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Origin of Characteristic Properties of Natural Rubber—Synergistic Effect of Fatty Acids on Crystallization of cis-1,4-Polyisoprene: II, Mixed and Esterified Fatty Acids in Natural Rubber

Naoyuki Nishiyama、Seiichi Kawahara、Takashi Kakubo 等 5 位作者1996-09-01Rubber Chemistry and Technology

Abstract Crystallization behavior of deproteinized natural rubber at −25°C was investigated by dilatometry in connection with the effect of long-chain fatty acid groups, esterified to the rubber chain, as well as free fatty acids and their esters. The overall crystallization rate decreased after removal of the acetone…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Structural and Dielectric Properties of Ba(Ti1-xSnx)O3 Thin Films

Mitsuo Tsukada、M. Mukaida、Shintaro Miyazawa1996-09-01Japanese Journal of Applied Physics

Close correlation between the dielectric constant and the degree of preferential (111) orientation is found for Ba(Ti 0.85 Sn 0.15 )O 3 ( BTS 15 ) solid-solution thin films deposited on a Pt/Ti/SiO 2 /Si(100) substrate by pulsed laser deposition. It is shown that substrate temperature is the principal factor which det…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

Influence of central metal and ligand system on conduction type and charge carrier transport in phthalocyanine thin films

Julius Meyer、Derck Schlettwein1996-09-01Advanced Materials for Optics and Electronics

By changing the chemical composition of phthalocyanine molecules, the electrical properties of the ensemble in the solid state can be influenced directly. This is shown for phthalocyaninatomanganese (PcMn) as compared with purely divalent central metals and for complexes in which the ligand system has been modified by…

Porphyrin and Phthalocyanine ChemistryTransition Metal Oxide NanomaterialsElectrochemical Analysis and Applications

Effects of associations between humic acids and iron or aluminium on the flocculation and aggregation of kaolin and quartz

M. ARIAS、María Teresa Barral、F. DIAZ‐FIERROS1996-09-01European Journal of Soil Science

Summary The aggregative effect of organic matter on soil particles is conditioned by its composition and concentration and the degree to which it is associated with metal ions and oxides in the soil. We treated suspensions of kaolin or quartz substrates at pH 5 with metal (Fe or Al; c. 3 to 23 mg g −1 of substrate) or…

Soil and Unsaturated FlowClay minerals and soil interactionsMine drainage and remediation techniques

Tetrabutyl ammonium iodide, cetyl pyridinium bromide and cetyl trimethyl ammonium bromide as corrosion inhibitors for mild steel in sulphuric acid

V. Savithri、S.M. Mayanna1996-09-01ePrints@Bangalore University (Bangalore University)

The inhibitive action of tetrabutyl ammonium iodide, cetyl pyridinium bromide and cetyl trimethyl ammonium bromide towards the corrosion of mild steel in sulphuric acid has been investigated by weight loss and polarisation techniques. The percentage inhibition varies with the nature and concentration of the inhibitor,…

Corrosion Behavior and InhibitionInorganic and Organometallic ChemistrySynthesis and properties of polymers

Random copolymers in concentrated solutions

B. W. Swift、Mónica Olvera de la Cruz1996-09-01Europhysics Letters (EPL)

We study concentrated solutions of ideal A-B symmetric random copolymers in non-selective good solvents by computer simulations. When the effective net A-B interaction per thermal energy in the solution (χ eff ) is larger than 2, the scattering function has a peak at a molecular weight ( N ) independent wave vector k…

Advanced Polymer Synthesis and CharacterizationMaterial Dynamics and PropertiesBlock Copolymer Self-Assembly

Mechanism of optical recording in doped liquid crystals

Stanisław Bartkiewicz、Andrzej Miniewicz1996-09-01Advanced Materials for Optics and Electronics

A new principal mechanism underlying real-time holographic grating recording in a thin cell filled with a nematic liquid crystal doped with a dye is proposed. In the experiment a laser light interference pattern is mapped in the form of a spatial modulation of index of refraction. This is achieved by respective modula…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotorefractive and Nonlinear Optics

Possibility of New Mixed Bismuth Layer-Structured Ferroelectrics

Tadashi Takenaka、Kyo Komura Kyo Komura、Kōichirō Sakata1996-09-01Japanese Journal of Applied Physics

Possibilities of new ferroelectrics, Bi 5 Nb 3 O 15 (BIN) and Bi 5 Ta 3 O 15 (BTA), where A=Bi 5+ , B=Nb 5+ and Ta 5+ and k =1, in the general formula of mixed bismuth layer-structured oxides (MBLSO), Bi 4 A 2 k -1 B 2 k +1 O 6 k +9 ( k =1, 2, 3, 4), are discussed using ordinary fired, hot-pressed and hot-forged ceram…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsAcoustic Wave Resonator Technologies

Evaluation of Acellular Human Dermis as a Dermal Analog in a Composite Skin Graft

Daniel A. Medalie、Ronald G. Tompkins、Jeffrey R. Morgan1996-09-01ASAIO Journal

This study evaluated the structure and function of a dermal substitute composed of de-epidermalized, acellular human dermis, and tested its performance as part of a composite skin graft with cultured human keratinocytes. The acellular dermis retained much of the complex structure of native dermis, as demonstrated by i…

Electrospun Nanofibers in Biomedical ApplicationsWound Healing and TreatmentsSilk-based biomaterials and applications

Biodegradable Polymers from Agricultural Products

John M. Krochta、Cathérine L. C. De Mulder-Johnston1996-09-01ACS symposium series

Biological recycling of biodegradable polymers is an important option for reducing municipal solid waste. Legislation, including prohibitions on disposal of non-biodegradable waste at sea, is making development of biodegradable products more urgent. Biodegradable polymers based on cellulose, starch, protein, microbial…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Salt-based approach for frequency conversion materials

Mark J. Rosker、Patricia Cunningham、M. D. Ewbank 等 8 位作者1996-09-01Pure and Applied Optics Journal of the European Optical Society Part A

A salt-based approach for the development of frequency conversion materials is presented. Salts are generally rugged materials due to their strong ionic bonding. A high degree of chemical substitution (both of anion and cation) is possible, including highly nonlinear organic ions. This flexibility is consistent with t…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchPhotorefractive and Nonlinear Optics

Structural transitions in ordered, cylindrical foams

N Pittet、Philippe Boltenhagen、N. Rivier 等 4 位作者1996-09-01Europhysics Letters (EPL)

A soap froth with bubbles of equal size in a cylindrical tube tends to crystallise. We exhibit, experimentally and by simulation, two sequences of transitions between different crystalline structures. Each transition is induced by a single dislocation. The two different sequences of transitions are associated with dif…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Anomaly in the Infrared Active Phonon Modes and Its Relationship to the Dielectric Constant of (Ba1-xSrx)(Mg 1/3Ta 2/3)O 3 Compound

Toru Nagai Toru Nagai、Masaaki Sugiyama、Mutsuo Sando 等 4 位作者1996-09-01Japanese Journal of Applied Physics

A characteristic change in the dielectric properties with A-site substitution is known in complex perovskite compounds, (Ba, Sr)(B', B")O 3 , which are expected to be applied to dielectric resonators. Recently, a phase transformation upon tilting of oxygen octahedra has been found in some of the compounds. However the…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Linear and Nonlinear Optical Properties of CdS and CdSe Nanoparticles Stabilized with Poly(N-vinyl-2-pyrrolidone)

Hiroshi Yao、Shigeru Takahara、Hirokazu Mizuma 等 5 位作者1996-09-01Japanese Journal of Applied Physics

CdS and CdSe nanoparticles were prepared in organic solvents in the presence of poly(N-vinyl-2-pyrrolidone) (PVP). PVP plays an essential role in preventing the flocculation of concentrated nanoparticles (stabilizing effect), and in controlling the particle size under the influence of the solvent used. FT-IR measureme…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNonlinear Optical Materials Studies

Microencapsulation in polyurea shell: Kinetics and film structure

Shivesh Yadav、Kartic C. Khilar、Akkihebbal K. Suresh1996-09-01AIChE Journal

Abstract Interfacial polycondensation is an important polymerization technique that encapsulates a variety of active principles. Mechanisms governing the reaction and interplay of physical and chemical rate processes need to be understood for both rational design of reaction equipment and the process control to produc…

Polymer crystallization and propertiesPolymer composites and self-healingRheology and Fluid Dynamics Studies

Observation of ferroelectric domain structures by secondary-electron microscopy in as-grown KTiOPO4crystals

G. Rosenman、A. Skliar、I. Lareah 等 6 位作者1996-09-01Physical review. B, Condensed matter

Ferroelectric domain structures of as-grown KTiOP${\mathrm{O}}_{4}$ crystals are observed on polished polar surfaces by the scanning secondary-electron microscopy (SEM) method. The results demonstrate a different contrast origin for domain boundaries and domains themselves. It is shown that the electron-beam irradiati…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Electron beam technology—SEM to microcolumn

T. H. P. Chang、M. G. R. Thomson、Mingzhu Yu 等 8 位作者1996-09-01Microelectronic Engineering

As a continued effort to improve the performance of low energy scanning electron probe systems for application in microscopy, lithography, metrology, etc., miniaturized electron beam columns, approximately 3 mm in length, demonstrating a probe size of 10 nm with a beam current of ≥1 nA at 1 keV, have been successfully…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesIntegrated Circuits and Semiconductor Failure Analysis

Schlieren Textures in Biaxial Nematic Liquid Crystals

S. Chandrasekhar、Geetha G. Nair、Klaüs Praefcke 等 4 位作者1996-09-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

The optical textures exhibited by the mesophases of three compounds, all of which are reported to show the biaxial nematic phase, have been examined. The textures are of the usual nematic schlieren type, except that they consist entirely of disclinations of strength |s| = 1/2. It is suggested that the absence of discl…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Molecular Characterisation of Formamidase from Methylophilus methylotrophus

Neil R. Wyborn、James Mills、Steven G. Williams 等 4 位作者1996-09-01European Journal of Biochemistry

A 3.2-kbp PstI fragment of DNA encoding formamidase from the methylotrophic bacterium Methylophilus methylotrophus which had previously been cloned (pNW3) [Wyborn, N.R., Scherr, D.J. & Jones, C.W. (1994) Microbiology 140, 191-195], was subcloned as a 2.3 kbp HindIII fragment (pNW323). Nucleotide sequencing showed that…

Enzyme Structure and FunctionEnzyme Production and CharacterizationBiochemical and Molecular Research

Furo-fused 2H-chromenes: synthesis and photochromic properties

Jean‐Luc Pozzo、André Samat、Robert Guglielmetti 等 5 位作者1996-09-01Canadian Journal of Chemistry

New photochromic chromenes annulated with a furan ring have been synthesized. Thus, suitable heterocyclic phenols react with different propargylic alcohols in acidic medium to give the corresponding ethers, which cyclize into benzopyrans by thermal Claisen rearrangement. This synthetic approach was found to lead to a…

Photochromic and Fluorescence ChemistrySynthesis of Indole DerivativesSynthesis of Organic Compounds