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Hydrophobic monolayered nanoflakes of tungsten oxide: coupled exfoliation and fracture in a nonpolar organic medium

Masashi Honda、Yuya Oaki、Hiroaki Imai2015-01-01Chemical Communications

Coupled exfoliation and fracture induced formation of hydrophobic monolayered nanoflakes in a nonpolar organic medium. The hydrophobic monolayered nanoflakes 5-20 nm in lateral size consisted of a tungstate layer with surface modification by stearylammonium ions (C18H37NH3)0.397 H0.603Cs3W11O35·xH2O (x < 0.625).

Advanced Photocatalysis TechniquesPorphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and Applications

Dodenuclear [MnIII8LnIII4] clusters with 2-(hydroxymethyl)pyridine: syntheses, structures, and magnetic properties

Lei Sun、Hui Chen、Chengbing Ma 等 4 位作者2015-01-01Dalton Transactions

A new family of isostructural Mn/Ln dodenuclear clusters: [Mn8Ln4(O)8(hmp)4(O2CPh)12(NO3)4(PhCO2H)(C2H5OH)] [Ln = La (1), Pr (2), Nd (3), Gd (4), Dy(5), hmpH = 2-(hydroxymethyl)pyridine] have been synthesized by the reaction of Mn(NO3)2 and Ln(NO3)3·6H2O with hmpH and benzoic acid as co-ligands. Compounds 1-5 possess…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Microphase separation in thin films of lamellar forming polydisperse di-block copolymers

Rajeev Kumar、Bradley S. Lokitz、Scott Sides 等 9 位作者2015-01-01RSC Advances

Effects of polydispersity in chain lengths on microphase separation in thin films of di-block copolymers are studied using self-consistent field theory (SCFT) and neutron reflectivity experiments.

Rheology and Fluid Dynamics StudiesBlock Copolymer Self-AssemblyFluid Dynamics and Thin Films

Diamond Based Field‐Effect Transistors of Zr Gate with SiNx Dielectric Layers

Wei Wang、Chao Hu、S. Y. Li 等 8 位作者2015-01-01Journal of Nanomaterials

Investigation of Zr‐gate diamond field‐effect transistor with SiN x dielectric layers (SD‐FET) has been carried out. SD‐FET works in normally on depletion mode with p‐type channel, whose sheet carrier density and hole mobility are evaluated to be 2.17 × 10 13 cm −2 and 24.4 cm 2 ·V −1 ·s −1 , respectively. The output…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

High thermal radiation of Ca-doped lanthanum chromite

Yi Lu、Zhenggang Fang、Chunhua Lu 等 7 位作者2015-01-01RSC Advances

The graph describes the preparation process and characterization methods, as well as applications of samples.

Thermal and Kinetic AnalysisNuclear materials and radiation effectsPigment Synthesis and Properties

The template-assisted synthesis of polypyrrole hollow microspheres with a double-shelled structure

Chunyu Niu、Bingfang Zou、Yongqiang Wang 等 6 位作者2015-01-01Chemical Communications

Double-shelled polypyrrole hollow microspheres were synthesized via a novel template-assisted concept, using iron oxide hollow microspheres as both the sacrificial template and initiator in acidic solution.

Supercapacitor Materials and FabricationConducting polymers and applicationsCovalent Organic Framework Applications

Interactions of a zwitterionic thiophene-based conjugated polymer with surfactants

Telma Costa、Diego de Azevedo、Beverly Stewart 等 8 位作者2015-01-01Polymer Chemistry

Structural organization and photoluminescence properties of zwitterionic conjugated polymer–surfactant assemblies depend on specific and non-specific polymer–surfactant interactions within the aggregate.

Surfactants and Colloidal SystemsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Sensing single molecules with carbon–boron-nitride nanotubes

Laith A. Algharagholy、Thomas Pope、Qusiy Al‐Galiby 等 6 位作者2015-01-01Journal of Materials Chemistry C

We investigate the molecular sensing properties of carbon nanotube–boron nitride–carbon nanotube (CNT–BN–CNT) junctions.

Carbon Nanotubes in CompositesGraphene research and applicationsMolecular Junctions and Nanostructures

Ultrathin undoped tetrahedral amorphous carbon films: thickness dependence of the electronic structure and implications for their electrochemical behaviour

Vera Protopopova、Niklas Wester、M. A. Caro 等 7 位作者2015-01-01Physical Chemistry Chemical Physics

In this paper we show that the electronic properties of ultrathin tetrahedral amorphous carbon (ta-C) films are heavily dependent on their thickness. By using scanning tunnelling spectroscopy, Raman spectroscopy, and conductive atomic force microscopy, it was found that a decrease of ta-C thickness from 30 to 7 nm lea…

Graphene research and applicationsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Liquid-crystalline compounds containing both a strong push–pull azo chromophore and a cholesteryl unit as photoresponsive molecular glass materials

Renbo Wei、Zeda Xu、Xiyang Liu 等 5 位作者2015-01-01Journal of Materials Chemistry C

A series of liquid-crystalline (LC) compounds (R-Chol, R: CA, CN and NT), containing both a strong push–pull azo chromophore and a cholesteryl unit, was synthesized as novel molecular glass materials.

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Development of a diffuse reflectance infrared fourier transform spectroscopy (DRIFTS) cell for the in situ analysis of co-electrolysis in a solid oxide cell

Denis Cumming、Christopher Tumilson、S. F. Rebecca Taylor 等 8 位作者2015-01-01Faraday Discussions

Co-electrolysis of carbon dioxide and steam has been shown to be an efficient way to produce syngas, however further optimisation requires detailed understanding of the complex reactions, transport processes and degradation mechanisms occurring in the solid oxide cell (SOC) during operation. Whilst electrochemical mea…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCatalysis and Oxidation Reactions

Targeted killing of metastatic cells using a platelet-inspired drug delivery system

Victor Y. Pan、Preethi N. Siva、Christa L. Modery-Pawlowski 等 5 位作者2015-01-01RSC Advances

Pro-metastatic tumor cells in circulation interact with active platelets that mediate various mechanisms of hematologic metastasis. Elucidating and utilizing these interactions on delivery vehicles can provide unique ways of metastasis-targeted drug delivery.

Nanoparticle-Based Drug DeliveryExtracellular vesicles in diseaseNanoplatforms for cancer theranostics

Dual responsive macroemulsion stabilized by Y-shaped amphiphilic AB 2 miktoarm star copolymers

Heng Li、Duanguang Yang、Yong Gao 等 5 位作者2015-01-01RSC Advances

Y-shaped amphiphilic PS–(PDMAEMA) <sub>2</sub> miktoarm star copolymers stabilized o/w macroemulsion showed pH-induced demulsification and thermo-induced phase inversion.

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationPickering emulsions and particle stabilization

Anisotropic gold nanoassembly: a study on polarization-dependent and polarization-selective surface-enhanced Raman scattering

Mohammad Kamal Hossain、Genin Gary Huang、Yoshita Tanaka 等 5 位作者2015-01-01Physical Chemistry Chemical Physics

A simple one-step process was adopted to fabricate anisotropic gold nanoassemblies. Evaporation-assisted nanoparticle assembly at the meniscus was maintained in this regard. Scanning electron microscopy confirmed that the constituent nanoparticles of the anisotropic gold nanoassembly are neither in physical contact no…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Efficient size control of copper nanoparticles generated in irradiated aqueous solutions of star-shaped polyelectrolyte containers

Alexey A. Zezin、Vladimir I. Feldman、С. С. Абрамчук 等 8 位作者2015-01-01Physical Chemistry Chemical Physics

The formation of copper nanoparticles (Cu-NPs) in irradiated aqueous solutions of star-shaped poly(acrylic acid) (PAA) were studied at two pH values. Transmission electron microscopy (TEM) demonstrates that the star-shaped macromolecules loaded with Cu(2+) ions can act as individual nanosized containers providing a pe…

Gold and Silver Nanoparticles Synthesis and ApplicationsPolymer Surface Interaction StudiesElectrostatics and Colloid Interactions

Fabrication of gold and silver hierarchically micro/nanostructured arrays by localized electrocrystallization for application as SERS substrates

Jingjing Wang、Guotao Duan、Guangqiang Liu 等 6 位作者2015-01-01Journal of Materials Chemistry C

A method based on a polypyrrole through-pore template induced by the colloidal monolayer is developed to fabricate gold and silver hierarchically micro/nanostructured arrays.

Gold and Silver Nanoparticles Synthesis and ApplicationsNonlinear Optical Materials StudiesNanofabrication and Lithography Techniques

Ag plasmonic nanostructures and a novel gel electrolyte in a high efficiency TiO 2 /CdS solar cell

P. Naresh Kumar、Melepurath Deepa、Avanish Kumar Srivastava2015-01-01Physical Chemistry Chemical Physics

A novel photoanode architecture with plasmonic silver (Ag) nanostructures embedded in titania (TiO2), which served as the wide band gap semiconducting support and CdS quantum dots (QDs), as light absorbers, is presented. Ag nanostructures were prepared by a polyol method and are comprised of clumps of nanorods, 15-35…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films