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Structural and dynamical properties of chlorinated hydrocarbons studied with resonant inelastic x-ray scattering

R. Bohinc、M. Žitnik、K. Bučar 等 11 位作者2016-04-06The Journal of Chemical Physics

We present a theoretical and experimental study of resonant inelastic x-ray scattering on a large group of chlorinated hydrocarbons: CH3Cl, CH2Cl2, CHCl3, CCl4, CH3CH2Cl, ClCH2CH2Cl, CH3CHCl2, CH3CCl3, C2H2Cl2-iso, C2H2Cl2-cis, C2H2Cl2-trans, and C6H5Cl. Differences in structural and dynamical properties of the molecu…

X-ray Spectroscopy and Fluorescence AnalysisNuclear Physics and ApplicationsX-ray Diffraction in Crystallography

Ferroelectric thin films with liquid crystal for gradient index applications

Oliver Willekens、John P. George、Kristiaan Neyts 等 4 位作者2016-04-06Optics Express

We report on the first ever combination of a thin film of lead zirconate titanate (PZT) with a liquid crystal (LC) layer. Many liquid crystal applications use a transparent conductive oxide to switch the liquid crystal. Our proposed processing does not, instead relying on the extremely high dielectric constant of the…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotorefractive and Nonlinear Optics

Structural Characterization of Gd2O3Phosphor Synthesized by Solid-State Reaction and Combustion Method Using X-Ray Diffraction and Transmission Electron Microscopic Techniques

Raunak Kumar Tamrakar、D. P. Bisen、Ishwar Prasad Sahu 等 5 位作者2016-04-06Journal of Display Technology

The combustion synthesis and conventional solidstate reaction method was used to synthesize Gadolinium oxide (Gd2O3) phosphor. Nanoranged Gd2O3was successfully synthesized by ignition of gadolinium nitrate followed by combustion in the presence of urea, and for the solid-state reaction method, boric acid was used as a…

Luminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics SynthesisInorganic Chemistry and Materials

Castellaroite, Mn2+ 3(AsO4)2·4.5H2O, a new mineral from Italy related to metaswitzerite

Anthony R. Kampf、Fernando Cámara、Marco E. Ciriotti 等 6 位作者2016-04-06European Journal of Mineralogy

Castellaroite (IMA2015-071), Mn 2+ 3 (AsO 4 ) 2 •4.5H 2 O, is a new secondary arsenate mineral from the Monte Nero mine, Rocchetta Vara, La Spezia, Liguria, Italy and the Valletta mine, near Canosio, Cuneo, Piedmont, Italy.It crystallized from As-and Mn-rich hydrothermal fluids in an oxidizing environment.At Monte Ner…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Development and evaluation of N-naphthyl-N,O-succinyl chitosan micelles containing clotrimazole for oral candidiasis treatment

Prasopchai Tonglairoum、Thisirak Woraphatphadung、Tanasait Ngawhirunpat 等 7 位作者2016-04-06Pharmaceutical Development and Technology

Clotrimazole (CZ)-loaded N-naphthyl-N,O-succinyl chitosan (NSCS) micelles have been developed as an alternative for oral candidiasis treatment. NSCS was synthesized by reductive N-amination and N,O-succinylation. CZ was incorporated into the micelles using various methods, including the dropping method, the dialysis m…

Nanocomposite Films for Food PackagingAdvancements in Transdermal Drug DeliveryAdvanced Drug Delivery Systems

Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy

Justyna Ciesielczuk、Janusz Janeczek、Mateusz Dulski 等 4 位作者2016-04-06European Journal of Mineralogy

A suite of 60 mineral samples with compositions intermediate between pseudomalachite, Cu 5 (PO 4 ) 2 (OH) 4 , and its arsenate analogue cornwallite, and between kipushite, (Cu,Zn) 6 (PO 4 ) 2 (OH) 6 ·H 2 O, and its arsenate analogue philipsburgite was investigated by electron-probe microanalysis, scanning electron mic…

Geological and Geochemical AnalysisCrystal Structures and PropertiesClay minerals and soil interactions

Silk-ionomer and silk-tropoelastin hydrogels as charged three-dimensional culture platforms for the regulation of hMSC response

Rossella Calabrese、Nicole R. Raia、Wenwen Huang 等 8 位作者2016-04-06Journal of Tissue Engineering and Regenerative Medicine

The response of human bone marrow-derived mesenchymal stem cells (hMSCs) encapsulated in three-dimensional (3D) charged protein hydrogels was studied. Combining silk fibroin (S) with recombinant human tropoelastin (E) or silk ionomers (I) provided protein composite alloys with tunable physicochemical and biological fe…

Bone Tissue Engineering MaterialsCell Adhesion Molecules ResearchSilk-based biomaterials and applications

Porous SiOCH Thin Films Obtained by Foaming

Julien El Sabahy、G. Castellan、Florence Ricoul 等 4 位作者2016-04-06The Journal of Physical Chemistry C

Porous organosilicate thin films (SiOCH) deposited by plasma-enhanced chemical vapor deposition (PECVD) are used as dielectric layers in advanced microelectronic interconnections and as chemical layers in chemical sensors and biosensors. One challenge is to increase the porosity in these films, the classical method be…

Mesoporous Materials and CatalysisCopper Interconnects and ReliabilitySilicone and Siloxane Chemistry

Behavior of the Chemical Potential in Calcite and Magnesite Crystals: A Damped Harmonic Oscillation

Marco Bruno、Marco Rubbo、Francesco Roberto Massaro2016-04-06Crystal Growth & Design

The behavior of the chemical potential of the species CaCO 3 and MgCO 3 in proximity of the (10.4) crystal face of calcite and magnesite is determined at the quantum–mechanical level by adopting a recent calculation strategy conceived in our research laboratory. A very peculiar trend of this quantity from the (10.4) s…

High-pressure geophysics and materialsCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

Effective Preparation of Bamboo Cellulose Fibers in Quaternary Ammonium/DMSO Solvent

Zeming Jiang、Jiaojiao Miao、Yongqi Yu 等 4 位作者2016-04-06BioResources

A novel, efficient, and direct blend of solvents, tetrabutylammonium acetate/dimethyl sulfoxide (TBAA/DMSO), was used for the dissolution and regeneration of bamboo pulp. Regenerated fibers were successfully prepared by a wet spinning process. The bamboo pulp without any pretreatment was readily soluble in the solvent…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesInnovations in Concrete and Construction Materials

Polytypism of cronstedtite from Pohled, Czech Republic

J. Hybler、Jiří Sejkora、Viktor Venclík2016-04-06European Journal of Mineralogy

Single crystals of the 1:1 layered iron silicate cronstedtite from the new occurrence in Pohled, Czech republic were studied with aid of the single crystal X-ray diffractometer with area detector. Chemical composition of some crystals were determined by the EPMA. Three types of crystals were discerned: 1) mixed crysta…

Geological and Geochemical AnalysisCrystal Structures and PropertiesClay minerals and soil interactions

Snap Transitions of Pressurized Graphene Blisters

Peng Wang、Kenneth M. Liechti、Rui Huang2016-04-06Journal of Applied Mechanics

Blister tests are commonly used to determine the mechanical and interfacial properties of thin film materials with recent applications for graphene. This paper presents a numerical study on snap transitions of pressurized graphene blisters. A continuum model is adopted combining a nonlinear plate theory for monolayer…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Physical and tribological characteristics of porous NiTi SMA fabricated by powder metallurgy

Neeraj Sharma、Tilak Raj、Kamal Kumar2016-04-06Particulate Science And Technology

This paper presents the mechanical and tribological characteristics of the NiTi shape memory alloy (SMA) fabricated by powder metallurgy. This material has prominent applications in micro-electromechanical systems, medical implants, actuator, space and aerospace industries, etc. In every field, wear characteristics pl…

Polymer composites and self-healingShape Memory Alloy TransformationsSoft Robotics and Applications

Precise 3D printing of micro/nanostructures using highly conductive carbon nanotube-thiol-acrylate composites

Y. Liu、W. Xiong、Li Jiang 等 5 位作者2016-04-06Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Two-photon polymerization (TPP) is of increasing interest due to its unique combination of truly three-dimensional (3D) fabrication capability and ultrahigh spatial resolution of ~40 nm. However, the stringent requirements of non-linear resins seriously limit the material functionality of 3D printing via TPP. Precise…

Carbon Nanotubes in CompositesConducting polymers and applicationsNonlinear Optical Materials Studies

Synthesis and characterization of poly(methyl methacrylate)/graphene‐based thermally expandable microcapsules

Majid Safajou‐Jahankhanemlou、Farhang Abbasi、Mehdi Salami‐Kalajahi2016-04-06Polymer Composites

Graphene oxide (GO) was prepared via Hummers' method and reduced by hydrazine monohydrate. GO was modified with (3‐methacryloxypropyl)triethoxysilane (MPS) and the obtained GO‐MPS nanosheets were reduced by hydrazine monohydrate. The different modified nanosheets were utilized to fabricate microballoons based on methy…

Graphene research and applicationsPolymer Nanocomposites and PropertiesGraphene and Nanomaterials Applications

Impact of the Electron–Phonon Interactions on the Polaron Dynamics in Graphene Nanoribbons

Ana Virgínia Passos Abreu、Jonathan Fernando Teixeira、A. L. A. Fonseca 等 6 位作者2016-04-06The Journal of Physical Chemistry A

The influence of the electron-phonon (e-ph) interactions on the filed-included polaron dynamics in armchair graphene nanoribbons (GNRs) is theoretically investigated in the scope of a two-dimensional tight-binding model. The results show that the localization of the polaronic charge increases when the strength of e-ph…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Using strain gradient elasticity in conjunction with Gurtin–Murdoch theory for modeling the coupled effects of surface and size phenomena on the instability of narrow nano-switch

Maryam Keivani、Ali Koochi、Abolfazl Kanani 等 6 位作者2016-04-06Proceedings of the Institution of Mechanical Engineers Part C Journal of Mechanical Engineering Science

While comprehensive researches have been conducted on modeling the electromechanical stability of wide-enough beam-plate nano-switches, few researchers have focused on modeling the electromechanical instability of narrow-width nano-switches. For such systems, considering the coupled effects of surface stresses and siz…

Advanced MEMS and NEMS TechnologiesMechanical and Optical ResonatorsNonlocal and gradient elasticity in micro/nano structures

Mechanical behaviour and microstructure of Cf/ZrC, Cf/SiC and Cf/ZrC – SiC composites

Changfeng Yan、Ronghao Liu、C. Zhang 等 5 位作者2016-04-06Advances in Applied Ceramics Structural Functional and Bioceramics

Cf/ZrC, Cf/SiC and Cf/ZrC–SiC composites were successfully prepared by polymer infiltration and pyrolysis (PIP) using polycarbosilane and a liquid ZrC precursor. The densification process, mechanical properties and microstructures were studied in a view of comparison. After the same total 20 PIP cycles, the Cf/ZrC, Cf…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Formation and Transformation Behavior of Sodium Dehydroacetate Hydrates

Zhang Xia、Chuang Xie、Yao‐Hui Huang 等 8 位作者2016-04-06Molecules

The effect of various controlling factors on the polymorphic outcome of sodium dehydroacetate crystallization was investigated in this study. Cooling crystallization experiments of sodium dehydroacetate in water were conducted at different concentrations. The results revealed that the rate of supersaturation generatio…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility StudiesFreezing and Crystallization Processes

Influences of Liquid‐Phase Sintering on Structure, Grain Growth, and Dielectric Behavior of PbZr 0.52 Ti 0.48 O 3 Ceramics

Shraddha Joshi、Smita Acharya2016-04-06International Journal of Applied Ceramic Technology

In this work, to formulate piezoceramic systems such as PbZr 0.52 Ti 0.48 O 3 ( PZT ) for low‐temperature co‐fired ceramic ( LTCC )‐based devices, liquid‐phase sintering approach is demonstrated. ZnO–B 2 O 3 ( ZB ) binary glass system is used as sintering aid. X‐ray diffraction ( XRD ) study confirms the formation of…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectrical and Thermal Properties of Materials