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Phase Behavior of Colloids in Binary Liquid Mixtures

Yalia Jayalakshmi、Eric W. Kaler1997-02-17Physical Review Letters

Partially miscible binary liquids containing silica colloids show equilibrium phase boundaries and critical lines. The phase separation is ternary in nature, and measurements allow construction of the ternary phase prism for colloids dispersed in binary fluid mixtures. Comparison with earlier aggregation studies stron…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Dynamics of Block Copolymer Micelles Revealed by X-Ray Intensity Fluctuation Spectroscopy

S. G. J. Mochrie、Anne M. Mayes、Alec Sandy 等 8 位作者1997-02-17Physical Review Letters

We report x-ray intensity fluctuation spectroscopy measurements of the equilibrium dynamics of polymer micelle liquids, composed of polystyrene-polyisoprene block copolymer micelles within a polystyrene homopolymer matrix. The equilibrium dynamics were investigated for times between one and several hundred seconds, an…

Material Dynamics and PropertiesTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

Surface states and space charge layer dynamics on Si(111)2×1: A free electron laser-synchrotron radiation study

M. Marsi、Marie-Emmanuelle Couprie、Laurent Nahon 等 10 位作者1997-02-17Applied Physics Letters

Combining the use of a UV storage ring free electron laser and of synchrotron radiation, a time resolved core level spectroscopy study has been performed on photoexcited Si(111)2×1 surfaces with subnanosecond resolution. This enabled us to measure band bending fluctuations, caused by surface carrier dynamics, during t…

Semiconductor materials and devicesAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Large magnetic entropy change in La0.75Ca0.25MnO3

Z.B. Guo、Jierui Zhang、Heng‐Li Huang 等 5 位作者1997-02-17Applied Physics Letters

Magnetic entropy change of La0.75Ca0.25MnO3 with different particle size has been investigated. Magnetic entropy change ∼4.7 J/kg K larger than that of Gd has been observed at 224 K under a magnetic field of 1.5 T in comparatively big particles. This phenomenon of large magnetic entropy change indicates that the perov…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsOptical properties and cooling technologies in crystalline materials

Sonoluminescing Air Bubbles Rectify Argon

Detlef Lohse、Michael P. Brenner、Todd F. Dupont 等 5 位作者1997-02-17Physical Review Letters

The dynamics of single bubble sonoluminescence (SBSL) strongly depends on the percentage of inert gas within the bubble. We propose a theory for this dependence, based on a combination of principles from sonochemistry and hydrodynamic stability. The nitrogen and oxygen dissociation and subsequent reaction to water sol…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging

Spectroscopic Evidence for Excitonic Localization in Fractal Antenna Supermolecules

Raoul Kopelman、Michael R. Shortreed、Zhong-You Shi 等 8 位作者1997-02-17Physical Review Letters

Direct experimental evidence is presented for the existence of localized excitations on fractal supermolecular structures that may serve as photonic antenna systems. For one dendrimer family the electronic spectra show no redshift with system size, indicating that the excitations are localized at the nodes of the Cayl…

Molecular Junctions and NanostructuresDendrimers and Hyperbranched PolymersNanocluster Synthesis and Applications

K2WSe4

D. Röhnert、C. Näther、W. Bensch1997-02-15Acta Crystallographica Section C Crystal Structure Communications

The crystal structure of potassium tungsten tetraselenide is based on isolated, slightly distorted WSe4 tetrahedra joined via K+ ions. The compound is isotypic with the previously reported Rb and Cs analogues and crystallizes in the β-K2SO4 structure type.

Crystal Structures and PropertiesOrganometallic Compounds Synthesis and CharacterizationInorganic Chemistry and Materials

New Superstructure on the Surface of 2H-NbSe2and Tunneling Spectra at 4.2 K

Fumio Komori、Takao Iwaki、Ken Hattori 等 5 位作者1997-02-15Journal of the Physical Society of Japan

The atomic structure and tunneling spectra of a cleaved surface of a 2H-NbSe 2 single crystal were studied by scanning tunneling microscopy at 4.2 K. Small domains with \(\sqrt{13} \times \sqrt{13}\) modulation were found adjacent to the flat surface with a 3 ×3 intrinsic charge density wave (CDW). The surface atom ar…

Physics of Superconductivity and MagnetismOrganic and Molecular Conductors ResearchIron-based superconductors research

Spin-0 soliton formation in spin-Peierls systems: Charge-transfer complexes DAP-TCNQ and DAP-DMTCNQ

Taro Sekikawa、Hiroshi Okamoto、Tadaoki Mitani 等 6 位作者1997-02-15Physical review. B, Condensed matter

The optical and magnetic properties of the spin-Peierls system, segregated-stack charge-transfer complexes, 1,6-pyrenediamine (DAP)-tetracyanoquinodimethane (TCNQ) and DAP-2,5-dimethyl-TCNQ (DMTCNQ), are investigated to gain insight into the nonlinear excitations in the spin-Peierls system. The band filling of the sys…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryOrganic and Molecular Conductors Research

Specific heat of Si:(P,B) at low temperatures

Stefan Wagner、Mitja Lakner、H. v. Löhneysen1997-02-15Physical review. B, Condensed matter

The specific heat C of Si:(P,B) with carrier concentration N between 0.8 and 17.8\ifmmode\times\else\texttimes\fi{}${10}^{18}$ ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}3}$ and compensation ratio varying from 0.25 to 1 was measured in the temperature range between 0.06 and 3 K and in magnetic fields up to 6 T. Above the…

Theoretical and Computational PhysicsChemical and Physical Properties of MaterialsSurface and Thin Film Phenomena

Electronic-oscillator analysis of femtosecond four-wave mixing in conjugated polyenes

T. Meier、Sergei Tretiak、Vladimir Chernyak 等 4 位作者1997-02-15Physical review. B, Condensed matter

Equations of motion which describe the nonlinear optical response of conjugated polyenes using a collective electronic-oscillator representation are derived. Specific signatures of electronic correlations which enter as anharmonicities and scattering between oscillators are predicted in ultrafast resonant four-wave mi…

Advanced Fiber Laser TechnologiesNonlinear Optical Materials ResearchPhotorefractive and Nonlinear Optics

Influence of surface coverage on the effective optical properties of porous silicon modeled as a Si-wire array

J. E. Lugo、J. A. del Rio、J. Tagüeña-Martı́nez1997-02-15Journal of Applied Physics

The effective dielectric function, effective absorption coefficient and effective refractive index for a model of porous silicon (PS) are calculated using the volume and surface averaging method. The model consists of periodic Si wires with different surface coverages. This approach allows to obtain analytical results…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Determination of electric-field gradients in semiconductors with high precision and high sensitivity

G. Denninger、D. Reiser1997-02-15Physical review. B, Condensed matter

Wurtzite-type semiconductors such as GaN and ZnO exhibit intrinsic electric-field gradients at the nuclear sites due to the hexagonal lattice symmetry. We have determined these field gradients ${\mathrm{V}}_{\mathrm{ZZ}}$ for all the nuclear sites by a magnetic double-resonance scheme. Shallow donors, which are presen…

GaN-based semiconductor devices and materialsAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Reflecting polarizing beam splitter

Carlos Lima、Leandro L. Soares、Lucila Cescato 等 4 位作者1997-02-15Optics Letters

We propose and experimentally demonstrate the use of metal-covered lamellar relief gratings as a polarizing beam splitter operating at a single wavelength near Littrow incidence. We report the characteristics of a grating produced by holography and reactive ion etching that was calculated for operation as beam splitte…

Photorefractive and Nonlinear OpticsSolid State Laser TechnologiesOptical Coatings and Gratings

LEED and photoemission study of the stability ofVO2ssurfaces

E. Goering、M. Schramme、Oliver Müller 等 8 位作者1997-02-15Physical review. B, Condensed matter

We present low-energy electron-diffraction (LEED) and photoemission measurements of single-crystal surfaces of ${\mathrm{VO}}_{2}$ , made possible using samples oriented and characterized in situ. LEED shows that the (100) surface has a (1\ifmmode\times\else\texttimes\fi{}2) reconstruction, but the (110) and (101) sur…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsGa2O3 and related materials

Photoluminescence properties of silicon quantum-well layers

Peter N. Saeta、Alan Gallagher1997-02-15Physical review. B, Condensed matter

Nanometer-scale crystal silicon films surrounded by ${\mathrm{SiO}}_{2}$ were prepared by oxidizing silicon-on-insulator substrates prepared from SIMOX (separation by implantation of oxygen) and crystallized hydrogenated amorphous silicon films. Average silicon layer thickness was determined from reflection spectra. W…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Auger photoelectron coincidence spectroscopy studies: Trends in theL2,3-M4,5M4,5line shapes across the 3d transition-metal series

C.P. Lund、S.M. Thurgate、A. B. Wedding1997-02-15Physical review. B, Condensed matter

The Auger-emission process from solids can be very complex, with a variety of processes producing intensity in the final spectra. The ${\mathrm{L}}_{2,3}$-${\mathrm{M}}_{4,5}$${\mathrm{M}}_{4,5}$ (${\mathrm{L}}_{2,3}$-MM) Auger spectra of the 3d transition metals, in particular, show many complicating effects. Auger p…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Ab initio theoretical comparative study of magnetic coupling inKNiF3sandK2NiF4s

Ibério de P. R. Moreira、Francesc Illas1997-02-15Physical review. B, Condensed matter

The origin of magnetic coupling in ${\mathrm{KNiF}}_{3}$ and ${\mathrm{K}}_{2}$ ${\mathrm{NiF}}_{4}$ is studied by means of an ab initio cluster model approach. By a detailed study of the mapping between eigenstates of the exact nonrelativistic and spin model Hamiltonians it is possible to obtain the magnetic coupling…

Magnetism in coordination complexesAdvanced NMR Techniques and ApplicationsInorganic Fluorides and Related Compounds

Refractive index as a function of photon energy for AlGaAs between 1.2 and 1.8 eV

Y. Kokubo、I. Ohta1997-02-15Journal of Applied Physics

An expression of refractive indices for AlGaAs is presented which agrees reasonably with the experimental results by H. C. Casey Jr., D. D. Shell, and M. B. Panish [Appl. Phys. Lett. 24, 63 (1974)]. This expression is approximately derived by using the method of least squares and is applicable to a determination of th…

Semiconductor Quantum Structures and DevicesPhotonic and Optical DevicesOptical Coatings and Gratings

A New Polymorph of Li4P2O7

Abdelaali Daidouh、M.L. Veiga、C. Pico 等 4 位作者1997-02-15Acta Crystallographica Section C Crystal Structure Communications

The purpose of the present paper is to report the crystal structure of a new phase of tetralithium diphosphate identified by single-crystal X-ray diffraction. The structure consists of layers built from Li—O tetrahedra and pyrophosphate groups connected to each other through edges and vertices.

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyChemical Synthesis and Characterization