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Adiabatic polymerization of acrylamide using a persulfate–bisulfite redox couple

Karin Pohl、Ferdinand Rodriguez1981-02-01Journal of Applied Polymer Science

The temperature rise during the adiabatic polymerization of acrylamide in water has been used to characterize the kinetic parameters. Based on initial rate data, the following equation is obtained: where concentrations of monomer, persulfate, and bisulfite are in mole/kg, T is in K, and t is in min. The order with res…

Polymer Science and PVC

Studies on structural foam processing. III. Bubble dynamics in foam extrusion through a converging die

Hee Ju Yoo、Chang Dae Han1981-02-01Polymer Engineering and Science

Abstract An experimental and theoretical study was carried out to achieve a better understanding of bubble dynamics in foam extrusion through a converging die. For the experimental study, a number of converging channels were constructed of aluminum, with glass windows on both sides. Bubble dynamics in the flow channel…

Polymer composites and self-healingPickering emulsions and particle stabilizationPolymer Foaming and Composites

Mesomorphic Behaviour of Dodecyl Benzene Sulfonic Acid and Its Sodium Salt

D. Krishnamurti、R. Somashekar1981-02-01Molecular crystals and liquid crystals

X-ray and optical studies in the paper show that dodecyl benzene sulfonic acid and the mixtures of its sodium salt with (i) water and (ii) methane sulfonic acid exhibit the smectic A phase. Interference studies are described in the paper to establish the molecular orientation in the droplets and batonnets.

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation

Calculated magnetic properties of some isomers of pyracylene

J.A.N.F. Gomes、R. B. Mallion1981-02-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCalculated magnetic properties of some isomers of pyracyleneJ. A. N. F. Gomes and R. B. MallionCite this: J. Org. Chem. 1981, 46, 4, 719–727Publication Date (Print):February 1, 1981Publication History Published online1 May 2002Published inissue 1 February 1981https://doi.org…

Magnetism in coordination complexesInorganic and Organometallic ChemistryThermal and Kinetic Analysis

Lattice Dynamics and Invar Properties in f.c.c. FeMn Alloy

Y. Endoh、Y. Noda、Masamichi Iizumi1981-02-01Journal of the Physical Society of Japan

Using inelastic neutron scattering the phonon dispersion relations in a single crystal of face centered cubic Fe 0.7 Mn 0.3 have been determined at several temperatures above and below the Néel temperature of 412 K. The shifts of the frequencies of the [110] T 1 mode below T N have been observed, which eventually give…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsMetallurgical and Alloy Processes

Elastic energy dissipation effects in α + β and β phase composition ranges of the palladium-hydrogen system

F.M. Mazzolai、P. G. Bordoni、F. A. Lewis1981-02-01Journal of Physics F Metal Physics

Elastic energy dissipation (internal friction) peaks, arising from both stress-induced, bulk lattice rearrangements of hydrogen interstitials (H (1) peak) and hydrogen dislocation interactions (H (2) peak), have been investigated over a wide range of the hydrogen content in alpha + beta and beta phase concentration ra…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsAdvanced Physical and Chemical Molecular Interactions

Redox reactions of copper in zeolite A. Four crystal structures of vacuum-desolvated copper-exchanged zeolite A, Cu8-A

Han Sik Lee、Karl Seff1981-02-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRedox reactions of copper in zeolite A. Four crystal structures of vacuum-desolvated copper-exchanged zeolite A, Cu8-AHan Sik Lee and Karl SeffCite this: J. Phys. Chem. 1981, 85, 4, 397–405Publication Date (Print):February 1, 1981Publication History Published online1 May 200…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsSurface Chemistry and Catalysis

Theoretical π‐π* circular dichroic spectra of helical poly(glycine) and poly(L‐alanine) as functions of backbone torsion angles

Jon Applequist1981-02-01Biopolymers

Abstract Circular dichroic spectra and oscillator strengths of the π‐π transition near 190 nm are calculated for helical (Gly) 6 and (Ala) 6 at 30° intervals of the backbone torsion angles (ϕ,ψ) over the range ‐180° ≤ ϕ ≤ ‐60°, −60° ≤ ψ ≤ 180°, using the partially dispersive normal mode treatment of the dipole interac…

Collagen: Extraction and CharacterizationVarious Chemistry Research TopicsChemistry and Stereochemistry Studies

Crystal data for ferric molybdate: Fe2(MoO4)3

V. Massarotti、Gemma de la Flor、Alberto Marini1981-02-01Journal of Applied Crystallography

Indexed powder patterns of the monoclinic phase, stable at room temperature, and of the orthorhombic phase, stable for T > 786 K, are given. The cell dimensions are: a = 15.737 (8), b = 9.231 (5), c = 18.224 (9) Å, β = 125.46 (2)° at 295 K; a = 9.330 (3), b = 12.868 (5), c = 9.242 (3) Å at 818.6 K. Linear equations de…

Luminescence Properties of Advanced MaterialsThermal and Kinetic AnalysisPigment Synthesis and Properties

Redox Potential Measurements in High Temperature Aqueous Systems

Digby D. Macdonald、Arthur C. Scott、Paul R. Wentrcek1981-02-01Journal of The Electrochemical Society

Redox potential measurements on platinum and Type 304 stainless steel in equilibrium ( or ) and nonequilibrium boric acid/lithium hydroxide solutions at 275°C are reported. For equilibrium systems containing hydrogen, good agreement was obtained between the measured potentials on platinum and calculated equilibrium po…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsThermal and Kinetic Analysis

The sense of Jahn-Teller distortions in octahedral copper(II) and other transition-metal complexes

Malcolm Gerloch1981-02-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe sense of Jahn-Teller distortions in octahedral copper(II) and other transition-metal complexesMalcolm GerlochCite this: Inorg. Chem. 1981, 20, 2, 638–640Publication Date (Print):February 1, 1981Publication History Published online1 May 2002Published inissue 1 February 19…

Advanced Chemical Physics StudiesMagnetism in coordination complexesCatalysis and Oxidation Reactions

Role of molybdenum in phosphorus-induced temper embrittlement of 12%Cr martensitic stainless steel

Raphaëlle Guillou、M. Guttmann、Ph. Dumoulin1981-02-01Metal Science

Molybdenum considerably reduced reversible temper embrittlement (RTE) of 12%Cr martensitic stainless steels by scavenging P in the matrix, which decreased P segregation to the grain boundaries. Contrary to the case of many low-alloy steels, Mo additions as large as 1 wt-% were still beneficial, due to the lower C cont…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and Creep

Principal magnetic susceptibilities of MnO and their temperature dependence

M. S. Jagadeesh、M. S. Seehra1981-02-01Physical review. B, Condensed matter

The temperature dependence of the principal susceptibilities, ${\ensuremath{\chi}}_{\ensuremath{\parallel}}$ and ${\ensuremath{\chi}}_{\ensuremath{\perp}}$, of MnO are reported in the range of 4.2 to 300 K from the studies in a single crystal from which nonstoichiometries have been removed. A procedure combining selec…

Magnetic properties of thin filmsMultiferroics and related materialsMagnetic Properties and Applications

A Controlled Composition Study of Calcium Carbonate Crystal Growth: The Influence of Scale Inhibitors

George H. Nancollas、Thomas F. Kazmierczak、Eric Schuttringer1981-02-01CORROSION

The precipitation of calcium carbonate is of considerable importance in a wide variety of scale forming situations since carbonate concentrations in the environment are usually quite appreciable. As a first-formed solid phase, calcium carbonate may induce the growth of other scale minerals on its surface. Since the so…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation Techniques

Electrical Conductivity Mechanism in Zinc and Copper Substituted Magnetite

G. Srinivasan、C. M. Srivastava1981-02-01physica status solidi (b)

Abstract The electrical transport properties in polycrystalline ferrous zinc ferrites, Zn x Fe 3− x O 4 ( x = 0, 0.2, 0.4, 0.6) and ferrous zinc–copper ferrites, Zn x Cu 0.1 Fe 2.9‐ x O 4 ( x = 0, 0.1, 0.2, 0.3, 0.4), are studied by measuring the conductivity and the Seebeck coefficient. The conductivity is shown to a…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

The examination of fresh or living plant material in an environmental scanning electron microscope

G. D. Danilatos1981-02-01Journal of Microscopy

SUMMARY An environmental scanning electron microscope (ESEM) has been developed which allows the examination of specimens at pressures up to 6 kPa. This new technique has been applied to the examination of live and wet plant specimens. The results are compared with those obtained using similar material that has been d…

Electron and X-Ray Spectroscopy Techniques

Molecular dynamics study of a single polymer chain in solution

Wolfgang Bruns、R. Bansal1981-02-01The Journal of Chemical Physics

We have carried out a computer simulation of the dynamics of a model polymer chain in solution. The polymer is represented by a nonamer linked through bonds which are constrained to be fixed (bead–rod model). All particles are assumed to interact via a Lennard-Jones potential and the simulations have been performed at…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

The crystal structure of Benzoic Acid: a redetermination with X-rays at room temperature; a summary of neutron-diffraction work at temperatures down to 5 K

作者信息未提供1981-02-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The crystal structure of benzoic acid, C 6 H 5 CO 2 H, has been redetermined by X-ray diffraction at room temperature. Extensive neutron-diffraction measurements have also been made: by single-crystal methods at room temperature and 130 K; and, at 130 K and 5 K, by powder-profile analysis on C 6 D 5 CO 2 H. T…

Crystallography and molecular interactionsCultural Heritage Materials AnalysisX-ray Diffraction in Crystallography

Excited-state absorption in the pump region of alexandrite

M. L. Shand、J. C. Walling、R. C. Morris1981-02-01Journal of Applied Physics

Excited-state absorption in alexandrite has been measured from 420 to 680 nm by using pulsed flash lamp pumping and a dye laser probe. The excited-state absorption cross section is generally of the same order of magnitude as the ground-state absorption cross section (10−19 cm2) and therefore may represent a large loss…

Glass properties and applicationsPhotorefractive and Nonlinear OpticsSolid State Laser Technologies