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Corrosión of reinforcements in reinforced and prestressed concretes. II part
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Current knowledge on the basic principles of concrete shrinkage
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STUDIES OF INSULIN CRYSTALS AT LOW TEMPERATURES: EFFECTS ON MOSAIC CHARACTER AND RADIATION SENSITIVITY
Proceedings of the National Academy of Sciences (PNAS), a peer reviewed journal of the National Academy of Sciences (NAS) - an authoritative source of high-impact, original research that broadly spans the biological, physical, and social sciences.
The Atterberg limits and their significance in the ceramic and brick industries
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Factors influencing the early stages of the compaction of clays and sands; review
Abstract A review with 79 references.
The size effect and the non-local Boltzmann transport equation in orifice and disk geometry
A variational approximation is obtained for the resistance (or total entropy production) of a circular orifice in a plane diaphragm at which the scattering is specular. It is found that the Ohm's law prediction must be multiplied by a correction factor of the order of unity and added to the `small orifice' Knudsen con…
Properties of linear elastomeric polyurethanes
Abstract The viscoelastic properties of some polyester‐urethanes are compared with the properties of other polymers. The behavior observed is anomalous in that these polyurethanes exhibit an unusually high value of modulus well above their T g , unaccounted for by either crosslinking or crystallinity. Various experime…
Work hardening of dispersion-hardened crystals
A new theory of work hardening in dispersion-hardened single crystals—by which we mean soft crystals containing hard non-deforming particles of a second phase—is described. It is based on the fact that, if the particles do not deform plastically, and the interface between particle and matrix does not fracture, then se…
A New, General Synthetic Method for the Preparation of Linear Poly‐p‐xylylenes
Abstract A new, general synthetic route to poly‐ p ‐xylylene and substituted poly‐ p ‐xylylenes is described. The key intermediate in the new process is di‐ p ‐xylylene [(2,2) p ‐cyclophane]. It has been found that di‐ p ‐xylylene is quantitatively cleaved by vacuum vapor‐phase pyrolysis at 600°C. to two molecules of…
TAUTOMERIC TRANSFORMATIONS OF PHENOLS
CONTENTS I. Introduction 817 II. Tautomerism of phenols 818 III. Tautomerism of nitrosophenols 823 IV. Tautomerism of azophenols 825 V. Equilibrium phenol–quinonoid transformations of p -substituted phenols 827
Electron nuclear double resonance study of a nitrogen centre in diamond
Abstract Endor measurements on a type 1b diamond with paramagnetic nitrogen centres were made at 4.2, 77 and 300 °K by means of a 35000 Mc/s spectrometer. The axially symmetric nitrogen hyperfine coupling and quadrupole coupling parameters at 4.2 °K are Aiso., = 92.228 ± 0.001, Aaniso. = 10.903 ± 0.002, P = – 3.974 ±…
Measurement of the Electron Energy Spectrum Resulting from a Double Auger Process in Argon
Received 24 October 1966DOI:https://doi.org/10.1103/PhysRevLett.17.1079©1966 American Physical Society
Molybdenum Diselenide: Rhombohedral High Pressure-High Temperature Polymorph
A three-layered rhombohedral form of molybdenum diselenide has been produced by subjecting the normal two-layered hexagonal form to pressures of 40 kilobars and temperatures of 1500 degrees C. The new form is isostructural with rhombohedral molybdenum disulfide.
The heats of combustion of graphite, diamond and some non-graphitic carbons
Abstract The heats of combustion of graphite and diamond have been redetermined in a high precision aneroid calorimeter. It is shown that the result obtained for graphite is consistent with all recently published figures with the exception of that reported by Prosen & Rossini (1944). The latter is significantly hi…
EPR in Selenium
EPR studies at X-band frequencies have been carried out between 300° and 77°K on amorphous and crystalline selenium. Dominating the spectra of the amorphous material were a large number of paramagnetic centers ∼1019/cc which contribute to an unusually broad and inhomogeneous line of width, ΔHp p∼3Kg and g=2.3 to 2.8±0…
PHASE TRANSITIONS OF ADSORBATES: 1. SPECIFIC HEAT AND DIMENSIONAL CHANGES OF THE POROUS GLASS – WATER SYSTEM
The specific heat and dimensional changes of the porous 96% silica glass – water system were measured simultaneously between −35 °C and +2 °C with coverages of 1.6, 4.0, 5.3, and 7.7 molecular layers. The specific heat of the adsorbate below the transition range was found to be higher than that of ice. No phase change…
Crystal Structure of CH3NH3NiCl3
The crystal structure of the new complex, CH3NH3NiCl3, has been determined. The compound crystallizes in the space group Cmcm with a=6.94, b=14.94, and c=5.95 Å. Each nickel ion has a distorted octahedral coordination with two chloride ions at 2.405 Å and four chloride ions at 2.351 Å. Adjacent octahedra along the c a…
INFRARED ABSORPTION OF SINGLE CRYSTALS OF ANHYDROUS SODIUM FORMATE
The infrared absorption of single crystals of sodium formate has been measured in the region of 250 cm −1 to 4 000 cm −1 . Thin sections cut perpendicular to the unique axis were employed and spectra were recorded with light polarized at various angles in this plane. It has been possible to assign unambiguously all of…
Heat Capacity of Alpha Uranium from 1.7 to 25°K
The heat capacity of high-purity alpha uranium has been determined from 1.7 to 23\ifmmode^\circ\else\textdegree\fi{}K and smoothed into previous data at 25\ifmmode^\circ\else\textdegree\fi{}K. These heat capacities are significantly lower than the values reported by other investigators. The values for $\ensuremath{\ga…