Materials Literature
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Blocked isocyanates were successfully encapsulated into polystyrene and hydroxyl and amine functionalized polymeric nanospheres via emulsion polymerization. The nanocapsules were characterized via Fourier transform infrared spectroscopy, differential scanning calorimetry and transmission electronic microscopy. The blo…
We developed a novel and convenient method for the synthesis of a potentially safe non-viral gene delivery vehicle based on the cationic block copolymer of spermine and aspartic acid (ASSP) and coupled it with polyethylene glycol (PEG). The copolymer ASSP was prepared by direct polycondensation in the ionic liquid, bu…
In order to improve thermo mechanical properties of cured epoxy resin, hydroxyl terminated polyethersulfone (PES) and N,N′-bismaleimido-4,4′-diphenyl methane (BMI) were incorporated to diglycidyl ether of bisphenol A (DGEBA) type epoxy resin and cured with diaminiodiphenylmethane (DDM). The resulting hybrid matrices,…
A new way of improving the heat dissipating ability and PV efficiency of the solar cells by enhancing the thermal conductivity of the rear EVA layer was reported. The thermal conductivity, electrical resistivity, degree of curing of the EVA encapsulating composites and the PV efficiency of the solar cells are investig…
Two different models accounting for the dependences of χ and g interaction parameters on both temperature and composition have been applied to different ternary polymer systems (TPS) solvent(1)/polymer(2)/polymer(3). The analyzed TPS have consisted on ten different polymer mixtures in chloroform as common solvent that…
A heterotropic ternary complex was obtained from a photochromic dithienylethene derivative bearing pyridyl groups (1), a chiral tetrasubstituted ferrocene as a scissoring component bearing two pyridyl and free-base porphyrin groups (3*), and a biaryl derivative as an intermediately bridging component bearing four zinc…
In this report, a polystyrene−ionic liquid (PS-IL) composite nanofiber was successfully produced for the first time by an electrospinning method. The electrospun composite films were characterized by SEM, FTIR, cyclic voltammetry, water contact angle (WCA) measurement, and conductivity measurement. The dimension, morp…
Sorption is a common treatment for removing pollutants from natural environments. Layered double hydroxides (LDHs), which consist of brucite-like positive layers and sodium dodecyl sulfate intercalated with LDH (SDS−LDH), are considered to be potential organic pollutant sorbents. The objectives of this study were (1)…
Bi 5 Ti 3 Fe O 15 bulk ceramic and thin film samples are prepared using the sol-gel method. The dielectric, ferroelectric, and magnetic behaviors of these samples are measured in order to investigate the possible multiferroic effect. The superparamagnetic behavior with dominant antiferromagnetic (AFM) interaction back…
Tumblerlike magnetic/fluorescein isothiocyanate (FITC)-labeled mesoporous silica nanoparticles, Mag-Dye@MSNs, have been developed, which are composed of silica-coated core-shell superparamagnetic iron oxide (SPIO@SiO(2)) nanoparticles co-condensed with FITC-incorporated mesoporous silica. Mag-Dye@MSNs can label human…
BiFeO 3 (BFO) films deposited on SrTiO3 (001) substrates and on LaNiO3-coated SrTiO3 (001) substrates with different annealing ambiences of oxygen and nitrogen were studied by using micro-Raman spectroscopy and x-ray diffraction (XRD). XRD showed that the films are in single-phase with rhombohedral structure. Accordin…
The atomic structures of bare gold clusters provide the foundation to understand the enhanced catalytic properties of supported gold nanoparticles. However, the richness of diverse structures and the strong relativistic effects have posed considerable challenges for a systematic understanding of gold clusters with mor…
The accidental discovery over 300 years ago of the artists' pigment Prussian blue, iron(III) hexacyanoferrate(II), opened up a whole new area of chemistry—that of the cyanide radical. The variable composition of Prussian blue has tantalized chemists, until investigations by X-ray crystallography in the late 20th centu…
We demonstrate the use of a novel design of a photoelectron microscope in combination to an imaging energy filter for momentum resolved photoelectron detection. Together with a time resolved imaging detector, it is possible to combine spatial, momentum, energy, and time resolution of photoelectrons within the same ins…
We study the spin dynamics of a long nanomagnet driven by an electrical current. In the case of only DC current, the spin dynamics has a sophisticated bifurcation diagram of attractors. One type of attractors is a weak chaos. On the other hand, in the case of only AC current, the spin dynamics has a rather simple bifu…
We theoretically show how constant-energy maps of the angle-resolved photoemission intensity can be used to test wave function symmetry in graphene. For monolayer graphene, we demonstrate that the observed anisotropy of angle-resolved photoelectron spectroscopy spectra is a manifestation of what has been recently bran…
Nanocrystalline manganite La0.50Ba0.50MnO3 was synthesized by an optimized sol-gel method. The initial sample was subjected to step-by-step heat treatment under air atmosphere. The ion stoichiometry, the morphology of crystallites of ceramics, and the magnetic properties were studied. It is established that the averag…
Complementary hydrogen bonded cross-linked polymer networks based on two distinct hydrogen bonding recognition motifs have been synthesized by using a combination of ring-opening metathesis polymerization and hydrogen bonding interactions and were subsequently characterized in solution using rheometry. The hydrogen bo…
A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5.acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular pi-pi interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction pl…
This work attempts to detail selected relevant studies on the behaviour of steel in acidic media. Factors affect the inhibition efficiency of the organic compounds in acidic media were discussed; the effect of he structure, the effect of zero-charge potential and the effect of synergistic effect. Different additives o…