Materials Literature
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Some physical, catalytic, and regulatory properties of ketopantoate hydroxymethyltransferase (5,10-methylenetetrahydrofolate: alpha-ketoisovalerate hydroxymethyltranferase) from Escherichia coli are described. This enzyme catalyzes the reversible synthesis of ketopantoate (Reaction 1), an essential precursor of pantot…
The 11B and 207Pb NMR spectra have been used to study the structure of glasses in the system PbO–B2O3–SiO2. The results indicate that the glasses do not contain an appreciable number of BO−3 units, and the network-forming lead atoms play an important role in the compositional behavior of N4 (the fraction of boron atom…
A number of local potentials have been suggested to represent the non-local exchange kernel in electron-atom scattering. A comparative numerical study has been made in which phase shifts for the elastic scattering of electrons by H, He+ and He using these potentials are tested against those calculated from the exchang…
New measurements of electrical conductivity along the $b$ axis of tetrathiafulvalenium-tetracyanoquinodimethanide (TTF-TCNQ) are combined with published results to provide a comprehensive summary including approximately 600 samples studied at 18 different laboratories. The magnitudes of these measured conductivities d…
An experimental study of foam extrusion was carried out to determine the effect of processing variables on the quality of the foam produced. For the study, the chemical blowing agent azodicarbonamide was used, together with an activator and a nucleating agent, to produce thermoplastic foams of low-density polyethylene…
Abstract A polycarbosilane, the starting material of β-SiC fibers, was prepared without autoclave. The new method is simple and more economical than the previous one. Furthermore, a great number of bundles of SiC fibers were obtained by way of oxidative reactions of polycarbosilane fibers.
Synthetic CaTiSiOu has been shown to undergo a reversible, displacive phase transition at 220 + 20oC from space group P2r/a to A2/a, using high-temperature single crystal X-ray diffraction techniques. The transition is signaled by disappearance of reflections of the type hkl: k + / odd. The structure of a synthetic P2…
Abstract Scan electron micrographs are shown of (1) kaolinite and dickite which crystallized from solution within cavities, (2) kaolinite weathered from clastic primary silicate material, (3) residual kaolinite from primary silicate rock, (4) kaolinite above and below a basal unconformity on granitic rock, and (5) hyd…
Abstract The formation energy of vacancies is measured under conditions of very low vacancy concentrations for ultrahigh purity aluminium, after quenching down to 4 K. A value of (0.69 ± 0.03) eV is found. Similar experiments made using pure magnesium yield a formation energy of (0.79 ± 0.03) eV. It is shown that in m…
Flexoelectric effects are observed in both the nematic and smectic-A phases of p-butoxybenzal-p- (β-methylbutyl) aniline (BBMBA) and p-cyano-benzylidine-p-octyloxyaniline (CBOOA). This is the first reported observation of flexoelectricity in smectic phases. The use of a symmetric interdigital electrode in the homeotro…
The environmental and metallurgical variables affecting erosion-corrosion of copper-nickel alloys in sea water are reviewed. Other copper alloys and corrosive environments are reviewed to a limited extent, and some consideration is also given to galvanic corrosion in flowing sea water. The various laboratory test meth…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic effects in transition metal porphyrins. 2. The sensitivity of redox and ligand addition reactions in para-substituted tetraphenylporphyrin complexes of cobalt(II)F. Ann Walker, D. Beroiz, and K. M. KadishCite this: J. Am. Chem. Soc. 1976, 98, 12, 3484–3489Publicat…
Gradient refractive index antireflection films are produced by a chemical etch/leach process applied to glasses sensitized by a phase-separating heat treatment. The reflectance (two surfaces) is effectively reduced from ~ 8% to < 1/2% in the wavelength regime 0.35–2.5 μ. The broadband antireflection film consists o…
Bovine serum albumin, gelatin, fibrinogen and pepsin impaired the attachment of a marine pseudomonad to polystyrene Petri dishes, apparently through adsorption on the dish surface. Serum albumin also appeared to affect the bacterial surface. The basic proteins protamine and histone did not markedly inhibit attachment.…
The (low-atomic-number ceramic) materials carbon, SiC, Be2C, B4C, TiC, BN, Si3N4, Al2O3, and BeO provide a range of property values that are useful for evaluating range of applicability of low-atomic-number ceramic materials in fusion reactors. A survey of recent literature provides a base for conceptual design analys…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolid state polymerization of sulfur nitride (S2N2) to (SN)xMarshall J. Cohen, A. F. Garito, A. J. Heeger, A. G. MacDiarmid, C. M. Mikulski, M. S. Saran, and J. KleppingerCite this: J. Am. Chem. Soc. 1976, 98, 13, 3844–3848Publication Date (Print):June 1, 1976Publication His…
Auroral electron scattering and energy loss are calculated by using for the first time a multiangle equation of transfer at all energies. The results are compared with those obtained by using a Fokker-Planck equation. Both equations have been solved in terms of their eigensolutions. The equation of transfer has also b…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of electrically conductive organic solidsR. C. Wheland and J. L. GillsonCite this: J. Am. Chem. Soc. 1976, 98, 13, 3916–3925Publication Date (Print):June 1, 1976Publication History Published online1 May 2002Published inissue 1 June 1976https://pubs.acs.org/doi/10.1…
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