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Bubbles creeping in a viscous liquid along a slightly inclined plane

Pascale Aussillous、David Quéré2002-08-01Europhysics Letters (EPL)

We describe the upwards movement of an air bubble creeping along a slightly inclined plane immersed in a viscous liquid which totally wets the solid. After characterizing the shape of the static bubble under a horizontal plane, we tilt the plane and study the resulting motion. The bubble reaches a steady velocity, whi…

Fluid Dynamics and MixingInnovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilization

Crystallization of Layered Double Hydroxides by Ultrasound and the Effect of Crystal Quality on Their Surface Properties

Yoshimi Seida、Yoshio Nakano、Yasuo Nakamura2002-08-01Clays and Clay Minerals

Abstract The ultrasound technique was applied to the synthesis of layered double hydroxides. The use of ultrasound in the synthesis of these compounds was studied in terms of its effect on their crystal qualities and surface properties. The crystal qualities of the compounds synthesized with ultrasound were compared w…

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsIndustrial Gas Emission Control

Liposomes for Intravenous Drug Targeting: Design and Applications

Josbert M. Metselaar、Enrico Mastrobattista、Gert Storm2002-08-01Mini-Reviews in Medicinal Chemistry

Drug targeting with liposomes has been studied for over 25 years and has demonstrated its value in clinical practice. This mini review offers an overview of the design and application of liposomes for i.v. drug targeting. Two approaches are outlined: passive and active targeting. The former approach is based on liposo…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene Delivery

Synthesis and Characterization of Poly(methyl acrylate) Grafted from Poly(thiophene) to Form Solid-State Fluorescent Materials

Philip J. Costanzo、Kristoffer K. Stokes2002-08-01Macromolecules

This paper describes the synthesis and characterization of graft copolymers having a poly(thiophene) (PT) backbone with poly(methyl acrylate) (pMA) sidearms. Thiophene monomer containing a protected alcohol group was prepared and polymerized via the McCullough method to yield regioregular PT. The backbone was then fun…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsMolecular Junctions and Nanostructures

Evidence for Bulk Residual Stress Strengthening in Al 2 O 3 /SiC Nanocomposites

L. Ferroni、Giuseppe Pezzotti2002-08-01Journal of the American Ceramic Society

The fracture behavior of Al 2 O 3 /SiC nanocomposites has been studied as a function of the SiC volume fraction and compared to that of the pure Al 2 O 3 matrix. A pronounced strengthening effect was only observed for materials with low SiC content (i.e., ≤10 vol%) although no evidence of concurrent toughening was fou…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesBoron and Carbon Nanomaterials Research

Synthesis of biodegradable copolymers with low‐toxicity zirconium compounds. III. Synthesis and chain‐microstructure analysis of terpolymer obtained from L‐lactide, glycolide, and ϵ‐caprolactone initiated by zirconium(IV) acetylacetonate

P. Dobrzyński2002-08-01Journal of Polymer Science Part A Polymer Chemistry

Abstract Zirconium(IV) acetylacetonate [Zr(acac) 4 ] is a very good initiator for the terpolymerization of glycolide with L‐lactide and ϵ‐caprolactone. The microstructure of the obtained terpolymer was determined by NMR spectroscopy and then compared with terpolymers obtained in the presence of stanous(II) octoate [Sn…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Prediction of Rare‐Earth A 2 Hf 2 O 7 Pyrochlore Phases

Christopher R. Stanek、Robin W. Grimes2002-08-01Journal of the American Ceramic Society

Within the series of A 2 O 3 ‐HfO 2 phase diagrams (A ranges in cationic radius from Lu 3+ to La 3+ ), only those from Gd 2 Hf 2 O 7 to La 2 Hf 2 O 7 are known to exhibit a pyrochlore phase field. For A cations smaller than Gd 3+ , only a disordered fluorite phase field exists. Disorder energies for the entire series…

Advanced Condensed Matter PhysicsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Tumor-targeting, Systemically Delivered Antisense HER-2 Chemosensitizes Human Breast Cancer Xenografts Irrespective of HER-2 Levels

Antonina Rait、Kathleen F. Pirollo、Laiman Xiang 等 5 位作者2002-08-01Molecular Medicine

BACKGROUND: The failure to respond to chemotherapy is a major obstacle in the successful treatment of breast cancer. We have previously shown that anti-HER-2 antisense oligonucleotide (AS HER-2 ODN) treatment was able to sensitize breast cancer cells to various chemotherapeutic agents in vitro irrespective of their HE…

Nanoparticle-Based Drug DeliveryProtease and Inhibitor MechanismsRNA Interference and Gene Delivery

Structure and composition of electrochemically prepared oxide layers on Co in alkaline solutions studied by XPS

Annette Foelske、Hans‐Henning Strehblow2002-08-01Surface and Interface Analysis

Abstract Passive layers on cobalt were prepared in 0.1 N NaOH (pH 13) under potentiostatic control with systematic variation of the relevant parameters, such as time and potential, and examined by x‐ray photoelectron spectroscopy (XPS). The electrochemical preparation of the sputter‐cleaned samples and their transfer…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides

Synthesis of CeO2 Spherical Fine Particles by Homogeneous Precipitation Method with Polyethylene Glycol

Naofumi Uekawa、Masayuki Ueta、Yong Jun Wu 等 4 位作者2002-08-01Chemistry Letters

Abstract CeO2(IV) fine particles were prepared by heating a polyethylene glycol solution of Ce(NO3)3·6H2O at 383 K for 3 h. When a polyethylene glycol whose molecular weight was 7500 or 20000 was used for the preparation, the obtained CeO2 particles were almost monodispersed.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Rayleigh–Taylor instability of violently collapsing bubbles

Hao Lin、Brian D. Storey、Andrew J. Szeri2002-08-01Physics of Fluids

In a classical paper Plesset has determined conditions under which a bubble changing in volume maintains a spherical shape. The stability analysis was further developed by Prosperetti to include the effects of liquid viscosity on the evolving shape modes. In the present work the theory is further modified to include t…

Fluid Dynamics and MixingFluid Dynamics and Heat TransferUltrasound and Cavitation Phenomena

Possibility of Radiation-Induced Degradation of Concrete by Alkali-Silica Reaction of Aggregates

Tsuneki Ichikawa、Hitoshi Koizumi2002-08-01Journal of Nuclear Science and Technology

The effect of Ar ion irradiation on the reactivity of crystalline and amorphous quartz to alkali has been examined for clarifying whether radiation from nuclear reactors accelerates the degradation of concrete by inducing alkali-silica reaction of aggregates. Distorted amorphous quartz generated on the surface of quar…

Concrete and Cement Materials ResearchGlass properties and applicationsNuclear materials and radiation effects

An Assessment of Covalent Grafting of RGD Peptides to the Surface of a Compliant Poly(Carbonate-Urea)Urethane Vascular Conduit versus Conventional Biological Coatings: Its Role in Enhancing Cellular Retention

B Krijgsman、Alexander M. Seifalian、Henryk J. Salacinski 等 7 位作者2002-08-01Tissue Engineering

The aim of sodding prosthetic grafts with endothelial cells (EC) is to establish a functioning antithrombogenic monolayer of EC. Application of basement membrane proteins improves EC adherence on ePTFE grafts. Their addition to a biodurable compliant poly(carbonate-urea)urethane graft (CPU) was studied with respect to…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesTissue Engineering and Regenerative Medicine

Semiconducting properties of oxide and passive films formed on AISI 304 stainless steel and Alloy 600

M.G.S. Ferreira、M. Da Cunha Belo、N. E. Hakiki 等 6 位作者2002-08-01Journal of the Brazilian Chemical Society

The semiconducting properties of passive films formed on AISI 304 stainless steel and Alloy 600 in borate buffer solution were studied by capacitance (Mott-Schottky approach) and photocurrent measurements. Oxide films formed on 304 stainless steel in air at 350 ºC have also been studied. The results obtained show that…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Cobalt(II)/(III) Complexes Containingo-Iminothiobenzosemiquinonato(1−) ando-Iminobenzosemiquinonato(1−) π-Radical Ligands

Diran Herebıan、Prasanta Ghosh、Hyungphil Chun 等 6 位作者2002-08-01European Journal of Inorganic Chemistry

The coordination chemistry of 6-amino-2,4-di-tert-butylthiophenol (H[LSAP]) and of 2-anilino-4,6-di-tert-butylphenol (H[LOAP]) with cobalt(II) ions was investigated in the presence and absence of dioxygen. It was shown that both compounds were redox-non-innocent ligands, existing in different protonation and oxidation…

Metal complexes synthesis and propertiesMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

High performance films: Review of new materials and trends

M. L. Friedman、Gerard Walsh2002-08-01Polymer Engineering and Science

Abstract This paper reviews some modern aspects and trends in the development of high performance polymer materials and processing technologies providing fabrication of advanced film and film structures. Changes in understanding of technical requirements and properties, along with novel approaches in creating high per…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Simulating Tethered Polymer Layers in Shear Flow with the Dissipative Particle Dynamics Technique

Christopher M. Wijmans、Berend Smit2002-08-01Macromolecules

The dissipative particle dynamics (DPD) method is used to simulate shear flow between two flat plates. To test this technique, simulations were conducted of both constant and oscillatory shear of a simple fluid. The results of these simulations agree well with theoretical predictions. We subsequently applied our model…

Polymer Surface Interaction StudiesBlock Copolymer Self-AssemblyNanopore and Nanochannel Transport Studies

Faraday Rotation Effect of Highly Tb2O3/Dy2O3-Concentrated B2O3−Ga2O3−SiO2−P2O5 Glasses

Tomokatsu Hayakawa、Masayuki Nogami、Nobuyuki Nishi 等 4 位作者2002-08-01Chemistry of Materials

A large amount of Tb2O3 and Dy2O3 has successfully been incorporated into a borate glass with a molar composition of 5B2O3−3Ga2O3−3SiO2−P2O5. Raman scattering analysis revealed the existence of isolated orthborate (BO3)3- groups with increasing rare-earth content. The obtained glass exhibited an excellent Faraday rota…

Glass properties and applicationsCrystal Structures and PropertiesMagneto-Optical Properties and Applications

Orientation-induced crystallization in isotactic polypropylene melt by shear deformation

Rajesh H. Somani、Ling Yang、Igors Šics 等 9 位作者2002-08-01Macromolecular Symposia

Development of orientation-induced precursor structures (nuclei) prior to crystallization in isotactic polypropylene melt under shear flow was studied by in-situ synchrotron small-angle X-ray scattering (SAXS) and rheo-optical techniques. SAXS patterns at 165°C immediately after shear (rate = 60 s−1, ts = 5 s) showed…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Transfer Wicking Mechanisms of Knitted Fabrics Used as Undergarments for Outdoor Activities

Q. Zhuang、S.C. Harlock、D.B. Brook2002-08-01Textile Research Journal

This study investigates liquid transfer from fabric layer to layer and liquid interaction between different fabrics in clothing systems. A higher external pressure leads to an early onset of transfer wicking. There exists an optimum value of external pressure for the maximum water transfer. The greater the water conte…

Interactive and Immersive DisplaysDyeing and Modifying Textile FibersTextile materials and evaluations