductive p…

Advancements in Solid Oxide Fuel CellsGlass properties and applicationsNuclear materials and radiation effects

Molecular charge states and contact charge exchange in polymers

T. J. Fabish、C. B. Duke1977-10-01Journal of Applied Physics

Observation of a new phenomenon, the reversible change in sign of charge transferred to a polymer upon sequential contacts with a series of metals, is reported. This observation is interpreted using a model which attributes the polymer charges to the occurrence of local intrinsic molecular-ion states. A phenomenologic…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

The mechanism of nucleation for in vitro collagen fibril formation

Wayne D. Comper、Arthur Veis1977-10-01Biopolymers

Abstract The formation of collagen fibrils from soluble monomers and aggregates by thermal gelation at neutral pH can be divided into two distinct stages: a nucleation phase and a growth phase. Turbidity studies of the kinetics of the precipitation reaction show that the lag‐phase time or nucleation reaction time, t ′…

Proteins in Food SystemsDyeing and Modifying Textile FibersCollagen: Extraction and Characterization

Metal-non-metal transition in silver chalcogenides

P. Junod、H. Hediger、B. Kilchör 等 4 位作者1977-10-01Philosophical magazine

The paper reviews the crystallographic, optical, magnetic and transport properties of silver chalcogenides Ag2S and Ag2Se. In the low temperature β-phases, the influence of stoichiometry on the respective magnitude of ionic and electronic conductivities is important. In the disordered high-temperature α-phases, the ch…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

A detailed assignment of the O–H stretching bands of ice I

E. Whalley1977-10-01Canadian Journal of Chemistry

A detailed assignment of the infrared and Raman O–H stretching bands of disordered ice Ih and Ic is proposed. It is based on the assumptions that the spectra of disordered ice Ic are closely related to those of ordered ice Ic, and that the spectra of the as yet unrealized ordered ice Ic can be predicted from the spect…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSpectroscopy and Quantum Chemical Studies

Dimensions, Birefringences, and Force-Elongation Behavior of Major and Minor Ampullate Silk Fibers from Orb-Web-Spinning Spiders—The Effects of Wetting on these Properties

Robert W. Work1977-10-01Textile Research Journal

The effects of wetting by water were determined on the dimensions, birefringences, and force-elongation behavior of major and minor ampullate silk fibers from Araneus diadematus Clerck, and major only from Araneus sericatus Clerck and Araneus gemma (McCook) (all family Araneidae). The values obtained at room condition…

Adhesion, Friction, and Surface InteractionsSilk-based biomaterials and applicationsCollagen: Extraction and Characterization

Grating efficiency theory as it applies to blazed and holographic gratings

E. G. Loewen、M. Nevière、D. Maystre1977-10-01Applied Optics

Recently developed rigorous theories have been used to investigate the diffraction efficiency behavior of both blazed and holographic gratings. In order to assist designers of spectrometric systems we have covered a complete range of blaze angles for triangular grooves and modulations for sinusoidal groove shape in fi…

Photonic and Optical DevicesPhotorefractive and Nonlinear OpticsOptical Coatings and Gratings

The physics of zinc oxide varistors

P. R. Emtage1977-10-01Journal of Applied Physics

This paper presents a physical description of the action of ZnO varistors, which are complex ceramic bodies of ZnO grains sintered in an oxide flux; their conductivity is very low at low voltage, but becomes high after a certain breakdown voltage is reached. It is found that depletion layers in the ZnO adjacent to the…

ZnO doping and propertiesSolidification and crystal growth phenomenaCharacterization and Applications of Magnetic Nanoparticles

Ion Thermochemistry and Solvation From Gas Phase Ion Equilibria

P. Kebarle1977-10-01Annual Review of Physical Chemistry

Machine learning (ML) is transforming all areas of science. The complex and time-consuming calculations in molecular simulations are particularly suitable for an ML revolution and have already been profoundly affected by the application of existing ML ...Read More

Analytical chemistry methods developmentMass Spectrometry Techniques and ApplicationsThermal and Kinetic Analysis

The Synergistic Effect of Ni and Fe on the Sea Water Corrosion of Copper Alloys

K. D. Efird1977-10-01CORROSION

Sea water corrosion studies on Cu-Ni-Fe alloys ranging in nickel content from 0 to 30% and iron content from <0.05 to 2% have demonstrated a synergistic effect between nickel and iron in these copper alloys. This effect is apparent in corrosion data such as low velocity sea water and jet impingement tests, as w…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques