Materials Literature
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Random copolymers were prepared by Candida antarctica lipase B (Novozyme-435) catalyzed copolymerization of omega-pentadecalactone (PDL) with epsilon-caprolactone (CL). Over the whole composition range PDL-CL copolymers are highly crystalline (melting enthalpy by differential scanning calorimetry, above 100 J/g; cryst…
Using numerical simulation techniques such as the transfer matrix method and the commercially available code Microwave Studio, we study the transmission properties of left-handed (LH) metamaterials and arrays of split-ring resonators (SRRs). We examine the dependence of the transmission through single- and double-ring…
We discuss a free boundary problem for two moving solid-liquid interfaces that strongly interact via the diffusion field in the liquid layer between them. This problem arises in the context of liquid film migration (LFM) during the partial melting of solid alloys. In the LFM mechanism the system chooses a more efficie…
Bundles of many fibers, with statistically distributed thresholds for breakdown of individual fibers and where the load carried by a bursting fiber is equally distributed among the surviving members, are considered. During the breakdown process, avalanches consisting of simultaneous rupture of several fibers occur, wi…
The static and dynamic properties of the isotropic XY-model $(s=1/2)$ on the inhomogeneous periodic chain, composed of \emph{N} segments with \emph{n} different exchange interactions and magnetic moments, in a transverse field \emph{h} are obtained exactly at arbitrary temperatures. The properties are determined by in…
A numerical approach is proposed for studying the quantum optical modes in the Klein-Gordon lattices where the energy contribution of the atomic displacements is non-quadratic. The features of the biphonon excitations are investigated in detail for different non-quadratic contributions to the Hamiltonian. The results…
Highly dispersed gold particles (<2 nm) were synthesized within the pores of mesoporous silica with pore sizes ranging from 2.2 to 6.5 nm and different pore structures (2D-hexagonal, 3D-hexagonal, and cubic). The catalysts were reduced in flowing H2 at 200 degrees C and then used for CO oxidation at temperatures rangi…
We report on the Raman spectra of ${\mathrm{Ti}}_{3}\mathrm{Si}{\mathrm{C}}_{2}$ (312), ${M}_{2}\mathrm{Al}\mathrm{C}\phantom{\rule{0.3em}{0ex}}(211)$ ($M=\mathrm{Ti}$, V, Cr, and Nb) and ${\mathrm{Ti}}_{4}\mathrm{Al}{\mathrm{N}}_{3}$ (413), as representative compounds from the family of ${M}_{n+1}A{X}_{n}$ phases. In…
We have designed and evaluated biodegradable porous polymeric microparticles as a scaffold for cell growth. The hypothesis was that microparticles with optimized composition and properties would have better cell adhesion and hence cell growth into a tissue-like structure. Solvent-evaporation method was modified using…
The evidence that double negative media, with an effective negative permittivity, and an effective negative permeability, can be manufactured to operate at frequencies ranging from microwave to optical is ushering in a new era of metamaterials. They are referred to here as 'left-handed', even though a variety of names…
Measurements of the heat capacity C(T,H) of the one-dimensional quantum magnet TiOCl are presented for temperatures 2K < T < 300K and magnetic fields up to 5T. Distinct anomalies at 91K and 67K signal two subsequent phase transitions. The lower of these transitions clearly is of first order and seems to be related to…
By LDA+U method with spin-orbit coupling (LDA+U+SO) the magnetic state and electronic structure have been investigated for plutonium in δand αphases and for Pu compounds: PuN, PuCoGa5, PuRh2, PuSi2, PuTe, and PuSb. For metallic plutonium in both phases in agreement with experiment a nonmagnetic ground state was found…
We report the design of a platform for the delivery of hydrophobic drugs via a macromolecular prodrug approach combined with LbL-assembled polyelectrolyte multilayers. A hyaluronan ester prodrug of the chemotherapeutic drug paclitaxel has been synthesized. Conjugation of the drug to hyaluronan through a labile succina…
In this study we report results for a systematic study of the wetting of structured gold surfaces formed by electrodeposition through monolayer templates of close-packed uniform submicrometer spheres. Removal of the template after deposition leaves a regular hexagonal array of sphere segment pores where the depth of t…
The adsorption of vitamin E onto mesoporous carbons CMK-1 and CMK-3 from vitamin E solutions with different concentrations in nonpolar ( n -heptane) and polar ( n -butanol) solvent has been studied for the first time, and the results are compared to a conventional microporous carbon adsorbent, activated carbon. The am…
The oxygen vacancy in WO(3) has previously been implicated in the electrochromism mechanism in this material. Previous theoretical calculations on the oxygen vacancy in WO(3) have not considered the full range of crystal structures adopted by the material. Here we report studies of the oxygen vacancy in seven crystal…
Ultra-small (3.1 nm) multifunctional CdS:Mn/ZnS core-shell semiconductor quantum dots (Qdots), which possess fluorescent, radio-opacity, and paramagnetic properties, have been shown here. To demonstrate in vivo bioimaging capability, a rat was administered endovascularly with Qdots conjugated with a TAT peptide. The l…
Chalcogenide aerogels based entirely on semiconducting II-VI or IV-VI frameworks have been prepared from a general strategy that involves oxidative aggregation of metal chalcogenide nanoparticle building blocks followed by supercritical solvent removal. The resultant materials are mesoporous, exhibit high surface area…
There are numerous examples where animals or plants synthesize extracellular high-performance skeletal biocomposites consisting of a matrix reinforced by fibrous biopolymers. Cellulose, the world's most abundant natural, renewable, biodegradable polymer, is a classical example of these reinforcing elements, which occu…
Recently, carbon-nanotubes (CNT) have become a main focus in the polymer nanocomposites field. In a previous study, polymer composites with good CNT dispersion were obtained using a twin-screw extruder. There was a close correlation among the following three parameters: the total shear strain [γ·t] responsible for the…