Materials Literature
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We report a method for the fabrication of nanoporous nanowires with high surface area and well-defined pore morphology. The nanoporous nanowires are formed in a two-step process involving electrochemical deposition of a single-phase, two-component AxB1−x alloy into a nanoporous template, and subsequent chemical etchin…
We study transmission at a boundary between a right-handed medium (RHM: epsilon>0, mu>0) and a frequency dispersive left-handed medium [LHM: epsilon(omega)<0, mu(omega)<0 for some omega], both homogeneous and isotropic. In order to account for the dispersion, two types of signal spectra are considered. The first consi…
Following the discovery of fullerenes and carbon nanotubes, it was shown that nanoparticles of inorganic layered compounds, like MoS2, are unstable in the planar form and they form closed cage structures with polyhedral or nanotubular shapes. Various issues on the structure, synthesis, and properties of such inorganic…
Nanosized inverted domain dots in ferroelectric materials have potential applications in ultrahigh-density rewritable data storage systems. Here, a data storage system based on scanning nonlinear dielectric microscopy and thin films of ferroelectric single-crystal lithium tantalite is presented. Through domain enginee…
Transport properties of artificial solids composed of colloidal CdSe nanocrystals (NCs) are studied from 6 to 250 K, before and after annealing. After the solids are annealed, three changes are observed. First, transmission electron micrographs show that the separation between NCs decreases with annealing. Second, the…
X-ray diffraction, UV-vis absorption and photoluminescence (PL) spectroscopy have been used to study the well-known order-disorder transition (ODT) to the beta phase in poly(9,9-(di n,n-octyl)fluorene)) (PF8) thin film samples through combination of time-dependent and temperature-dependent measurements. The ODT is wel…
We disagree with a number of statements by Dolinsek et al. about the specificity of phason dynamics in quasicrystals (QCs).
Three-dimensional ultrathin polymer shells have been produced by a combination of step-by-step adsorption of polyelectrolytes on glutaraldehyde-treated human erythrocytes and subsequent solubilization of the cytoplasmatic constituents by means of a deproteinizing agent. The obtained hollow films preserve both the size…
The dynamic properties of suspensions of rodlike cellulose microcrystallites (whiskers) are investigated using polarized and depolarized dynamic light scattering (DLS, DDLS) and transient electric birefringence (TEB). The whiskers were prepared by controlled sulfuric acid hydrolysis from cotton and tunicate cellulose…
This is a reply to cond-mat/0211660 by A.K. Taganstev, which consists of a set of criticisms of our publications on polarisation fatigue in Applied Physics Letters. Although his comments were rejected by Applied Physics Letters more than two years ago, Dr Tagantsev has published them in this archive on 29/11/2002. We…
We report the fabrication and the operation of nanomechanical resonant structures in nanocrystalline diamond. For this purpose, continuous diamond films as thin as 80 nm were grown using microwave plasma enhanced chemical vapor deposition. The lateral dimensions of the fabricated structures were as small as 50 nm and…
We observed high and persistent spontaneous buildup of the surface potential (SP) upon vacuum deposition of tris(8-hydroxyquinolinato) aluminum(III) (Alq3) on an Au substrate under dark conditions. SP determined by the Kelvin probe method reached 28 V at a thickness of 560 nm and the surface of the Alq3 film was posit…
A theoretical model is presented for low-frequency magnetoelectric (ME) effects in bilayers of magnetostrictive and piezoelectric phases. An approach is proposed for the consideration of actual boundary conditions at the interface. An averaging method is used to estimate effective material parameters. The model predic…
A stable ternary inclusion complex comprising a host, an electron donor, and an electron acceptor with a long alkyl tail (see schematic representation) triggers the spontaneous formation of giant vesicles (see TEM image). The ternary complex behaves as a supramolecular amphiphile with a large polar head group and a si…
A new link in the chain: After a long period of inactivity, research into one-dimensional compounds based on linear arrays of transition metals is experiencing a renaissance. Recently, oligomeric and polymeric chains have been reported for a variety of transition metals. One such compound of a particularly exotic vari…
Experimental measurements of the viscosity of silica (SiO2) are critically examined; the best measurements show an activation energy of 515 kJ/mole above 1400 °C and 720 kJ/mole below this temperature. The diffusion of silicon and oxygen in silica have temperature dependencies close to that of the high temperature vis…
Carbon nanotubes were discovered in 1991. It was soon recognized that layered metal dichalcogenides such as MoS2 could also form fullerene and nanotube type structures, and the first synthesis was reported in 1992. Since then, a large number of layered chalcogenides and other materials have been shown to form nanotube…
Easily accessible [(salen)(iPrO)Al] exerts excellent molecular-weight and stereochemical control in lactide polymerization either in solution or in the absence of solvent. The R,R initiator shows a marked preference for L-lactide over D-lactide. Stereoblock copolylactides (see scheme) with high melting points can be p…
Correlation consistent basis sets for accurately describing core–core and core–valence correlation effects in atoms and molecules have been developed for the second row atoms Al–Ar. Two different optimization strategies were investigated, which led to two families of core–valence basis sets when the optimized function…
Article Anwendung der Rasterelektronenmikroskopie und der Transmissionselektronenmikroskopie in der Halbleiterindustrie / Application of Scanning Electron Microscopy and Transmission Electron Microscopy in Semiconductor Industry was published on December 1, 2002 in the journal Practical Metallography (volume 39, issue…