Materials Literature
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Grain-boundary (GB) properties in a polycrystalline system are generally anisotropic; in particular, both the GB energy and the mobility depend on the GB misorientation. Here the effect of anisotropic GB properties on two- dimensional grain growth is investigated by computer simulation. A stochastic velocity Monte Car…
End-grafted polystyrene “brushes” of various thickness and grafting density on silica surfaces were synthesized by surface-initiated polymerization. The “brushes” were studied by contact angle measurements, ellipsometry, and scanning force microscopy (SFM). Wetting behavior of thin polystyrene film on the top of the g…
Seeding effects on the microstructure and mechanical properties of single‐phase Ca‐α‐SiAlON ceramics have been investigated. Whereas a small amount of seeds can transform the microstructure from one of fine equiaxed grains to one consisting of many needle‐like grains, the highest fracture toughness of 8 MPa·m 1/2 is n…
Author: Schmidt, S. et al.; Genre: Journal Article; Issued: 2002-05; Keywords: MPI für Metallforschung; Abt. Rühle; grain boundary segregation; liquid-metal embrittlement; analytical transmission electron microscopy; Al-Ga alloys; Title: Gallium segregation at grain boundaries in aluminium
Nanocrystalline MgAl2O4 powders were prepared by a thermal decomposition method, i.e. by use of molten salts. This method involves co-melting stoichiometric amounts of magnesium nitrate hydrate Mg(NO3)2.6H 2O and aluminium nitrate hydrate Al(N O3) 3.9H2O at 500°C. The spinel content of the co-melted and calcined powde…
Flexible large sheets of dimethylsiloxane‐based inorganic/organic hybrids with sizes of ∼200 mm × 290 mm and ∼1.5 mm thickness have been fabricated from poly(dimethylsiloxane) (PDMS) and metal alkoxides of Zr and Ta. The hybrid sheets were characterized by XPS, EXAFS, FT‐IR, HRTEM, and SAXS. The inorganic components d…
Synthesis of Mn2+-activated zinc silicate phosphor using the combustion method is described. An efficient phosphor can be prepared by this method at reaction temperatures as low as 500 °C in a few minutes. The phosphor so prepared is compared with those prepared by other methods such as sol–gel and CGUPS.
Abstract Experimental results for the gross heat of combustion of over 140 commercial and developmental polymers and small molecules of known chemical structure were used to derive additive molar group contributions to the heat of combustion. The materials examined contained carbon, hydrogen, oxygen, nitrogen, phospho…
Assuming a practical use in ITER facility, rapid recovery and supply of tritium to accommodate pulsed plasma operation cycle with minimal inventory was tested. For this purpose, tritium will be supplied from heated bed with vacuum pump while heat of reaction is supplied externally. For recovery, hydriding reaction occ…
In this study, the model presented in Part I is used to investigate phenomena related to the compression of fiber assemblies that are not accounted for by van Wyk's theory of the uniaxial compression of an initially random fiber assembly. In order to do this, the potential energy, the work done on the assembly, and a…
The dielectric permittivity and ac conductivity of bis-(Methyltriphenyl-phosphonium) 2 tetraiodomercurate (II), [(CH 3 )(C 6 H 5 ) 3 P] 2 HgI 4 , has been measured in at 300-400 K and 0.11-20 kHz. The frequency dependent conductivity is interpreted in terms of the jump relaxation model, where translational and reorien…
Cadmium mercury thiocyanate (CdHg(SCN)4, CMTC) and its two lewis base adducts: cadmium mercury thiocyanate dimethyl-sulphoxide (CdHg(SCN)4(H6C2OS)2, CMTD) and cadmium mercury thiocyanate glycol monomethyl ether (CdHg(SCN)4(C3H8O2), CMTG) have been discovered as nonlinear optical (NLO) crystal materials. Their structur…
Abstract The change in Mooney viscosity ( ML 1+4 ) with aging was followed for silica filled compounds containing various silanes and polar additives. Several mechanisms for the aging stability are postulated and evaluated through experimentation. The type of silane or polar additive used can cause the ML 1+4 to incre…
Blazed diffractive optical elements (DOEs) were studied for the violet wavelength by electron-beam lithography. By optimizing electron-beam writing parameters and electron-dose distributions, we fabricated eight kinds of grating (period A = 10-0.54 microgm) with excellent blazed structure. It has been demonstrated tha…
We investigated the effects of the sintering atmosphere on the interface structure and grain‐growth behavior in 10‐vol%‐YAG‐added SiC. When α‐SiC was liquid‐phase‐sintered in an Ar atmosphere, the grain/matrix interface was faceted, and abnormal grain growth occurred, regardless of the presence of α‐seed grains. In co…
Transforming growth factor-beta1 is a fibrogenic cytokine that is important in the development of fibroproliferative disorders of the skin after injury. To investigate the role of transforming growth factor-beta1 produced by keratinocytes during wound healing, a plasmid with the human transforming growth factor-beta1…
Methyltrioxorhenium(VII) (MTO) has been immobilized in the mesoporous silica MCM-41 functionalized with pendant bipyridyl (bpy) groups of the type 4-[(−O)3Si(CH2)4]-4′-CH3-2,2′-bipyridine. Powder X-ray diffraction and N2 adsorption-desorption studies confirm that the regular hexagonal symmetry of the host is retained…
Detector-grade undoped chemical vapor deposited (CVD) diamond samples have been studied with thermally stimulated currents (TSC) and photoinduced current transient spectroscopy (PICTS) analyses in the temperature range 300–650 K. Two previously unknown defects have been identified, characterized by activation energies…
To approach a microscopic understanding of the reaction kinetics on complex surfaces of heterogeneous catalysts, we combine multimolecular beam techniques and a supported model catalyst approach. The model systems are prepared under ultrahigh vacuum (UHV) conditions and have been characterized in detail with respect t…
The complex {Fe[HC(3,5-Me2pz)3]2}I2 (1) has been prepared from the reaction of FeI2 and HC(3,5-Me2pz)3 (pz = pyrazolyl ring) in a 1:2 ratio. The complex is high-spin in both the solid state and in solution at ambient temperature. In the solid state, magnetic susceptibility and Mössbauer spectral studies indicate that…