Materials Literature
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Toughening mechanism of polypropylene (PP) blended with ethylene–propylene–diene rubber (EPDM) following selective crosslinking was examined in comparison with that of blends of PP before crosslinking. The yield stress, strength of craze, and density of void which are dominant factors for enhancing toughness in PP ble…
Measurements were made on a series of cotton/polyester blends having different compositions. The results showed that the time to ignition increased as the polyester contents of the fabric were increased. An explanation of this observation is given. Both the orientation of the fabric and the temperature of the furnace…
Incorporation of hard clay causes improvement in most of the physical properties of zinc-sulfonated EPDM of high ethylene content. Zinc stearate reduces the melt viscosity of the clay-filled zinc-sulfonated EPDM during high-temperature processing, but does not adversely affect the physical properties at ambient temper…
Based on a successful description of II-VI ternary alloys, which introduces an empirical bowing parameter to the widely used virtual crystal approximation, we set up a tight-binding Hamiltonian to describe the Zn_{1-y}Cd_ySe_{1-x}Te_x and Zn_{.9}Cd_{.1}S_{.07}Se_{.93} quaternary alloys. We just use a formula that can…
The intersection volume of two independent 2-level cut Gaussian random fields is proposed to model the open-cell microstructure of organic aerogels. The experimentally measured X-ray scattering intensity, surface area and solid thermal conductivity of both polymeric and colloidal organic aerogels can be accounted for…
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…
The magnetization and transport properties of (Ln = La, Eu or Lu; ) perovskites have been studied. It is shown that the substitution of by La, Eu or Lu up to x = 0.1 leads to a sharp increase in the magnetization and conductivity. Further replacement of Ca results in a decrease in the magnetization due to the regular…
Complete dislocations in quasicrystals are intersections of dislocations in a high-dimensional lattice with an irrational cut that represents the physical space. We study the properties which proceed from that definition, either by methods relevant to the Volterra process, or by topological methods. The Volterra proce…
The complex AC conductivity of the sol - gel-derived cobalt silicate gel-glasses is reported for the frequency range and temperature range 80 - 300 K. The experimental results were analysed in terms of theoretical models based on quantum tunnelling and classical hopping theories. It has been observed that classical ho…
We report ab initio calculations of the electronic structures and the band line-ups of heterocrystalline superlattices (HSLs) , and (n = 1,2,3). The band line-ups at both the (3C-BN)/(2H-BN) interface and the (3C-SiC)/(2H-SiC) interface are found to be type II, with valence-band offsets of 0.16 eV and 0.14 eV and cond…
Exchange interaction between two lanthanide or actinide ions of configuration bridged by common diamagnetic ligands is theoretically studied using a modified version of the superexchange theory developed in this paper. Exchange spin Hamiltonians were calculated for the and dimers serving as models of the and - superex…
In measurements of the dielectric dispersion carried out on single crystals of antiferroelectric lead zirconate a polar relaxation mode in the frequency range from to has been found. Using the Cole - Cole relation for the complex response the relaxation frequency and dielectric step of the mode have been determined as…
We have made a detailed study of sonoluminescence (SL) in high magnetic fields. In magnetic field sweeps at constant levels of acoustic drive, SL disappears above a pressure-dependent threshold magnetic field. Sweeps of acoustic drive at fixed magnetic fields show that the upper and lower bounds of forcing pressure th…
Local electron field emission properties of diamondlike carbon (DLC) films were measured by a probe method in 1 atmosphere ambient pressure, using the modified scanning tunneling microscopic (STM) system, and the diode method. In the STM probe method, the field emission was turn on at a low bias as +2.67 V. A large em…
Pulsed laser induced reactive quenching at a liquid–solid interface was used for the synthesis of tetrahedrally coordinated crystalline carbon nitride on a tungsten substrate. The crystalline phase was identified by transmission electron diffraction. X-ray photoelectron spectroscopy indicated that the carbon atoms are…
The dielectric dispersion in glycine phosphite crystal over the frequency range 30 - 1000 MHz is presented. Ferroelectric dispersion of the Debye type along the b-axis occurs in the microwave-frequency region and is caused by a single relaxational soft mode. The powder IR (at low temperatures between 300 and 14 K) and…
Low-field piezoelectric coefficient and strain were investigated in Ca-modified PbTiO3 thin films by means of optical interferometry. A remanent piezoelectric coefficient of 70 pm/V was observed that agrees well with the values previously reported for the bulk ceramics of the same composition. The efficient poling of…
Manganites of the series , with x = 0, 0.1, 0.3, 0.5, 0.7 and 1.0, have been characterized in ceramic form and thin films have been prepared by pulsed laser deposition. Characterization techniques included x-ray diffraction, conductivity and magnetoresistance, magnetization and susceptibility, optical spectroscopy and…
Ab initio molecular dynamics simulations are employed to investigate the dominant migration mechanism of the gallium vacancy in gaas as well as to assess its free energy of formation and the rate constant of gallium self-diffusion. our analysis suggests that the vacancy migrates by second nearest neighbour hops. the c…