Materials Literature
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Abstract Summary: The preparation of syndiotactic poly(propylene) (sPP) nanocomposites with multi‐walled carbon nanotubes (MWNTs), carbon nanofibers (CNFs), and carbon black (CB) as fillers was accomplished by the in situ polymerization of propylene with a metallocene/methylalumoxane (MAO) catalyst. Different pre‐trea…
Novel protein-based hydrogels have been prepared by blending gelatin (G) with amorphous Bombyx mori silk fibroin (SF) and subsequently promoting the formation of beta-sheet crystals in SF upon exposure to methanol or methanol/water solutions. Differential scanning calorimetry of the resultant hydrogels confirms the pr…
We study the role of defects in the ``single-chain magnet'' CoPhOMe by inserting a controlled number of diamagnetic impurities. The samples are analyzed with unprecedented accuracy with the particle induced x-ray emission technique, and with ac and dc magnetic measurements. In an external applied field the system show…
Systematical molecular statics and dynamics simulations are performed on the interlayer friction and energy dissipation of biwalled carbon nanotubes of different chirality and size, with and without defects. The interlayer friction force of perfect bitube systems is strongly dependent on commensuration and independent…
Abstract Summary: A controlled fabrication of rod‐like nanostructures of cadmium sulfide (CdS) incorporated into polymer fiber matrices has been developed by an electrospinning method. Here, poly(vinyl pyrrolidone) (PVP) was used as a polymer capping reagent, utilizing the interactions of cadmium ions with the carbony…
The electronic and optical properties of carbon nanoscrolls were investigated using a first-principles method based on density functional theory and the local density approximation (LDA). Two models of different sizes were considered and their properties were compared. The nanoscrolls were found to be metallic and sem…
Fluorescent semiconductor nanoparticles, or quantum dots, have potential uses as an optical material, in which the optoelectronic properties can be tuned precisely by particle size. Advances in chemical synthesis have led to improvements in size and shape control, cost, and safety. A limiting step in large-scale produ…
Large-scale well-aligned ZnO nanotubes with outer diameters of 100-300 nm and lengths of tens of micrometres have been prepared by a template-based chemical vapour deposition method. The photoluminescence spectrum of the ZnO nanotube arrays consists of a strong violet band at 414 nm, a blue band at 462 nm and a weak s…
Valencies get remix: A unique kind of electronic structure (Mn+0.5)(μ-L.−)(Mn+0.5) which was previously discussed only for metal–ligand charge-transfer (MLCT) excited states is established structurally and by quantum chemical analysis for both rac (see picture) and meso isomers of [(μ-abpy){Ru(acac)2}2] (abpy=2,2′-azo…
Abstract Summary: The liquid‐liquid phase separation (LLPS) is often coupled with other ordering processes such as crystallization. In a polyolefin blend system, overwhelming changes in crystallization kinetics due to concentration fluctuation caused by spontaneous spinodal LLPS have been observed. Consequently, we ar…
The size control of vertically aligned ZnO nanorod arrays (NRAs) grown by catalyst-free metalorganic chemical vapour deposition is accomplished by changing the O/Zn precursor ratio. At a higher O/Zn precursor ratio, fat ZnO NRAs with excellent alignment are produced. In contrast, slim ZnO NRAs that are considerably le…
Nanoclay-reinforced agarose nanocomposite films with varying weight concentration ranging from 0 to 80% of nanoclay were prepared, and structurally and mechanically characterized. Structural characterization was carried out by transmission electron microscopy (TEM), scanning electron microscopy (SEM) and atomic force…
The compositional ordering of Ag, Pb, Sb, Te ions in ${(\mathrm{Ag}\mathrm{Sb}{\mathrm{Te}}_{2})}_{x}{(\mathrm{Pb}\mathrm{Te})}_{2(1\ensuremath{-}x)}$ systems possessing a NaCl structure is studied using a Coulomb lattice gas (CLG) model on a face-centered cubic (fcc) lattice and Monte Carlo simulations. Our results s…
Abstract Summary: Polycaprolactone (PCL) and starch/PCL blends (SPCL) are shown to have the potential to be used in a range of biomedical applications and can be processed with conventional melting‐based procedures. In this paper, the thermal and thermomechanical analyses of PCL and SPCL were performed, using DSC, opt…
Abstract Summary: An oil‐in‐water high internal phase emulsion consisting of acrylic acid, water, and a crosslinker ( N , N′ ‐methylene bisacrylamide) as the water phase, and toluene as the oil phase was successfully stabilised to sustain thermal initiation of radical polymerisation resulting in porous open‐cellular m…
Abstract Summary: Poly(butylene succinate‐ co ‐adipate) (PBSA) and organically modified montmorillonite (OMMT) nanocomposites of three different compositions were prepared by melt‐extrusion in a batch mixer. The structure of the nanocomposites was studied using X‐ray diffraction (XRD) and transmission electron microsc…
Dilution effects on the long-range ordered state of the doubly degenerate $e_g$ orbital are investigated. Quenched impurities without the orbital degree of freedom are introduced in the orbital model where the long-range order is realized by the order-from-disorder mechanism. It is shown by the Monte-Carlo simulation…
In CuCl bulk crystal negatively charged excitons (trions $X^-$) can be induced by the resonant optical excitation of extra electrons in conduction band minimum. In the case of light polarization and due to the top valence band structure of CuCl only the electrons with spin antiparallel to the direction of the light pr…
In superconducting circuits with interbit untunable (e.g., capacitive) couplings, ideal local quantum operations cannot be exactly performed on individual Josephson qubits. Here we propose an effective dynamical decoupling approach to overcome the "fixed-interaction" difficulty for effectively implementing elemental l…
This paper examines friction as a function of the sliding velocity and applied normal load from air to UHV in a scanning force microscope (SFM) experiment in which a sharp silicon tip slides against a flat Si(100) sample. Under ambient conditions, both surfaces are covered by a native oxide, which is hydrophilic. Duri…