Materials Literature
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A detailed study on the pseudomorphic conversion of ordered mesoporous Co(3)O(4) and ferrihydrite into CoO and Fe(3)O(4), respectively, by using alcohol/water vapor as a gentle reducing agent is described. The reduction conditions for the transformation were optimized. In addition, the first one-pot synthesis of mesos…
Abstract Zinc nitride films were deposited on glass or silicon substrates by reactive magnetron RF sputtering of zinc in N 2 –Ar ambient. The deposition conditions were optimized in terms of substrate temperature and N 2 /Ar sputtering gas ratio, and representative films were then studied by structure, optical and spe…
Two new hydrated borates Sr(3)B(6)O(11)(OH)(2) (1) and Ba(3)B(6)O(11)(OH)(2) (2) were hydrothermally synthesized. Their structures were determined by single-crystal X-ray diffraction and further characterized by IR, powder XRD, and DSC/TGA. Compound 1 crystallizes in the triclinic space group P-1 with unit cell parame…
We present metamaterial-induced transparency (MIT) phenomena with enhanced magnetic fields in hybrid dielectric metamaterials. Using two hybrid structures of identical-dielectric-constant resonators (IDRs) and distinct-dielectric-constant resonators (DDRs), we demonstrate a larger group index (ng~354), better bandwidt…
Herein, we demonstrate a new approach towards the construction of supercapacitors consisting of carbon nanotubes (CNTs) and conducting polymers (ECPs) with high specific power, high specific energy, and stable cycling performance through a 3D design of a thin film of polyaniline (PANI) on an aligned small carbon nanot…
In present article, we disclose a fast switchable grating based on nematic liquid crystals. A fine striped electrode has been exploited to generate the grating profile and a driving scheme to drive the grating cell has also been proposed, which enable us to drive the cell up to very high frequency (∼2 kHz) with eviden…
We analyse the optical activity in twisted dimers, the meta-atoms of a chiral metamaterial, by introducing a simple yet accurate model for the coupling between them. The near-field interaction coefficients are derived from a Lagrangian model and include the effects of retardation, whereas the far-field radiation is ba…
Goldatomen auf der Spur: Bilder von einkernigen Goldkomplexen auf Zeolith-NaY-Trägermaterialien, die mit aberrationskorrigierter Rasterelektronenmikroskopie erhalten wurden, zeigen bei atomarer Auflösung der Goldatome, wo sich die Goldkomplexe im Zeolithgerüst befinden (siehe Bild), und belegen, dass sie die katalytis…
Diarylethene derivatives incorporating an azulene ring at the ethene moiety were synthesized. One derivative having thiazole rings showed the expected coloration reaction by excitation at 313 nm (to a higher singlet state) but not when excited at 635 nm (S(0) to S(1) excitation). The system demonstrates that the cycli…
Electron paramagnetic resonance (EPR), optical absorption, and FT-IR spectra of vanadyl ions in the sodium-lead borophosphate (Na(2)O-PbO-B(2)O(3)-P(2)O(5)) (SLBP) glass system have been studied. EPR spectra of all the glass samples exhibit resonance signals characteristic of VO(2+) ions. The spin Hamiltonian paramete…
Monitoring of stresses in in-service steel structural components is challenging, but crucial to structural safety and health evaluation. Elasto-magnetic (EM) sensors are promising for stress monitoring of steel structural components, because of their great capabilities for actual stress measurement, noncontact monitor…
A new metric is proposed to improve the fidelity of structures refined against precession electron diffraction data. The inherent dynamical nature of electron diffraction ensures that direct refinement of recorded intensities against structure-factor amplitudes can be prone to systematic errors. Here it is shown that…
ABSTRACT We report on the performance of biomimicked antireflection coating applied to dilute nitride solar cell. The coating consists of nanostructures replicating the moth‐eye geometry and has been fabricated by nanoimprint lithography directly within the window layer covering the dilute nitride absorbing junction.…
Vertical nanorod assembly over three dimensions is shown to result in the formation of Moiré interference patterns arising from rotational offsets between respective monolayer sheets. Six distinct patterns are observed in HRTEM and angular dark-field STEM (DF-STEM) images, allowing the exact angle of rotation to be de…
The bioinspired approach to the construction of well-ordered microstructures is a crucial intersection of the branches of materials science and biotechnology. In this study, size-tunable silver nanoparticles (Ag NPs) have been successfully prepared on a skin collagen fiber (SCF) biotemplate, which shows a hierarchical…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation V. Quemener, L. Vines, E. V. Monakhov, B. G. Svensson; Evolution of deep electronic states in ZnO…
The electrochemical behavior of highly crystallized single-walled carbon nanotubes (SWCNTs), having a small diameter distribution, is investigated by cyclic voltammetry (CV), using triethylmethylammonium tetrafluoroborate in propylene carbonate as an electrolyte. Unlike the CV curves previously observed by other resea…
The doping of graphene molecules by borazine (B(3)N(3)) units may modify the electronic properties favorably. Therefore, the influence of the substitution of the central benzene ring of hexa-peri-hexabenzocoronene (HBC, C(42)H(18)) by an isoelectronic B(3)N(3) ring resulting in C(36)B(3)N(3)H(18) (B3N3HBC) is investig…
Abstract The influence of an applied compressive stress on the hysteresis curve and domain structure in conventional (1 1 0) [0 0 1] Fe–3%Si steel cut transverse to the rolling direction is studied. Quasistatic hysteresis loops under compressive stress up to 75 MPa were measured. The magnetic domains and magnetization…
Nanoporous and nanostructured materials are becoming increasingly important for advanced applications involving, for example, bioactive materials, catalytic materials, energy storage and conversion materials, photonic crystals, membranes, and more. As such, they are exposed to a variety of harsh environments and often…