Materials Literature
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Abstract Solar‐to‐hydrogen conversion based on photocatalytic water splitting is a promising pathway for sustainable hydrogen production. The photocatalytic process requires highly active, inexpensive, and earth‐abundant materials as photocatalysts. As a presentative layer‐structured transition metal dichalcogenides,…
The syntheses of TiO 2 nanomaterials have attracted great interest due to their importance of wide area application. In this study a novel synthesis of TiO 2 NPs and mesoporous silica nanoparticle (MSNPs) sol-gel method has employed. The TiO 2 @SiO 2 nanocomposites were modified and decorated with Ag NPs by the chemic…
In recent years the utilization of secondary metabolites from plant extract has emerged as novel technology for the synthesis of various nanoparticles. In this manuscript synthesis of palladium nanoparticles (PdNPs) by using Terminalia bellirica fruit extract as reducing agent and capping agent. The synthesized PdNPs…
A novel molecular heterospin system composed of high-spin MnII (S = 5/2) and (3,5-dichloro-4-pyridyl)bis(2,4,6-trichlorophenyl)methyl radical (PyBTM; S = 1/2) was developed. The MnII ion formed distorted octahedral coordination geometry with two PyBTM radicals coordinated in the trans configuration. Magnetic studies d…
Cadmium Oxide and Bi doped Cadmium Oxide thin films are prepared by using the chemical spray pyrolysis technique a glass substrate at a temperature of (400?C) with volumetric concentration (2,4)%. The thickness of all prepared films is about (400±20) nm. Transmittance and Absorbance spectra are recorded in the wave le…
The discovery of magnetism at the LaAlO3/SrTiO3 heterostructures has attracted a lot of interests in regards to the origin of magnetic properties appearing in this nonmagnetic system. In this paper, the existence of a robust ferromagnetic state in the LaAlO3/SrTiO3 heterostructures is demonstrated. The oxygen vacancy…
ABSTRACT Alternative materials have long been studied and developed to replace conventional skin dressings with the emergence of new biopolymers and development of polymeric film fabrication techniques. As a new material for polymeric dressings, films of poly(hydroxybutyrate) (PHB) blended with esterified alginate (AL…
Nanomaterials ferrites have applications in making permanent magnets, high density information devices, color imaging etc. In the present examination, lithium ferrite is synthesized by sol-gel process. The x-ray diffraction (XRD) result shows that the structure of lithium ferrite is monoclinic structure. The average p…
ABSTRACT The demand for biobased barrier packaging alternatives is constantly growing. Poly(lactic acid) (PLA)‐based polymers are one of the most extensively studied biomass‐derived synthetic polymers; however, they typically lack water‐barrier properties. We synthesized a copolymer of d,l‐lactic acid, 1,4‐butanediol,…
Abstract Nonwoven fibrous mats of polyaniline/carbon black on conducting substrates are synthesized through a two‐step oxidative process. Adsorbed and catalyzed aniline monomers in the synthesis process improved the doping degree (0.381) in the hybrid fibers. The formation of a porous mat on substrates was confirmed b…
A parameterization of the ReaxFF reactive FF is performed using a Monte Carlo Simulated Annealing procedure for the modeling of a proline-catalyzed aldol reaction. Emphasis is put on the accurate reproduction of the relative stabilities of several key intermediates of the reaction, as well as, on the description of th…
Abstract Mesoporous hollow carbon nanospheres (MHCS) have been extensively studied owning to their unique structural features and diverse potential applications. A surfactant‐free self‐assembly approach between resorcinol/formaldehyde and silicon alkoxide has emerged as an important strategy to prepare MHCS. Extending…
Abstract To fabricate gelatin films with excellent mechanical and thermal properties, nanoscale hydroxyapatite (nHA) was introduced into a gelatin matrix. The effect of added nHA content (0–20 wt %) on the physicochemical properties of the nHA‐gelatine films was investigated. Morphology analyses confirmed that the nHA…
ABSTRACT In the present work, we have electrochemically deposited polyaniline nanowires (PANIS) on glassy carbon electrode (GCE) from its monomer liquid crystalline template of anilinium‐3‐pentadecyl phenyl sulphonic acid (An+ PDPSA−). Further, electrode was modified by the electrochemical patterning of gold nanoparti…
ABSTRACT In this article, we report the synthesis of a new bimodal surface ligand morphology on silica nanoparticles. Combining grafting‐to and grafting‐from approaches, in this study, we demonstrated the efficacy of anthracene surface modification for improving the dielectric breakdown strength (DBS) under alternatin…
Abstract Nanocrystal (NC) morphology, which decides the number of active sites and catalytic efficiency, is strongly determined by the gases involved in synthesis, treatment, and reaction. Myriad investigations have been performed to understand the morphological response to the involved gases. However, most prior work…
ABSTRACT A novel biobased thermoset interpenetrating network was introduced in this study. Epoxidized soybean oil (ESO) and poly(furfuryl alcohol) (PFA) were added to a commercial biobased epoxy resin. It was hypothesized that addition of ESO and PFA can decrease brittleness of bioepoxy resin and also increase biobase…
The cohesive energies of argon in its cubic and hexagonal closed packed structures are computed with an unprecedented accuracy of about 5 J mol(-1) (corresponding to 0.05 % of the total cohesive energy). The same relative accuracy with respect to experimental data is also found for the face-centered cubic lattice cons…
Abstract This paper reports large bathochromic shifts of up to 260 meV in both the excitonic absorption and emission peaks of oleylamine (OLA)-passivated molecule-like (CdSe)34 nanocrystals caused by postsynthetic treatment with the electron accepting Cd(O2CPh)2 complex at room temperature. These shifts are found to b…
The experimental observation of band-to-band tunneling in novel tunneling field-effect transistors utilizing a monolayer of MoS2 as the conducting channel is demonstrated. Our results indicate that the strong gate-coupling efficiency enabled by two-dimensional materials, such as monolayer MoS2, results in the direct m…