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Kramers-Kronig dispersive analysis and optical properties in the infrared, and revised vibrational behavior of orthorhombicNa2[Fe(CN)5NO]⋅2H2O

Oscar E. Piro、E.E. Castellano、Jorge A. Güida 等 4 位作者1989-01-15Physical review. B, Condensed matter

The optical parameters (namely, the complex dielectric tensor and refractive indexes) of sodium nitroprusside dihydrate (SNP), ${\mathrm{Na}}_{2}$[Fe(CN${)}_{5}$NO]\ensuremath{\cdot}2${\mathrm{H}}_{2}$O (orthorhombic, space group ${D}_{2h}^{12}$) in the infrared (ir) region 1550--2250 ${\mathrm{cm}}^{\mathrm{\ensurema…

Luminescence Properties of Advanced MaterialsMagnetism in coordination complexesNonlinear Optical Materials Research

Phason velocities inTaS2by x-ray diffuse scattering

W. Minor、Dean Chapman、S. N. Ehrlich 等 4 位作者1989-01-15Physical review. B, Condensed matter

The diffuse x-ray scattering surrounding satellite reflections caused by charge-density waves has been measured at two different temperatures and analyzed in terms of phason scattering. From this analysis, the phason velocity has been obtained for all directions of propagation.

High-pressure geophysics and materialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

A simultaneous electron paramagnetic resonance and optical absorption study of ultraviolet-induced defect centers in Ge-doped silica fibers

Robert N. Schwartz、G. R. Blair1989-01-15Journal of Applied Physics

Simultaneous electron paramagnetic resonance (EPR) and optical absorption studies were carried out at room temperature in a Ge-doped silica fiber-optic waveguide following in situ ultraviolet (UV) irradiation with 254-nm (4.88-eV) photons. We have observed that the UV-induced EPR is directly correlated with the UV-ind…

Photonic and Optical DevicesGlass properties and applicationsThin-Film Transistor Technologies

Fractal Nature of the Electronic Structure of a Penrose Tiling Lattice in a Magnetic Field

Tetsuo Hatakeyama、Hiroshi Kamimura1989-01-15Journal of the Physical Society of Japan

The one-electron energy spectrum of a Penrose tiling lattice in a magnetic field is studied with a tight-binding Hamiltonian. We show the following remarkable results characteristic of a Penrose lattice. (1) The density of states in a magnetic field has a central peak with zero width at zero energy. It is shown that t…

Theoretical and Computational PhysicsQuasicrystal Structures and PropertiesAdvanced Mathematical Theories and Applications

Aspects of degradation and stability of ABS copolymers. I. Effect of β‐carotene as antioxidant

E.A. Abdel-Razik1989-01-15Journal of Polymer Science Part A Polymer Chemistry

Abstract The oxidative degradation of polybutadiene–styrene–acrylonitrile (ABS) copolymer was extensively investigated. Three factors were studied: the influence of ageing temperature on the rate of the oxidation of the copolymer; the efficiency of β‐carotene as chain breaking antioxidant; and the effect of butadiene…

Polymer Nanocomposites and PropertiesThermal and Kinetic AnalysisPolymer Science and PVC

Modification of polymers via electrophilic aromatic substitution

Shadpour Mallakpour、George B. Butler1989-01-15Journal of Polymer Science Part A Polymer Chemistry

Abstract Three vinyl monomers, 2,4,6‐trimethoxystyrene, 4‐( N,N ‐dimethylamino)styrene, and N ‐methyl‐2‐vinylpyrrole, were synthesized via the Wittig reaction from the corresponding aldehyes. These monomers were homopolymerized by radical polymerization using α,α′‐azoisobutyronitrile (AIBN) as initiator at 60°C. The r…

Multicomponent Synthesis of HeterocyclesSynthesis and properties of polymersPhosphorus compounds and reactions

Effects of charge-density-wave depinning on the elastic properties ofNbSe3

X.‐D. Xiang、J. W. Brill1989-01-15Physical review. B, Condensed matter

Detailed measurements on the dc-voltage dependence of the Young's modulus E, shear modulus G, and their associated internal friction, in ${\mathrm{NbSe}}_{3}$ below both charge-density-wave (CDW) transitions, are reported. As for ${\mathrm{TaS}}_{3}$ [Phys. Rev. B 36, 2969 (1987)], the moduli decrease when the CDW bec…

Crystallography and molecular interactionsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Oxygen 2sspectroscopy

W. Ranke、H.J. Kuhr1989-01-15Physical review. B, Condensed matter

Photoemission from O 2s--derived levels appears at binding energies (BE) between \ensuremath{\sim}14 and \ensuremath{\sim}33 eV. It has been investigated systematically by photoelectron spectroscopy with synchrotron radiation for a variety of oxygen-containing adsorbates on Pt(111), Ge(001), and Si(001) surfaces. On P…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectron and X-Ray Spectroscopy Techniques

Permanent magnetic materials based on Nd2Fe14C prepared by melt spinning

R. Coehoorn、J. P. W. B. Duchateau、C.J.M. Denissen1989-01-15Journal of Applied Physics

Permanent magnetic materials containing the intermetallic compound Nd2Fe14C were obtained by annealing melt-spun flakes. As quenched flakes with compositions close to the stoichiometric composition consist of α-Fe, Nd2Fe17 with some dissolved carbon, and an amorphous phase. At approximately 700 °C Nd2Fe14C is formed i…

Metallic Glasses and Amorphous AlloysRare-earth and actinide compoundsMagnetic Properties of Alloys

Anisotropic superexchange and spin-resonance linewidth in diluted magnetic semiconductors

B. E. Larson、Hannelore Ehrenreich1989-01-15Physical review. B, Condensed matter

The Dzyaloshinski-Moriya (DM) anisotropic superexchange constant and the resulting electron-paramagnetic-resonance (EPR) linewidth in Mn-based II-VI-compound diluted magnetic semiconductors (DMS) such as ${\mathrm{Cd}}_{1\mathrm{\ensuremath{-}}\mathrm{x}}$${\mathrm{Mn}}_{\mathrm{x}}$Te are calculated quantitatively. A…

Quantum and electron transport phenomenaTheoretical and Computational PhysicsPhase-change materials and chalcogenides

Diffusion Phenomena in Thin Films and Microelectronic Materials

Deeksha Gupta、Paul S. Ho1989-01-15Medical Entomology and Zoology

A comprehensive review of diffusion phenomena in thin films and microelectronic materials - theory and technology. Contents include: Bulk Solids and Thin Films Anelastic Relaxation and Diffusion in Thin-Layer Materials Diffusion in Artificially Modulated Thin Films Diffusion and Growth in Oxide Films Diffusion Induced…

Microstructure and mechanical propertiesSolidification and crystal growth phenomenaCopper Interconnects and Reliability

Transport phenomena in polymer-graphite composite materials

A. A. Quivy、R. Deltour、A. G. M. Jansen 等 4 位作者1989-01-15Physical review. B, Condensed matter

The dc electrical resistance of a polymer-graphite composite has been studied in high magnetic fields (<10 T) and at low temperatures for different concentrations of graphite. The resistivity of the composites for the high graphite concentrations was much greater (${>10}^{4}$) than that of pure graphite, and abo…

Graphene research and applicationsFiber-reinforced polymer compositesGraphite, nuclear technology, radiation studies

On the Phase Transitions in 1 T -TaS 2

R. Manzke、T. Buslaps、B W Pfalzgraf 等 5 位作者1989-01-15Europhysics Letters (EPL)

The temperature-dependent electronic structure of 1 T -TaS 2 near the Fermi level, determined by means of angle-resolved photoemission with high-energy resolution of 35 meV, exhibits a distinct energy gap associated with a metal-semiconductor transition at 180 K on cooling, whereas on warming up the retransformation o…

Hydrogen embrittlement and corrosion behaviors in metalsIron-based superconductors researchMachine Learning in Materials Science

Velocity versus temperature relation for solidification and melting of silicon: A molecular-dynamics study

M. Kluge、John R. Ray1989-01-15Physical review. B, Condensed matter

We report on molecular-dynamics simulations to determine the steady-state velocity versus temperature relation for (001) solidification and melting of silicon using the Stillinger-Weber potential to model the interactions between the silicon atoms. Down to 250 K of undercooling, the simulation values show good agreeme…

Material Dynamics and PropertiesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Valence bond approach to exact nonlinear optical properties of conjugated systems

Z. G. Soos、S. Ramasesha1989-01-15The Journal of Chemical Physics

Diagrammatic valence-bond (DVB) theory is extended to dynamic nonlinear susceptibilities of interacting π electrons in Pariser–Parr–Pople (PPP) or other quantum cell models whose correlated ground state ‖G〉 is known. Corrections φ(1)(ω) and φ(2)(ω2,ω1) to ‖G〉 due to oscillating electric fields are found directly as li…

Nonlinear Optical Materials ResearchPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

The effect of spinning speed and drawing temperature on structure and properties of poly(ethylene terephthalate) yarns

R. Huisman、H. M. Heuvel1989-01-15Journal of Applied Polymer Science

Abstract From an industrial point of view, it is effective to have a relation between process conditions and resulting product properties. In practice there are many possible process conditions, whereas properties are generally interrelated in a complex way. Thus, there is a strong need for a physical understanding of…

Polymer crystallization and propertiesTextile materials and evaluationsMaterial Properties and Processing

Short-range order in glycerol. A molecular dynamics study

Leslie J. Root、Frank H. Stillinger1989-01-15The Journal of Chemical Physics

A molecular model has been constructed for glycerol and has been applied to a study of clusters and condensed phases by molecular dynamics simulation. Each molecule is regarded as a flexible polar complex of nine mass points (CH and CH2 groups are treated as ‘‘united atoms’’). Periodic arrays stabilize in a close appr…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

High-speed liquid-crystal modulators using transient nematic effect

Shin‐Tson Wu、Chiung‐Sheng Wu1989-01-15Journal of Applied Physics

The transient nematic effect, together with multiple pass technique and optimal temperature effect, was employed to demonstrate high-speed liquid-crystal modulators. As a result, nematic liquid-crystal modulators with frame time less than 50 μs have been achieved in the visible spectral region.

Photonic and Optical DevicesLiquid Crystal Research AdvancementsAdvanced Optical Imaging Technologies

Structural phase transitions in GaAs to 108 GPa

Samuel T. Weir、Yogesh K. Vohra、Craig A. Vanderborgh 等 4 位作者1989-01-15Physical review. B, Condensed matter

The III-V compound GaAs was studied using energy-dispersive x-ray diffraction with a synchro- tron source up to a pressure of 108 GPa. When the pressure was increased to 16.6 GPa, the GaAs sample transformed from the zinc-blende structure to an orthorhombic structure [GaAs(II)], space group Pmm2, consisting of a primi…

High-pressure geophysics and materialsBoron and Carbon Nanomaterials ResearchIron-based superconductors research

Studies on composites from wood and polypropylenes. II

Setsuko Takase、N. Shiraishi1989-01-15Journal of Applied Polymer Science

Abstract Composites of polypropylene (PP) or maleic‐anhydride‐modified polypropylene (MPP) with refiner ground pulp (RGP) were prepared under various kneading conditions (mixing temperature, rate of rotation, and mixing time) and evaluated for their tensile strength (σ max ), break elongation (ϵ max ), and Young's mod…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties