Materials Literature
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Magnetic and electric properties of a single crystal of ${\mathrm{La}}_{0.7}{\mathrm{Ca}}_{0.3}{\mathrm{CoO}}_{3}$ have been experimentally studied. The system attains a ferromagnetic spontaneous moment below 170 K and exhibits a reentrant spin-glass phase below 100 K. In the ordered and the reentrant phases, the low-…
Boron doped amorphous conducting carbon films show MI transition induced by doping. In this paper we discuss the ac conductivity of the films, which lie on the insulating side of MI transition. The ac conductivity data is analyzed as a function of frequency as well as temperature for both real as well as imaginary par…
We present the results of Monte Carlo simulations of the magnetic properties of a model for a single nanoparticle consisting in a ferromagnetic core surrounded by an antiferromagnetic shell. The simulations of hysteresis loops after cooling in a magnetic field display exchange bias effects. In order to understand the…
The spin polarization of ferromagnetic alkali-metal iron antimonides KFe4Sb12 and NaFe4Sb12 is studied by point-contact Andreev reflection using superconducting Nb and Pb tips. From these measurements an intrinsic transport spin polarization Pt of 67% and 60% for the K and Na compound, respectively, is inferred which…
The spin orientation of a magnetic dopant in a zinc-blende semiconductor strongly influences the spatial structure of an acceptor state bound to the dopant. The acceptor state has a roughly oblate shape with the short axis aligned with the dopant's core spin. For a Mn dopant in GaAs the local density of states at a si…
Considering effects of electric field on the low temperature absorption line of quantum well excitons, we show that, for moderate strength of the electric field, the main contribution to the field dependence of the line-width results from field induced modifications of inhomogeneous broadening of excitons. We find tha…
In order to combine silicon technology with the functionality of magnetic systems, a number of ferromagnetic (FM) materials have been suggested for the fabrication of metal/semiconductor heterojunctions. In this work, we present a systematic study of several candidate materials in contact with the Si surface. We emplo…
Electronically active biomaterials via directed peptide self-assembly: Redox-promoted self-assembly of an eight-residue cyclic D,L-α-peptide bearing four 1,4,5,8-naphthalenetetracarboxylic diimide (NDI) side chains results in the formation of electronically delocalized peptide nanotubes hundreds of nanometers in lengt…
The poor performance of hydrogen storage materials continues to hinder development of fuel cell-powered automobiles. Nanoscale carbons, in particular (activated carbon, exfoliated graphite, fullerenes, nanotubes, nanofibers, and nanohorns), have not fulfilled their initial promise. Here we show that carbon materials c…
(2005). Combined technology of production of ceramic coatings. Welding International: Vol. 19, No. 11, pp. 894-896.
Calcite crystals often nucleate and grow in solutions of calcium carbonate, and these crystallites can become trapped at the air water interface, where they form unusual structures. The most common is a fractal structure, which can extend over a large fraction of the interface, and whose origin is understood in terms…
Abstract In this article, experimental results on the effect of CO 2 sorption and desorption on the creep response of polycarbonate (PC) are presented. Tensile specimens machined from PC sheets were exposed to CO 2 and the absorbed gas mass fraction ranged from 0.045 to 0.12. The creep/creep recovery response of as‐re…
Eu 0.58 Sr 0.42 MnO 3 is found to own a wide variety of magnetic structures, and two subsequent magnetic transitions, a PM-AFM (paramagnetic-antiferromagnetic) transition followed by an AFM-FM (ferromagnetic) transition, are observed under proper magnetic field. It is found that the thermal response of heat capacity t…
The bulk and interfacial properties of ternary mixtures with asymmetric amphiphiles (A2B8) in A2 and B2 matrices and in A2 and B10 matrices are investigated by the dissipative particle dynamics type of molecular-dynamics simulations. The monomer concentrations of A2B8(phiA2B8) studied are below the critical micelle co…
Systematic syntheses of manganese derivatives with 2-pyridineethanol, 2-pyridinemethanol and 2,6-pyridinedimethanol as chelating ligands have been undertaken to produce [trans-Mn(C5H4N-2-CH2CH2OH)2Cl2] (1), [cis-Mn2(μ-Cl)2(Cl)2(C5H4N-2-CH2CH2OH)2(OH2)2] (2), [cis-Mn2(μ-Cl)2(C5H4N-2-CH2OH)4]Cl2 (3) and [MnCl{η3-C5H3N-2…
We have carried out a density functional theory study of the S = 1/2 [FeNO]7 tropocoronand complex, Fe(5,5-TC)NO, as well as of some simplified models of this compound. The calculations accurately reproduce the experimentally observed trigonal-bipyramidal geometry of this complex, featuring a linear NO in an equatoria…
Abstract Internal steam reforming induces an inhomogeneous temperature distribution in SOFC cell. A thermo‐mechanical model has been developed to determine both the temperature gradient and the stress field within an anode supported cell structure fed with methane. Residual stresses due to manufacturing process and th…
We report a method for probing electromechanical properties of multiwalled carbon nanotubes (CNTs). This method is based on atomic force microscopy measurements on a doubly clamped suspended CNT electrostatically deflected by a gate electrode. We measure the maximum deflection as a function of the applied gate voltage…
The specific activity of recombinant Pyrobaculum islandicum glutamate dehydrogenase (pis-GDH) expressed in Escherichia coli is much lower than that of the native enzyme. However, when the recombinant enzyme is heated at 90 degrees C or exposed to 5 M urea, the activity increases to a level comparable to that of the na…
A generalized 2D correlation NMR (GEN2D-NMR) scheme capable of substantially reducing the experimental time for two-dimensional correlation NMR experiments is described. The experimental time used in GEN2D-NMR is shortened to less than one-tenth of that required in traditional double Fourier transform 2D-NMR (FT2D-NMR…