Materials Literature
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Three linear diblock copolymers (PS- b -P2MP), two 3-miktoarm [PS(P2MP) 2 ] copolymers, and two 4-miktoarm star copolymers [PS(P2MP) 3 ] of styrene (S) and 2-methyl-1,3-pentadiene (2MP) were synthesized by anionic polymerization/high vacuum techniques and controlled chlorosilane chemistry. Molecular characterization o…
Surface binding between the carboxylic group and the TiO 2 nanoparticle is important in the potentially applicable dye-sensitized mesoporous TiO 2 crystalline solar cell. However, the nature of the surface binding is still not clear enough. We propose a new method to study the surface binding between the carboxylic gr…
The thermolysis products obtained by refluxing a series of vic-dihydroxychlorins in o-dichlorobenzene are characterized. Depending on the nature of substrates, this methodology provides an access for novel carbon-carbon linked chlorin-chlorin dimers and chlorin-porphyrin dimers with fixed and flexible orientations. Th…
We treat the non-relativistic Compton scattering process in which an incoming photon scatters from an N-electron many-body state to yield an outgoing photon and a recoil electron, without invoking the commonly used frameworks of either the impulse approximation (IA) or the independent particle model (IPM). An expressi…
A new method for doing feedback control of single quantum systems was proposed. Instead of feeding back precisely the process output, a cloning machine served to obtain the feedback signal and the output. A simple example was given to demonstrate the method.
We show that dipole-field induced antiferromagnetic coupling, or RKKY ferromagnetic coupling, between Co layers can strongly affect the low magnetic field switching behavior of Co/Cu/Co nanopillars. Whereas current-assisted switching at low fields in uncoupled nanopillars is always hysteretic, strong coupling of eithe…
Glass-coated, analyte-tagged nanoparticles (GANs) are core−shell particles where a nanometer-scale Au or Ag core is functionalized with Raman active molecules and encapsulated in a glass shell. The glass shell provides the particle with mechanical and chemical stability. Specifically, the glass coating renders the par…
Dependent on the relative particle core size, two distinct types of particle topologies in block copolymer/nanocrystal blends have been identified, that is, the localization of particles along the intermaterial dividing surface or at the center of the respective polymer domain. In ternary systems consisting of block c…
The developing neural tubes and associated neural crest cells were removed from stage 30 Ambystoma maculatum embryos to obtain larvae with aneurogenic forelimbs. Forelimbs were allowed to develop to late 3 digit or early 4 digit stages. Limbs amputated through the mid radius-ulna regenerated typically in the aneurogen…
Abstract Voltammetric and spectrophotometric measurements of poly(3,3″‐dipentoxy‐3′‐dicyanoethenyl‐2,2′:5′,2″‐terthiophene) (polyCN) films, in connection with other experimental evidence, reveal a normal oxidative, but a peculiar reductive behavior consisting of trapping of the negative charge during the cathodic scan…
Using an effective simplified continuum model for diblock copolymers, surfactants, and liquid crystals, the response of lamellar systems upon dilation and compression along the layer normal is investigated by large-scale parallelized dissipative particle dynamics like stabilized molecular dynamics simulation. We demon…
This paper presents the shear responses and interfacial rheology of photosensitive monolayers. Langmuir films of a fatty acid containing an azobenzene moiety that can undergo trans-cis photoisomerization have been investigated for their structural and dynamical properties. The cis conformation produces a structureless…
Supercritical CO 2 plasticization of semicrystalline poly(vinylidene fluoride) (PVDF) was investigated by measuring linear dilation as a function of temperature (75−130 °C) and pressure (138−670 bar) using a linear variable differential transformer (LVDT). The robustness of the LVDT technique allows the study of CO 2…
In this work we compare the relaxation properties of pure dehydrated glycerol with those of the glycerol usually studied (the glycerol sample which is not specially protected from water absorption). We show that the dielectric spectroscopy can distinguish between the different structures and dynamics of these two kind…
High-resolution electrical resistance R and $dR/dT$ measurements have been done in the (giant magnetocaloric) orthorhombic ${\mathrm{Gd}}_{5}({\mathrm{Si}}_{0.1}{\mathrm{Ge}}_{0.9}{)}_{4}$ compound to study their evolution through more than 50 thermal cycles between 300 K and 10 K. A detailed characterization of R and…
The Suzuki cross-coupling methodology provides a facile synthetic approach for the modular preparation of meso-tetraaryl cofacial bisporphyrins anchored by xanthene and dibenzofuran. This synthetic method furnishes cofacial bisporphyrin templates with enhanced steric and electronic protection from mu-oxo formation and…
We describe the synthesis, characterization, and lithographic performance of positive-working chemically amplified photosensitive polybenzoxazoles (PSPBOs) composed of partially tert -butoxycarbonyl (t-BOC) protected hyperbranched poly( o -hydroxyamide)s (HB-tbocPHAs) and diphenyliodonium 9,10-dimethoxyanthracene-2-su…
We report on the results of x-ray fluorescence measurements of ${\mathrm{CrO}}_{2}$ thin film, which show half-metallic electronic structure. The experimental finding that the elastically scattered radiation observed in Cr ${L}_{2,3}$ x-ray emission spectra is more prominent in ${\mathrm{CrO}}_{2}$ than in metallic Cr…
Fluorinated ansa substituted cyclophosphazenes endo-FcCH(2)P(S)(CH(2)O)(2)[P(F)N](2)(F(2)PN) [Fc = ferrocenyl] (1) and exo-FcCH(2)P(S)(CH(2)O)(2)[P(F)N](2)(F(2)PN) (2) readily transform to the spirocyclic compound [FcCH(2)P(S)(CH(2)O)(2)PN](F(2)PN)(2) (3) not only in the presence of CsF but also with non-fluorinated b…
Electrogenerated films of polyaniline were studied by potential steps in acetonitrile solutions to check for the presence of compaction, relaxation, and diffusion processes giving like-nucleation chronoamperograms such as those described by the electrochemically stimulated conformational relaxation (ESCR) model. This…