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Molecular Aggregation of Acetic Acid in a Carbon Tetrachloride Solution: A Molecular Dynamics Study with a View to Crystal Nucleation

A. Gavezzotti1999-02-01Chemistry - A European Journal

Molecular-crystal precursor states: Molecular dynamics in the nanosecond timescale shows how acetic acid molecules aggregate (see figure for one example) out of a solution in a nonpolar solvent. Is this demixing into a microemulsion the first stage of crystal nucleation?

Surfactants and Colloidal SystemsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Rapid Synthesis of Diaryl Carbazone by N-Bromosuccinimide and Pyridine as the Oxidation System

Yulu Wang、Zhi‐Fang Duan、Lti Shi 等 5 位作者1999-02-01Synthetic Communications

A new and rapid synthetic method of diaryl carbazone (ArN=NCONHNHAr) from aryl substituted carbazide is reported for the first time. Eight of the compounds were prepared by oxidation of aryl substituted carbazide using N-Bromosuccinimide and pyridine as the oxidation system in good yield under mild condition . This me…

Liquid Crystal Research AdvancementsPorphyrin and Phthalocyanine ChemistryAxial and Atropisomeric Chirality Synthesis

Fractal dielectric response of multidomain ferroelectrics from the irreversible thermodynamics standpoint

N. M. Galiyarova1999-02-01Ferroelectrics

The kinetics equations modified by introducing of the fractional derivatives are used for description of the different dielectric spectra and analysis of the relaxation times temperature dependences. The origin of fractal properties is being discussed in relation with scaling and percolation ideas. The temperature dep…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAcoustic Wave Phenomena Research

Optical properties of porous silicon layers processed with a HF:HCI:C2H5OH electrolyte

A. I. Belogorokhov、L. I. Belogorokhova1999-02-01Semiconductors

The properties of porous silicon samples prepared by adding hydrochloric acid to the usual hydrofluoric-acid electrolyte have been studied. These samples exhibit an intense photoluminescence that does not degrade over time and is unaffected by exposure to intense laser illumination. The peak photoluminescence from the…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Liquid crystalline 1,4-disubstituted cyclohexenylene derivatives

V. S. Bezborodov1999-02-01Liquid Crystals

The influence of the positions of the 1,4-cyclohexenylene fragment and its carbon-carbon double bond in the molecular core, on the mesomorphic behaviour and physical properties of 1,4-disubstituted cyclohexenylene derivatives is discussed and rationalized in terms of existing theories.

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Barkhausen effect in stepped motion of a plane domain boundary in gadolinium molybdate

V. Ya. Shur、E. L. Rumyantsev、V. P. Kuminov 等 5 位作者1999-02-01Physics of the Solid State

Barkhausen pulses generated in stepped motion of a single plane domain boundary (PDB) are investigated experimentally in single-crystalline wafers of the extrinsic ferroelastic ferroelectric gadolinium molybdate containing artificial pinning centers of the “field inhomogeneity” type near the edges of the sample. Two s…

Magnetic Properties and ApplicationsElectromagnetic Effects on MaterialsMaterial Properties and Failure Mechanisms

Recent Research on Yarn Hairiness Testing and Reduction: Part - Reduction of Yarn Hairiness

Xungai Wang1999-02-01Research Journal of Textile and Apparel

The first part ofthis series discussed current research on yam hairiness testing [Wang 1998]. In this part of the series, the importance of yam hairiness is outlined first. This is followed by a description of recent research on several novel ways of reducing yam hairiness.

Textile materials and evaluations

Type B Semiconductor Photocatalysis: On the Mechanism of the CdS-Catalyzed Linear Photoaddition of 2,5-Dihydrofuran to Azobenzene

Arne Reinheimer、A. Fernández、Horst Kisch1999-02-01Zeitschrift für Physikalische Chemie

Article Type B Semiconductor Photocatalysis: On the Mechanism of the CdS-Catalyzed Linear Photoaddition of 2,5-Dihydrofuran to Azobenzene was published on February 1, 1999 in the journal Zeitschrift für Physikalische Chemie (volume 213, issue 2).

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Visualization of Simulated Molten-Fuel Behavior in a Pressure Vessel Lower Head Using High-Frame-Rate Neutron Radiography

Hideo Nakamura、Yasuteru Sibamoto、Yoshinari Anoda 等 6 位作者1999-02-01Nuclear Technology

High-frame-rate neutron radiography is used to observe the behavior of a high-temperature (≤773 K) molten Pb-Bi alloy dropped into a vessel that contains water. Experiments are also performed with an empty vessel. Using high-speed cameras combined with image intensifiers and a high-flux neutron source, the interaction…

Heat Transfer and Boiling StudiesNuclear Materials and PropertiesNuclear Physics and Applications

Improved free-air ionization chamber for the measurement of x-rays

Wenzhuo Chen、Shi-Hwa Su、Leanne L. Su 等 4 位作者1999-02-01Metrologia

Based on an original design by F. H. Attix, an improved free-air ionization chamber was constructed at the National Radiation Standard Laboratory of the Institute of Nuclear Energy Research (INER, Taiwan), as the primary standard for x-rays generated at energy levels between 50 keV and 300 keV. Various improvements we…

Radiation Dose and ImagingRadiation Shielding Materials AnalysisAdvanced X-ray and CT Imaging

Colossal Magnetoresistance in Fine Particle of Layered-Perovskite La2—2xCa1+2xMn2O7 (x = 0.3) Synthesized at Low Temperatures

Kaiyou Wang、Wenhai Song、Ting Yu 等 6 位作者1999-02-01physica status solidi (a)

By means of a sol–gel method, we prepare layered-perovskite samples of La2—2xCa1+2xMn2O7 (x = 0.3) at synthesis temperatures from 1000 to 1200 °C. The grain size changes from 20 to 45 nm. A magnetoresistance above 25% at low temperatures is acquired in a field of 0.8 T. We also find that decreasing grain size is deter…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsThermal Expansion and Ionic Conductivity

Durability evaluation of Ni‐Cr‐Mo super alloys in a simulated scrubbed flue gas environment

K. Darowicki、Stefan Krakowiak1999-02-01Anti-Corrosion Methods and Materials

Results of DC electrochemical measurements of four Ni‐base alloys are presented. The tests were conducted in 1 percent sulphuric acid, containing 0.2 percent chlorides at temperature 353K. Gravimetric test, performed in the same conditions, revealed excellent properties of alloy signed A3. Pitting corrosion of alloy A…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Electronic Structure of Platinum-Group Minerals: Prediction of Semiconductor Band Gaps

D. Nguyen-Manh、Petros S. Ntoahae、D. G. Pettifor 等 4 位作者1999-02-01Molecular Simulation

We report first-principle electronic structure calculations of the three representative minerals of the platinum group: cooperite (PtS), braggite (PdPt3S4) and sperrylite (PtAs2) using the Tight-Binding Linear Muffin Tin Orbital (TB-LMTO) technique. We predict non-metallic behaviour for all three minerals with semicon…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesIron-based superconductors research

Smooth and jump-like dynamics of the plane domain wall in gadolinium molybdate

V. Ya. Shur、Е. В. Николаева、E. L. Rumyantsev 等 6 位作者1999-02-01Ferroelectrics

The paper deals with the detail investigation of the smooth motion of the single plane domain wall (PDW) in the vicinity of the initial/steady position and analysis of the mechanisms of Barkhausen noise generation during PDW jump-like motion.

High-pressure geophysics and materialsSolidification and crystal growth phenomenaMagnetic Properties and Applications

On temperature-time correspondence in high-rate deformation of metals

A. A. Gruzdkov、Yu. V. Petrov1999-02-01OpenAlex

Interest in the study of the dynamic properties of materials subjected to high-rate loading has been motivated by two circumstances. First, the design of structures and evaluation of technological processes require a correct consideration of the properties of the material to be used. Second, the study of the macroscop…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

High‐Temperature Creep and Microstructural Evolution of Chemically Vapor‐Deposited Silicon Carbide Fibers

Charles A. Lewinsohn、Lucille A. Giannuzzi、Charles E. Bakis 等 4 位作者1999-02-01Journal of the American Ceramic Society

The creep behavior of three types of silicon carbide fibers that have been fabricated via chemical vapor deposition is described. The fibers exhibit only primary creep over the range of conditions studied (1200°–1400°C, 190–500 MPa). A transmission electron microscopy study of the microstructural development that is i…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Tensile Ductility of Liquid-Phase Sintered β-Silicon Carbide at Elevated Temperature

T. Nagano、Hui Gu、Yutaka Shinoda 等 6 位作者1999-02-01Materials science forum

Nano-grain sized β-SiC was prepared with various additives by hot-pressing in Ar. The relative bulk densities were more than 95 %. As-sintered bodies were composed of equiaxed grains. Amorphous phase existed at grain boundaries in each as-sintered material. Tension tests were performed at the initial strain rates from…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Influence of Preforming on the Final Thickness Distribution of the Superplastically Deformed Domes

Nihat Akkuş、K. Suzuki、Masakazu Kawahara 等 4 位作者1999-02-01Materials science forum

This study reports the influence of preforming on the final thickness distribution of superplastically formed domes. It is very common to see about 50% thickness difference between apex and periphery of domes formed from initially uniform blanks. If the initial shape of the blank is modified properly by preforming, th…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced Surface Polishing Techniques

Polar properties of compatible ferroelastic domain walls

V. Janovec、L. Richterová、J. P[rcirc]ívratská1999-02-01Ferroelectrics

We show that the layer groups, describing the symmetry of compatible (coherent, permissible) ferroelastic domain walls, are polar. From this it follows that all compatible ferroelastic walls in dielectric crystals can be spontaneously polarized. We shortly discuss the feasibility of reversing the spontaneous polarizat…

Photorefractive and Nonlinear OpticsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Luminescence-spectral properties and structure of optical centers in Eu-and Ce-Eu-containing quartz gel-glasses

Г. Е. Малашкевич、A. G. Makhanek、А. В. Семченко 等 6 位作者1999-02-01Physics of the Solid State

Eu-and Ce-Eu-containing quartz glasses obtained by a direct sol-gel-glass transition are investigated. It is discovered that the conversion of a xerogel into a glass leads to lowering of the symmetry of the Eu3+ optical centers from hexagonal to orthorhombic and a many-fold increase in the efficiency of the excitation…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes