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Structural anomalies at the magnetic transition in centrosymmetricBiMnO3

E. Montanari、G. Calestani、L. Righi 等 7 位作者2007-06-28Physical Review B

The structural properties of ${\mathrm{BiMnO}}_{3}$ were determined from neutron powder diffraction data as a function of temperature and magnetic field. The structure at all temperatures was found to be centrosymmetric with space group $C2∕c$, which is incompatible with ferroelectricity. At ${T}_{C}\ensuremath{\simeq…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Structural and Transport Properties of Mixed Phosphotungstic Acid/Phosphomolybdic Acid/SiO2Glass Membranes for H2/O2Fuel Cells

Uma Thanganathan、Masayuki Nogami2007-06-28Chemistry of Materials

The synthesis and characterization of a novel inorganic glass composite membrane consisting of a mixture of phosphotungstic acid and phosphomolybdic acid are reported. Phosphosilicate gels doped with these two proton conducting donor components were derived by a sol−gel method. The influence of the textural properties…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

On the Crucial Role of Wetting in the Preparation of Conductive Polystyrene−Carbon Nanotube Composites

Nadia Grossiord、Hans Miltner、Joachim Loos 等 6 位作者2007-06-28Chemistry of Materials

Polystyrene−single-wall carbon nanotube (PS−SWNT) nanocomposites were prepared by directly mixing aqueous suspensions of exfoliated SWNTs and PS latex particles. After freeze-drying and compression molding, homogeneous polymer films were obtained with well-dispersed carbon nanotubes, as evidenced by scanning electron…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesConducting polymers and applications

Biodegradable double‐layer films based on biological resources: Polyhydroxybutyrate and cellulose

Viviana P. Cyras、Maria S. Commisso、Adriana N. Mauri 等 4 位作者2007-06-28Journal of Applied Polymer Science

Abstract A novel biocomposites double‐layer films using polyhydroxybutyrate (PHB) and cellulose paper were produced. The biocomposites were prepared by the solvent‐casting method (with chloroform). Films of the blends were characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scan…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Morphology of Critical Nuclei in Solid-State Phase Transformations

Lei Zhang、Long‐Qing Chen、Qiang Du2007-06-28Physical Review Letters

Predicting the shape of a critical nucleus in solids has been a long-standing problem in solid-state phase transformations. We show that a diffuse-interface approach together with a minimax algorithm is able to predict the critical nucleus morphology in elastically anisotropic solids without a priori assumptions. We d…

Microstructure and mechanical propertiesSolidification and crystal growth phenomenaComposite Material Mechanics

Different packing of external residues can explain differences in the thermostability of proteins from thermophilic and mesophilic organisms

Anna V. Glyakina、Sergiy O. Garbuzynskiy、Michail Yu. Lobanov 等 4 位作者2007-06-28Bioinformatics

MOTIVATION: Understanding the basis of protein stability in thermophilic organisms raises a general question: what structural properties of proteins are responsible for the higher thermostability of proteins from thermophilic organisms compared to proteins from mesophilic organisms? RESULTS: A unique database of 373 s…

Protein Structure and DynamicsBacteriophages and microbial interactionsEnzyme Structure and Function

Fluorine doping into diamond‐like carbon coatings inhibits protein adsorption and platelet activation

Terumitsu Hasebe、Satoshi Yohena、Aki Kamijo 等 7 位作者2007-06-28Journal of Biomedical Materials Research Part A

The first major event when a medical device comes in contact with blood is the adsorption of plasma proteins. Protein adsorption on the material surface leads to the activation of the blood coagulation cascade and the inflammatory process, which impair the lifetime of the material. Various efforts have been made to mi…

Diamond and Carbon-based Materials ResearchElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Bias Field Effects on Microwave Frequency Behavior of PZT/YIG Magnetoelectric Bilayer

C. Pettiford、Subinay Dasgupta、Jin Lou 等 5 位作者2007-06-28IEEE Transactions on Magnetics

Magnetoelectric behavior of a yttrium iron garnet (YIG)/zirconate titanate (PZT) magnetoelectric bilayer composite was studied over 1-7 GHz under different bias magnetic fields and electric fields by using a broadband air-gap microstrip with the PZT/YIG loaded in the air gap. Electrostatically induced ferrimagnetic re…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMagneto-Optical Properties and Applications

Self-assembly of β-sheet forming peptides into chiral fibrillar aggregates

Giovanni Bellesia、Joan‐Emma Shea2007-06-28The Journal of Chemical Physics

The authors introduce a novel mid-resolution off-lattice coarse-grained model to investigate the self-assembly of beta-sheet forming peptides. The model retains most of the peptide backbone degrees of freedom as well as one interaction center describing the side chains. The peptide consists of a core of alternating hy…

Protein Structure and DynamicsLipid Membrane Structure and BehaviorSupramolecular Self-Assembly in Materials

Effect of the Lattice Crystallinity on the Electron−Phonon Relaxation Rates in Gold Nanoparticles

Wenyu Huang、Wei Qian、Mostafa A. El‐Sayed 等 5 位作者2007-06-28The Journal of Physical Chemistry C

High Resolution Image Download MS PowerPoint Slide In order to study the importance of surface phonons on the electron−phonon relaxation in plasmonic nanoparticles, the effect of size, shape, and materials have recently been studied. Gold and silver nanoparticles have shown no dependence on size and shape while copper…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactions

Nonequilibrium Green’s function method for thermal transport in junctions

Jian‐Sheng Wang、Nan Zeng、Jian Wang 等 4 位作者2007-06-28Physical Review E

We present a detailed treatment of the nonequilibrium Green's function method for thermal transport due to atomic vibrations in nanostructures. Some of the key equations, such as self-energy and conductance with nonlinear effect, are derived. A self-consistent mean-field theory is proposed. Computational procedures ar…

Carbon Nanotubes in CompositesThermal properties of materialsThermal Radiation and Cooling Technologies

Routes to left-handed materials by magnetoelectric couplings

Cheng‐Wei Qiu、Hai‐Ying Yao、Le‐Wei Li 等 5 位作者2007-06-28Physical Review B

Magnetoelectric materials, which couple electric fields with magnetic fields, are intensively studied for physical realization and potential synthesis of left-handed materials (LHM). Both isotropic and anisotropic magnetoelectric materials are the realization of backward waves and/or negative refraction within certain…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsMultiferroics and related materials

Substituent Effect on Formation of Heterometallic Molecular Wheels: Synthesis, Crystal Structure, and Magnetic Properties

Zhong-Hai Ni、Li‐Fang Zhang、V. Tangoulis 等 7 位作者2007-06-28Inorganic Chemistry

The reaction of manganese(III) Schiff bases of the type salen(2-) (N,N'-ethylenebis(salicylideneaminato)) with X-substituted (X = CH(3), Cl) pyridinecarboxamide dicyanoferrite(III) [Fe(X-bpb)(CN)(2)](-) gave rise to a series of cyanide-bridged Mn(6)Fe(6) molecular wheels, [Mn(III)(salen)](6)[Fe(III)(bpmb)(CN)(2)](6) x…

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Elastic relaxation during 2D epitaxial growth: a study of in-plane lattice spacing oscillations

P. Muller、P. Turban、L. Lapena 等 4 位作者2007-06-28arXiv

The purpose of this paper is to report some new experimental and theoretical results about the analysis of in-plane lattice spacing oscillations during two-dimensional (2D) homo and hetero epitaxial growth. The physical origin of these oscillations comes from the finite size of the strained islands. The 2D islands may…

Materials Science

The Origin of Tunneling Anisotropic Magnetoresistance in Break Junctions

J. D. Burton、R. F. Sabirianov、J. P. Velev 等 5 位作者2007-06-28arXiv

First-principles calculations of electron tunneling transport in Ni and Co break junctions reveal strong dependence of the conductance on the magnetization direction, an effect known as tunneling anisotropic magnetoresistance (TAMR). The origin of this phenomenon stems from resonant states localized in the electrodes…

Mesoscale and Nanoscale PhysicsMaterials Science

Density functional calculations on the intricacies of Moiré patterns on graphite

Josep M. Campanera、G. Savini、Irene Suarez‐Martinez 等 4 位作者2007-06-28Physical Review B

Scanning tunneling microscopy (STM) imaging has detected a wealth of puzzling features on the surface of highly oriented pyrolytic graphite, among them, anomalously large superperiodicities, called Moir\'e patterns, caused by the lattice-mismatched top layer of graphite. Exactly, the top graphene layer rotates with re…

Carbon Nanotubes in CompositesGraphene research and applicationsChemical and Physical Properties of Materials

Functionalized Single-Walled Carbon Nanotubes for Carbon Fiber−Epoxy Composites

Elena Bekyarova、Erik T. Thostenson、Aiping Yu 等 7 位作者2007-06-28The Journal of Physical Chemistry C

Functionalized single-walled carbon nanotubes (SWNTs) are explored as nanoreinforcement for carbon fiber/epoxy composites. SWNTs functionalized with carboxylic acid groups (SWNT−COOH) are dispersed in epoxy and are used for infiltration of carbon fabric (CF) by the vacuum-assisted resin transfer molding technique to f…

Carbon Nanotubes in CompositesFiber-reinforced polymer compositesTribology and Wear Analysis

Spin configuration in a frustrated ferromagnetic/antiferromagnetic thin film system

T. K. Yamada、E. Martinez、A. Vega 等 8 位作者2007-06-28arXiv

We have studied the magnetic configuration in ultrathin antiferromagnetic Mn films grown around monoatomic steps on an Fe(001) surface by spin-polarized scanning tunneling microscopy/spectroscopy and ab-initio-parametrized self-consistent real-space tight binding calculations in which the spin quantization axis is ind…

Materials Science

Ordered spin-ice state in the geometrically frustrated metallic-ferromagnet Sm2Mo2O7

Surjeet Singh、R. Suryanarayanan、R. Tackett 等 7 位作者2007-06-28arXiv

The recent discovery of Spin-ice is a spectacular example of non-coplanar spin arrangements that can arise in the pyrochlore A2B2O7 structure. We present magnetic and thermodynamic studies on the metallic-ferromagnet pyrochlore Sm2Mo2O7. Our studies, carried out on oriented crystals, suggest that the Sm spins have an…

Materials ScienceStrongly Correlated Electrons

Surface effects in the Ni 2 p x-ray photoemission spectra of NiO

L. Soriano、I. Preda、J. M. González 等 6 位作者2007-06-28Physical Review B

We report experimental and theoretical evidence of surface effects in the Ni $2p$ x-ray photoemission spectra (XPS) of NiO. The Ni $2{p}_{3∕2}$ surface-enhanced XPS of a NiO sample show a relative enhancement of the intensity of the known satellite at $1.5\phantom{\rule{0.3em}{0ex}}\mathrm{eV}$ higher binding energy f…

Transition Metal Oxide NanomaterialsElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides