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Influence of inhibitor structure and metal/solution interface on the corrosion resistance of the protected metal

S.N. Raicheva、Е. И. Соколова2006-11-01Russian Journal of Electrochemistry

Seven systems of more than 60 compounds with possible inhibiting properties are investigated. Several methods are used: electrochemical, gravimetric, XPS, and SEM analyses. The inhibition efficiency Z is related to the chemical structure of inhibitors (sequences of compounds with regard to Z are found), their electron…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityMaterial Properties and Failure Mechanisms

RELIABLE PZT CMP TECHNOLOGY FOR NOVEL FRAM CAPACITORS

Seong Hee Choi、Hyeongchan Ko、Jungang Heo 等 15 位作者2006-11-01Integrated ferroelectrics

In this paper, we report novel (TE-free) FRAM capacitors using reliable PZT CMP process in order to improve ferroelectric properties and enhance mass productivity by simplifying integration of processes. FRAM capacitors were prepared using a PZT film for a stopping layer in ILD CMP using a high selective slurry having…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsFerroelectric and Negative Capacitance Devices

Densification and Microstructural Behaviour on the Sintering of Blended Elemental Ti-35Nb-7Zr-5Ta Alloy

Elisa B. Taddei、Vinícius André Rodrigues Henriques、Cosme Roberto Moreira Silva 等 4 位作者2006-11-01Materials science forum

Beta titanium alloys, e.g., are now the main target for medical materials. Ti-35Nb-7Zr- 5Ta alloy were manufactured by blended elemental (BE) powder method, which appears to be one of the most promising technique for titanium parts production at reduced cost. The process employs hydrided powders as raw materials with…

Metal and Thin Film MechanicsOrthopaedic implants and arthroplastyTitanium Alloys Microstructure and Properties

Effect of a low frequency electromagnetic field on the direct-chill (DC) casting of AZ80 magnesium alloy ingots

Shijie Guo、Qichi Le、Zhihao Zhao 等 5 位作者2006-11-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract The effects of a low frequency electromagnetic field applied during semi-continuous direct-chill casting on AZ80 ingots were investigated. The experiments were performed both in the absence and in the presence of the electromagnetic field. In contrast to the ingot cast in the conventional process, the microst…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAdvanced Welding Techniques Analysis

Spectroscopic Assessment of Australian Cotton Waxes

Jeffrey S. Church、Andrea L. Woodhead2006-11-01Applied Spectroscopy

An investigation into the spectroscopic analysis of cotton waxes on Australian cottons was undertaken. The chemical composition of cotton wax is complex and contains a number of lipid classes. Infrared transmission spectroscopy coupled with principal component analysis was found to be capable of discriminating between…

Dyeing and Modifying Textile FibersTextile materials and evaluationsColor Science and Applications

Electrical property evaluation of manganese-fluorine codoping of lead zirconate titanate thin films: Compatibility between hard material and piezoelectric activity

M. Detalle、Denis Rémiens、Laurent Lebrun 等 4 位作者2006-11-01Journal of Applied Physics

For some microelectromechanical system (MEMS) applications, the conditions of operation, high temperature, high stress, etc., can be very severe. Under these conditions the piezoelectric performance of polar material can decrease due to a partial (or a total) depoling induced by external excitations. So, it is importa…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Sm2Se5O13: A Selenite–Diselenite according to Sm2(SeO3)(Se2O5)2

Mathias S. Wickleder2006-11-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Pale yellow single crystals of Sm 2 (SeO 3 )(Se 2 O 5 ) 2 (monoclinic, P 2 1 / c , Z = 4, a = 1003.6(2), b = 1022.5(2), c = 1287.3(2) pm, β = 112.3(2)°) were obtained from the reaction of Sm 2 O 3 and SeO 2 at 350 °C in a sealed glass ampoule. In the crystal structure both Se 2 O 5 2− and SeO 3 2− groups conn…

Crystal Structures and PropertiesNuclear materials and radiation effectsMineralogy and Gemology Studies

FREQUENCY DEPENDENCE OF THE DIELECTRIC PROPERTIES AND COERCIVE FIELD OF PbZr0.4Ti0.6O3THIN FILMS

Tianzhi Liu、Zhigang Zhang、Dan Xie 等 6 位作者2006-11-01Integrated ferroelectrics

Frequency dependence of dielectric constant and coercive field are investigated for PbZr0.4Ti0.6O3 (PZT) capacitors. The calculations base on the in-series capacitor model show that the dielectric constant followe an universal-law dependence with various bias, which could be interpreted by constant phase model. The co…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

The common role of water molecule and lone electron pair as a bond-valence mediator in oxalate complexes: the crystal structures of Rb2(C2O4) · H2O and Tl2(C2O4)

Takuya Echigo、Mitsuyοshi Kimata2006-11-01Zeitschrift für Kristallographie - Crystalline Materials

The crystal structure of rubidium oxalate monohydrate, Rb 2 (C 2 O 4 ) · H 2 O, has been refined using an imaging-plate diffractometer system and graphite-monochromatized Mo K α radiation. The complex crystallizes in the monoclinic system, space group C 2/ c , with unit cell dimensions of a = 9.617(6), b = 6.353(5), c…

Glass properties and applicationsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Effects of tungsten and nickel on repassivation rate of stainless steels in chloride solution by electrochemical method

Seongkwan Kim、H. Kim、Ho-Gyu Kwan2006-11-01Materials and Corrosion

Abstract The recent development of the method for analyzing repassivation rate by a rapid scratch test and high field conduction model makes it possible to predict SCC susceptibility more quantitatively but it is impossible to distinguish the repassivation rates with a little difference due to the inaccurate measureme…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Synthesis and photodynamic activity of diaryl-porphyrins characterized by the presence of nitro groups

Stefano Banfi、Enrico Caruso、Emanuele Fieni 等 7 位作者2006-11-01Journal of Porphyrins and Phthalocyanines

A panel of nitro substituted 5,15-diaryl-porphyrins, featuring nitro groups either on the phenyl rings or on one of the two free meso-positions, was synthesized. In the former category, compounds 5-(3-nitrophenyl)-15-phenylporphyrin, 5,15-di(3-nitrophenyl)porphyrin and 5-(4-nitrophenyl)-15-phenylporphyrin were obtaine…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPorphyrin Metabolism and Disorders

Genetic Algorithm Application for Burnable Poison Placement in PWRs with Optimized UO 2 /Gd 2 O 3 Fuel Pin Configurations

Serkan Yιlmaz、Kostadin Ivanov、S.H. Levine 等 4 位作者2006-11-01Nuclear Technology

In this paper, an efficient genetic algorithm has placed burnable poisons (BPs) into all of the fresh fuel positions in the core employing the optimized BP configurations and techniques developed in two previous papers. Of importance was the previous development of a Kinf filter, which greatly reduced the computationa…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesHeat transfer and supercritical fluids

Thermodynamic modeling of the sodium alanates and the Na–Al–H system

Caian Qiu、Susanne M. Opalka、Gregory B. Olson 等 4 位作者2006-11-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract The thermodynamic properties of the Al –Na and Na–Al – H systems have been assessed by combining the “calculation of phase diagram” approach with first-principles predictions. The Gibbs energies of the individual phases were thermodynamically modeled, where the model parameters were obtained from best fit opt…

Hydrogen Storage and MaterialsNuclear Materials and PropertiesThermodynamic and Structural Properties of Metals and Alloys

Fracture behaviour of ultrafine-grained materials under static and cyclic loading

P. Hübner、Rene Kießling、Horst Biermann 等 4 位作者2006-11-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract Fracture-mechanics experiments were carried out on ultrafine-grained (UFG) samples of copper, titanium and an Al alloy to obtain the fracture behaviour under static and cyclic loading. The UFG-materials investigated show crack resistance behaviour under static loading, which was confirmed by ductile fracture…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesHigh-Velocity Impact and Material Behavior

Sintering of Cobalt and Strontium Doped Lanthanum Chromite Obtained by Combustion Synthesis

Luiz Fernando Grespan Setz、Hamilton Perez Soares Corrêa、C.O. Paiva-Santos 等 4 位作者2006-11-01Materials science forum

Lanthanum chromite (LaCrO3) is one of the most adequate materials for use as interconnector in solid oxide fuel cell (SOFC) applications, due to its intrinsic properties, namely its good electrical conductivity and resistance to environment conditions in fuel cell operations. Due to difficulties in sintering, additive…

Advancements in Solid Oxide Fuel CellsNuclear Materials and PropertiesElectronic and Structural Properties of Oxides

A Novel Method to Evaluate Fibre Hornification by High Resolution Thermogravimetric Analysis

Sunkyu Park、Richard A. Venditti、Hasan Jameel 等 4 位作者2006-11-01OpenAlex

Fibre hornification was evaluated by a parameter termed 'hard-to-remove (HR) water content', which was defined as the ratio of water mass to fibre mass at the transition between the constant rate zone and the falling rate zone from the isothermal TGA experiments. The results indicated that the HR water content could b…

Advanced Cellulose Research StudiesTextile materials and evaluationsMaterial Properties and Processing

Antioxidant Properties of Multiwall Carbon Nanotubes: First Measurements Using a Model Oxidative Reaction

Eldar Zeynalov、Joerg F. Friedrich2006-11-01Polymers and Polymer Composites

Carbon nanotubes (CNTs) have electron affinities similar to those of fullerenes and they are therefore capable of acting as radical traps in free radical chain reactions, including polymerisation and the thermo-oxidative degradation of polymers. It is proposed that the CNTs used as integral part of polymer composites…

Carbon Nanotubes in CompositesNanoparticles: synthesis and applicationsFullerene Chemistry and Applications

PROPERTIES OF Nb-AND Mo-MODIFICATED SrBi4Ti4O15 FERROELECTRIC CERAMICS

Can Jin、Jun Zhu、Xiangyu Mao 等 6 位作者2006-11-01Integrated ferroelectrics

An investigation on the ferroelectric and dielectric properties of higher-valent-cations Nb-and Mo-modificated SrBi4Ti4O15 ceramics was presented. The ferroelectric property of SrBi4Ti4O15 was both obviously improved by niobium and molybdenum doping. The remnant polarization (2P r ) of both Nb-and Mo-modificated SrBi4…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

SURFACE POTENTIAL RELAXATION OF FERROELECTRIC DOMAIN INVESTIGATED BY KELVIN PROBE FORCE MICROSCOPY

Jiyoon Kim、Yunseok Kim、Kwangsoo No 等 7 位作者2006-11-01Integrated ferroelectrics

We attempted to investigate the surface potential relaxation of ferroelectric thin film domain by using Kelvin probe force microscopy (KFM). To avoid charge suction phenomenon by a grounded tip, the offset voltage was applied to the base line of the pulse trace. It was found that the surface potential contrast decreas…

Ferroelectric and Piezoelectric MaterialsForce Microscopy Techniques and ApplicationsAcoustic Wave Resonator Technologies

AN EMENDED DESCRIPTION OFDECUSSATA(PATRICK) LANGE-BERTALOT & METZELTIN THAT INCLUDES PROTOPLAST ORGANIZATION AND DETAILED VALVE AND CINGULUM ULTRASTRUCTURE

Mark B. Edlund、Lynn A. Brant、Zlatko Levkov 等 4 位作者2006-11-01Diatom Research

The subgenus DECUSSATA R.M. Patrick was recently elevated to generic status as Decussata (R.M. Patrick) H. Lange-Bertalot & Metzeltin in Lange-Bertalot (2000. Iconographica Diatomologica, 9, 670–673) to accommodate Navicula placenta Ehrenberg and its allies. The description of Decussata is based on characteristics of…

Protist diversity and phylogenyDiatoms and Algae Research