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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure and magnetism of monomeric chlorobis(N-(2-phenylethyl)salicylideniminato)iron(III), Fe(SANE)2ClCharles J. Magurany and Charles E. StrouseCite this: Inorg. Chem. 1982, 21, 6, 2348–2350Publication Date (Print):June 1, 1982Publication History Published online1 May 200…
Abstract The process of determining the overlapping peaks in complex X‐ray photoelectron spectra of polymer surfaces is posed mathematically as an inverse problem whose solution can be reduced to a standard least‐squares procedure. Various models can be generated by assuming specific forms for the distribution of effe…
Abstract Vinyl chloride‐ethylene copolymers containing from 1.0 to 5.5 wt.% ethylene were synthesized and compounded with DOP plasticizer at levels of 0, 5, 10, 20, 30, and 40 parts per hundred parts of resin. Physical property tests indicated that, as an internal plasticizer, ethylene was 2 to 3 times more efficient…
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An investigation has been made of the feasibility of grading an electric field by means of electrically active particulate fillers in polymeric matrix materials. Concepts investigated included linear resistive, nonlinear resistive and capacitive grading. This paper describes the design, fabrication and electrical eval…
Abstract PVC is a notch‐sensitive polymer. The drop weight impact strength is also lost dramatically below 0°C. This requires special formulation considerations for critical applications. The general trend is to use polymeric impact modifiers, which are rubbery, graft polymers or blends of both hard and rubbery materi…
Abstract The paper presents the first experimental results of the equation of state and its derivatives such as isothermal compressibility, thermal expansion coefficient and thermal pressure coefficient for fluid sulphur which extend over the entire liquid‐vapour range, including the supercritical region up to 1200°C…
Abstract UF 6 , UF 5 and UF 4 have been studied by X‐ray photoelectron spectroscopy. U 4f 7/2 binding energies for these compounds were observed to be 384.9, 383.4 and 382.3 eV, respectively. The corresponding U 4f 5/2 energies were 395.7, 394.2 and 393.2 eV. Solid UF 6 was formed by condensation of a molecular beam o…
Abstract The red, diamagnetic complex [Mo(NO)(terpy)(CN)(HNO)] • 2H 2 O crystallizes in the triclinic space group P1̅(C 1 i -No2) with cell constants a = 867.1(3), b = 1008.4(4), c = 1095.6(3) pm, a = 73.64(3)°, β = 83.54(3)°, γ = 83.16(3)°, and Z = 2. The final R value of the single crystal X-ray analysis is 0.063 fo…
The temperature dependence of the generalized order parameter, namely the rotation angle of the Nb${\mathrm{O}}_{6}$ octahedron, at the antiferrodistortive transition in the perovskite crystal NaNb${\mathrm{O}}_{3}$, is derived through the high-resolution analysis of the second-order quadrupole shift of $^{23}\mathrm{…
Abstract The influence of the degree of polymerization (DP) of cellulose was evaluated in the preparation of micron‐sized cellulose IV II lamellar crystals in order to ascertain whether a regular chain‐folded morphology could develop during their growth. For this purpose, sharp fractions of cellulose acetate were coll…
Abstract Ferruginous clay partings in limestones of the marine, largely evaporitic, Upper Triassic Mohila Formation (Makhtesh Ramon, Israel) contain hexagonal plates and cube-like bodies up to one millimeter across. Analyses by electron microscopy, infrared and Mössbauer spectroscopy, and X-ray powder diffraction indi…
Stress corrosion cracking (SCO) investigations of sensitized 304 austenitic stainless steel were conducted using U-bend specimens of 6.45 and 12.85 mm radii of curvature in Samans solution, which represents the polythionic acid solution formed in the petroleum refineries during shutdown as a result of the interaction…
The dispersion of samples of calcium-saturated soil clay, calcium illite, and calcium bentonite was compared with the dispersion of sodium clays. Each clay was first freed of electrolytes, one sample of each being dialysed with water and a second washed with ethanol. All samples were then dried at 105°C. The dialysed…
The foam finishing technology (FFT) process is a novel application system for treating porous substrates with foamed chemicals at very low wet pickups. It involves the use of a rapidly-breaking low-density foam or froth as the delivery medium for finishing chemicals, precise metering and flow control for delivery of f…
The results are presented of an earlier analysis of a triaxial fabric by extension of the classical results of Peirce and Grosberg. Using the geometrical model of this earlier work, a theoretical analysis is presented in which the work necessary to deform the fabric is approximated by the change in strain energy in th…
The mechanism of coercivity in Fe-Cr-Co permanent magnet alloys has been investigated. An attempt has been made to separate the contribution to Hc of various mechanisms and microstructural variables by comparing spherical versus elongated particle morphology and aligned versus random distribution with varying particle…
A general method for the solution of ac low frequency electric fields in insulating systems is proposed. The method is based on decoupling Maxwell's equations, and their solution can beimplemented analytically or numerically. The finite difference numerical method is easily implemented to solve the field in polluted i…
We discuss the development of an original method preparing thermoluminescent dosimeters using magnesium borate and calcium sulfate materials activated with rare earths. This method is based upon the effect of sensitized thermoluminescent emission of basic TLD phosphors as well as on the method for producing these in s…
In concentrated solutions of sodium silicate with SiO 2:Na 2 O ratios ranging from 2:1 to 4:1, about 75% of the silica is present as extremely small particles which increase from 1 to 2 nm in diameter with increasing ratio. It is suggested that the ionized surface of the particles is covered with an absorbed monolayer…