Materials Literature
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The title compound contains a three-coordinate Cu + ion bonded to the sulfonamide nitrogen atom and to two CO ligands with long Cu−C bonds (1.90 and 1.91 Å) and a C−Cu−C bond angle of 122°. The two ν(CO) IR bands for this compound are at 2158 (s) and 2184 (m) cm - 1 .
From fine-structure investigations it is well known that in many icosahedral boron-rich solids the occupation densities of specific atomic sites are considerably reduced. Investigations of the electronic properties have proved that the electronic properties of these semiconductors are strongly influenced by high densi…
We derive a model for voltage-induced wetting, so-called electrowetting, from the principle of virtual displacement. Our model includes the possibility that charge is trapped in or on the wetted surface. Experimentally, we show reversible electrowetting for an aqueous droplet on an insulating layer of 10 micrometer th…
In a recent paper by Jones et al., it is argued, based on FP-LAPW band-structure calculations, that previous calculations of ground-state properties for actinides, using the FP-LMTO method implemented by J. M. Wills, are in error. We demonstrate in this paper that the conclusions of Jones et. al. are unfounded. Calcul…
In order to examine the scratching resistance of ultrathin hydrogenated amorphous carbon (a-C:H) coatings used in magnetic storage devices, a large number of scratches with reproducible residual groove depths well below 1 nm has been examined. All measurements were carried out with an atomic force microscope and diamo…
Authors designed the monomers having hetero-aromatic rings in their structures as optical materials of high refractive index. Among various hetero-aromatics, we noticed thiophene has a large atomic refraction. We synthesized novel mono- and bi-functional thiophene methacrylate derivatives. Their homopolymers had high…
This letter introduces the concept of a thermoelectromechanical cooler (TEMC), which modifies a traditional thermoelectric cooler (TEC) by using intermittent contact of a mechanical element synchronized with an applied pulsed current. Using Bi2Te3 as the thermoelectric material, it is predicted that the maximum temper…
The substitutions of rare earths for La on the magnetic properties of the perovskites La0.7−xRxA0.3MnO3 (0<x<0.7), R=Pr or Gd and A=Ca, Sr, or Ba have shown that small substitution of Pr slightly increases the coercive field Hc and magnetization M, and strongly improves the magnetoresistance (MR) while l…
In this letter, we report on the switching properties of an ordered system of Bi4Ti3O12 ferroelectric memory cells of an average lateral size of 0.18 μm formed via a self-assembling process. The ferroelectricity of these cells has been measured microscopically and it has been demonstrated that an individual cell of 0.…
We describe a simple, yet phenomenologically very different, low-temperature modification to the conventional metal–organic chemical vapor deposition. It has been applied to the epitaxy of hexagonal-phased Bi2Te3/Sb2Te3 superlattices on zinc-blende GaAs substrates. The modification enables a two-dimensional, layer-by-…
Patterned growth of freestanding carbon nanotube(s) on submicron nickel dot(s) on silicon has been achieved by plasma-enhanced-hot-filament-chemical-vapor deposition (PE-HF-CVD). A thin film nickel grid was fabricated on a silicon wafer by standard microlithographic techniques, and the PE-HF-CVD was done using acetyle…
In this article, the curing kinetics of two fast cure flip-chip epoxy encapsulants under both isothermal and nonisothermal conditions are investigated by differential scanning calorimetry. The method allows determination of the most suitable kinetic model and corresponding parameters. The kinetic analysis suggests tha…
Ring-opening polymerization of ε-caprolactone (CL) has been initiated with rare earth phenyl compounds in both bulk and solution. These rare earth phenyl initiators can give polycaprolactone (PCL) with high yield and high molecular weight. The polymerization mechanism is through a coordination-deprotonation-insertion…
Vein grafts are subject to increased tensile stress due to exposure to arterial blood pressure, which has been hypothesized to induce endothelial cell (EC) and smooth muscle cell (SMC) injury. This study was designed to verify this hypothesis and to develop a tissue engineering approach that can be used to prevent the…
We study thin, symmetric AB-copolymer films between neutral walls using the bond fluctuation model. Near the surface, the monomer distribution with respect to the chains’ center of mass is nonisotropic: The chains flatten on the surface. The resulting A- and B-lamellae have interfaces practically perpendicular to the…
Stability against deprotonation of polyaniline–polyamide 6 blends processed from formic acid can be significantly improved by the addition of a supporting protonating agent to the processing solution such as phenylphosphonic acid, camphorsulfonic acid, 2-acrylamide-2-methyl-1-propane sulfonic acid, or dibutyl phosphat…
Novel surface modifying macromolecules (SMMs) were developed for incorporation into polyethersulfone (PES) membranes, intended for pervaporation applications. These materials were synthesized with a diisocyanate, polypropylene oxide (PPO), and a fluoro-alcohol, and characterized for elemental analysis, molecular weigh…
The phase diagram of adsorbate-induced row-type-alignments, such as missing-row reconstructions induced by adsorbate-atoms on the FCC(110) surface, is calculated by the Blume-Emmery-Griffiths (BEG) model. In the model, we introduce adatom-adatom and dipole-dipole interactions between nearest-neighbor (NN) and next-nea…
Lithiophorite with a sandwich layered structure, which consists of stacked MnO 6 octahedral sheets and LiAl 2 (OH) 6 octahedral sheets, was prepared from a birnessite-type sodium manganese oxide with a layered structure, by using a hydrothermal soft chemical process. In the first step, lithium−aluminum hydroxide compl…
Whether interfacial tension between two molten polymers can be reduced significantly by the formation of copolymer at the interface by chemical reaction of functionalized chains is the question addressed by this paper. To answer it, model experiments are carried out by grafting of benzylamine end-functionalized deuter…