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FT-IR Spectroscopy Study of Surface Acidity and 2-Propanol Decomposition on Mixed Oxides Obtained upon Calcination of Layered Double Hydroxides

Fathi Kooli、C. Dianne Martin、V. Rives1997-04-01Langmuir

Mixed Ni−Cr−V, Mg−Cr−V, and Ni−Al−V oxides have been prepared by thermal decomposition of layered precursors with the hydrotalcite structure (brucite-like layers containing divalent and trivalent cations, and interlayer anions balancing the extra positive charge of the layers) at 300 or 500 °C. Surface acidity (Brönst…

Supercapacitor Materials and FabricationMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Size Determination of Small Cu-Clusters by EXAFS

Michael Borowski1997-04-01Journal de Physique IV (Proceedings)

A general model is presented which allows one to calculate the average number of neighbours in small clusters as a function of the cluster size. A formula is derived for spherical clusters and applied to small Cu clusters made by ion implantation in AIN. EXAFS was used to determine the atomic short range order and siz…

Electron and X-Ray Spectroscopy TechniquesX-ray Diffraction in CrystallographyAdvanced Materials Characterization Techniques

Uniaxial, shear, and poisson relaxation and their conversion to bulk relaxation: Studies on poly(methyl methacrylate)

Hongbing Lu、X. Zhang、W. G. Knauss1997-04-01Polymer Composites

Abstract Multiple viscoelastic properties were determined for poly(methyl methacrylate) in the context of examining experimental limitations on deriving other properties from these measurements, specifically time dependent bulk modulus behavior. By means of master curves for uniaxial extension on plate and cylinder sp…

Asphalt Pavement Performance EvaluationPolymer crystallization and propertiesPolymer Nanocomposites and Properties

The laguerre model for grain growth in three dimensions

Xinjian Xue、F. Righetti、H. Telley 等 5 位作者1997-04-01Philosophical Magazine B

We propose a novel and poweful methodology for three-dimensional (3D) grain growth modelling in both the anisotropic and the locally inhomogeneous cases, thus significantly generalizing previous related two-dimensional work. The fundamental modelling structures for the polycrystals and their behaviour are dynamically…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsEnzyme Structure and Function

ESIS TC 6 ROUND ROBIN ON FRACTURE TOUGHNESS

R. J. Prmas、R. Gstrein1997-04-01Fatigue & Fracture of Engineering Materials & Structures

Abstract— The Technical Committee “Ceramics” (TC 6) of the European Structural Integrity Society (ESIS) organized a round robin relating to the fracture toughness of ceramic materials at room temperature. Five materials were tested with five testing methods by eighteen laboratories. The five testing methods were: chev…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Crystal unfolding and chain disentanglement during semicrystalline polymer dissolution

Surya K. Mallapragada、Nicholas A. Peppas1997-04-01AIChE Journal

Abstract Mathematical models developed describe the unfolding of polymeric crystals in the presence of a solvent followed by their subsequent disentanglement. A thermodynamic model considering the free energy changes during crystal unfolding was proposed to obtain an expression for the unfolding rate. A simplified ver…

Polymer crystallization and propertiesEpoxy Resin Curing ProcessesInjection Molding Process and Properties

Properties and Crystalline Structures of Syndiotactic Poly(propylene-co-1-butene)

Naofumi Naga、Kooji Mizunuma、Hajime Sadatoshi 等 4 位作者1997-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTProperties and Crystalline Structures of Syndiotactic Poly(propylene-co-1-butene)Naofumi Naga, Kooji Mizunuma, Hajime Sadatoshi, and Masahiro KakugoView Author Information Petrochemicals Research Laboratory, Sumitomo Chemical Co. Lt…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Beidellite and Associated Clays from the Delamar Mine and Florida Mountain Area, Idaho

J. L. Post、B. L. Cupp、Fritz T. Madsen1997-04-01Clays and Clay Minerals

Abstract There has been much interest in the rare specimen of beidellite from the Black Jack Mine, Florida Mountain, Idaho. A variety of aluminous clays exists along veins such as the Black Jack vein, in rhyolite and latite flows, and in near-surface ash beds, often containing less than 1.0% MgO and 0.5% Na 2 0. Assoc…

Zeolite Catalysis and SynthesisGlass properties and applicationsClay minerals and soil interactions

Angular Dependence in Static and Dynamic Light Scattering from Randomly Branched Systems

Véronique Trappe、J. Bauer、Max Weißmüller 等 4 位作者1997-04-01Macromolecules

The static and dynamic properties of three randomly branched systems under good solvent conditions have been investigated by light scattering. Despite large differences in the topology and chemical structure of these systems one common scaled particle scattering function ( P ( qR g )) is obtained for the probed q rang…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsRheology and Fluid Dynamics Studies

A sample translatory type insert for automated magnetocaloric effect measurements

B. R. Gopal、Richard Chahine、T. K. Bose1997-04-01Review of Scientific Instruments

This paper describes the development of an automated sample translatory type apparatus capable of measuring the magnetocaloric effect of potential magnetic refrigerants over the temperature range 10 to 325 K in applied fields of up to 9 T. A Quantum Design® Physical Property Measurement System has been used as the hos…

Magnetic and transport properties of perovskites and related materialsSolidification and crystal growth phenomenaMagnetic Properties of Alloys

Microwave welding of high density polyethylene using intrinsically conductive polyaniline

Chung‐Yuan Wu、Avraham Benatar1997-04-01Polymer Engineering and Science

Abstract The use of intrinsically conductive polymers in welding of plastics and composites offers the possibility of developing new welding methods. Intrinsically conductive polyaniline (PANI) composite gaskets were used to microwave weld high density polyethylene (HDPE) bars. Two composite gaskets were made from a m…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Highlights in chemistry and physics of polymer stabilization

J. Pospı́šil、S. Nešpůrek1997-04-01Macromolecular Symposia

Abstract Deactivation of free radicals, hydroperoxides and harmful solar radiation are the principal mechanisms increasing stability of commodity and engineering polymers. The stabilization process is accompanied by transformations of individual additives. New compounds influence specifically the integral protecting m…

Polymer crystallization and propertiesPolymer Science and PVC

The flexoelectro-optic effect in cholesterics

Per Rudquist、T. Carlsson、L. Komitov 等 4 位作者1997-04-01Liquid Crystals

The flexoelectro-optic effect in short-pitch cholesterics [1] is analysed in terms of applied electric field strengths and material parameters such as the two flexoelectric coefficients es and eb and the three elastic constants. Starting from the free energy density of the uniformly lying-helix (ULH) configuration, in…

Nonlocal and gradient elasticity in micro/nano structuresKawasaki Disease and Coronary Complications

Electronic Band Structure Study of the Anomalous Electrical and Superconducting Properties of Hexagonal Alkali Tungsten Bronzes AxWO3 (A = K, Rb, Cs)

Kwang-Soon Lee、Dong‐Kyun Seo、M.‐H. WHANGBO1997-04-01Journal of the American Chemical Society

The electrical and superconducting properties of hexagonal alkali tungsten bronzes A x WO 3 (A = K, Rb, Cs) were examined by calculating the electronic band structure of a representative hexagonal tungsten bronze and analyzing reported crystal structures of A x WO 3 (A = K, Rb, Cs). These bronzes possess one-dimension…

Transition Metal Oxide NanomaterialsOrganic and Molecular Conductors ResearchThermal Expansion and Ionic Conductivity

Effect of Additives on the Electromechanical Properties of Pb(Zr,Ti)O 3 –Pb(Y 2/3 W 1/3 )O 3 Ceramics

Seok‐Jin Yoon、Amod Joshi、Kenji Uchino1997-04-01Journal of the American Ceramic Society

Dielectric and piezoelectric properties of 0.02Pb(Y 2/3 W 1/3 )O 3 0.98Pb(Zr0.52Ti0.48)O3 ceramics doped with additives (Nb 2 O 5 , La 2 O 3 , MnO 2 , and Fe 2 O 3 ) were investigated. The grain sizes of these ceramics decreased with increasing amounts of additives. For additions of MnO 2 and Fe 2 O 3 , dielectric los…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Hertzian Contact Damage in Porous Alumina Ceramics

Bruno A. Latella、B. H. O’Connor、Nitin P. Padture 等 4 位作者1997-04-01Journal of the American Ceramic Society

A study has been made of Hertzian contact damage in porous and dense liquid‐phase‐sintered aluminas. Indentation stressstrain curves show increasing nonlinearity as the materials become more porous, illustrating an increasing component of “quasi‐plasticity” in the contact damage. Observations of the surface and subsur…

Advanced ceramic materials synthesisAdvanced Surface Polishing TechniquesAdvanced materials and composites

Extracellular Matrix Assembly in Diatoms (Bacillariophyceae) (II. 2,6-Dichlorobenzonitrile Inhibition of Motility and Stalk Production in the Marine Diatom Achnanthes longipes)

Y. Wang、Jian‐Feng Lu、Jean‐Claude Mollet 等 5 位作者1997-04-01PLANT PHYSIOLOGY

The cellulose synthesis inhibitor 2,6-dichlorobenzonitrile (DCB) and the DCB analogs 2-chloro-6-fluorobenzonitrile, 3-amino-2,6-dichlorobenzonitrile, and 5-dimethylamino-naphthalene-1-sulfonyl-(3-cyano-2, 4-dichloro)aniline (DCBF) inhibited extracellular adhesive production in the marine diatom Achnanthes longipes, re…

Diatoms and Algae ResearchMarine Biology and Environmental ChemistryBiocrusts and Microbial Ecology

Studies of JetRing Spinning Part I: Reducing Yarn Hairiness with the JetRing

Xungai Wang、Menghe Miao、Yan-Lai How1997-04-01Textile Research Journal

This paper introduces the concept of JetRing spinning, a new spinning technique that incorporates features of both ring and air-jet spinning systems. In JetRing spinning, a single air jet is used below the yarn-forming zone of a conventional ring spinning system; this jet acts in a way similar to the first jet in air-…

Mechanical Behavior of CompositesTextile materials and evaluations

In SituRaman Spectroscopy of Supported Chromium Oxide Catalysts: 18O2−16O2Isotopic Labeling Studies

Bert M. Weckhuysen、Israel E. Wachs1997-04-01The Journal of Physical Chemistry B

The isothermal isotopic exchange reaction of 18 O 2 with 16 O of chromium(VI) oxide supported on zirconia, alumina, and titania has been investigated with in situ laser Raman spectroscopy. The isotopic exchange reaction is dependent on the support type, the Cr loading, and the reaction temperature. Complete isotopic e…

Catalytic Processes in Materials ScienceRadioactive element chemistry and processingCatalysis and Oxidation Reactions

Intermacromolecular Complexation due to Specific Interactions 4. The Hydrogen-Bonding Complex of Vinylphenol-Containing Copolymer and Vinylpyridine-Containing Copolymer

Maoliang Xiang、Ming Jiang、Yubao Zhang 等 5 位作者1997-04-01Macromolecules

The complexation of poly(styrene- co -vinylphenol) (STVPh) and poly(styrene- co -vinylpyridine) (STVPy) in nonaqueous solution was investigated with emphasis on the effect of the hydroxyl and pyridyl contents in the component polymers. Viscometry, nonradiative energy transfer fluorospectroscopy, and dynamic laser ligh…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesAdvanced Physical and Chemical Molecular Interactions