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Proton NMR Studies of Molecular-Level Mobility in Vulcanised and Epoxidised Natural Rubber

Robin K. Harris、Barry J. Say、Soon Ng1996-05-01Polymer International

Proton spin-lattice relaxations in the laboratory and rotating frames, together with transverse relaxation (free induction decay), have been measured for natural and epoxidised rubber, plus a series of vulcanised samples. The data have been analysed by fitting procedures to give characteristic times which are discusse…

Polymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Production of carbonates and hydrates and their use as flame retardant fillers

Roger Rothon1996-05-01Macromolecular Symposia

Abstract Flame retardant fillers are of growing importance as they do not give the high smoke and corrosive gas emissions associated with some other flame retardants The basic characteristics of a flame retardant filler are described, together with the manufacture of the principal commercial types. Experimental result…

Flame retardant materials and propertiesThermal and Kinetic AnalysisEnvironmental and Industrial Safety

X-ray-absorption spectroscopy ofNd3+-exchanged β-alumina crystal

F. Rocca、Alexei Kuzmin、J. Purāns 等 4 位作者1996-05-01Physical review. B, Condensed matter

The results of x-ray-absorption spectroscopy investigations of ${\mathrm{Nd}}^{3+}$ ions in a nearly fully exchanged (93%) sodium \ensuremath{\beta}-alumina crystal are reported. The ${\mathrm{Nd}}^{3+}$ local environment is reconstructed using a multishell best fit procedure and is compared with existing structural m…

Luminescence Properties of Advanced MaterialsRare-earth and actinide compoundsThermal Expansion and Ionic Conductivity

Synthesis and characterization of highly wettable hydrogel coatings for immobilization of marine bacteria

Paul Gatenholm、Jiřı́ Michálek、J. Vacı́k1996-05-01Macromolecular Symposia

Abstract This study evaluates hydrogels based on 2‐hydroxyethyl methacrylate (HEMA) and diethylene glycol ester of methacrylic acid (DEGMA) as candidates for a suitable matrix for immobilizing marine bacteria. Results are presented of investigations of the effect of monomer structure and polymer composition on wettabi…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationPolymer Surface Interaction Studies

Novel Sulfur Vulcanization Accelerators Based on Mercapto-Pyridine, -Pyrazine, and -Pyrimidine

Charles J. Rostek、Horng‐Jau Lin、David J. Sikora 等 6 位作者1996-05-01Rubber Chemistry and Technology

Abstract Sulfur vulcanization accelerators derived from 2-mercaptobenzothiazole (MBT) have been a staple for the rubber processing industry for over 65 years. Most noteworthy are the sulfenamide derivatives, which provide various combinations of scorch delay and cure rate, depending upon the basicity and steric nature…

Synthesis and properties of polymersQuinazolinone synthesis and applicationsSynthesis and Reactivity of Sulfur-Containing Compounds

Smart Materials: A Future for Composites

P. F. Gobin、G. Gutnin、M. Morin 等 5 位作者1996-05-01Journal of Intelligent Material Systems and Structures

Obviously, successive expertises in the processes of elementary materials are milestones which marked the early stages of mankind development (stone-age, bronze-age,...) and it is only since the beginning of the century that materials became multifunctional and required optimization of their different physical, mechan…

Additive Manufacturing and 3D Printing TechnologiesSilicone and Siloxane ChemistryMaterial Selection and Properties

Thermoluminescence Response of AL2O3:C to UV and Ionising Radiation

A.S. Pradhan、Pramod Kumar Sharma、V.K. Shirva1996-05-01Radiation Protection Dosimetry

Al2O3:C has been found to exhibit high thermoluminescence (TL) response to UV radiation in addition to ionising radiation. Though the change in absorption spectra and the process of deposition of energy by UV in Al2O3:C are considerably different from that by ionising radiation, the TL emission and the behaviour of gl…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesNuclear Materials and Properties

Resultant magnetic fields due to both windings and heavy current leads in large power transformers

Tang Renyuan、Yan Li、Lin Feng 等 4 位作者1996-05-01IEEE Transactions on Magnetics

The eddy current field due to both windings and heavy current leads (HCL) in large power transformers is analyzed by using the improved T-/spl Omega/ method, in which T and /spl Omega/ can be solved separately in different subregions. Thus, storage capacity and CPU time can be saved to a great extent. In addition, the…

Magnetic Properties and ApplicationsInduction Heating and Inverter TechnologyPower Systems and Renewable Energy

Structural and chemical characterization of vapor-deposited polythiophene films

T. R. Dillingham、D. M. Cornelison、S. W. Townsend1996-05-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The chemical structure, including changes in charge distribution upon doping, for vapor-deposited polythiophene films has been investigated using x-ray photoelectron spectroscopy (XPS). Two different methods of doping, coevaporation with FeCl3 and exposure to iodine vapor, are contrasted in this study and several chem…

Organic Electronics and PhotovoltaicsCorrosion Behavior and InhibitionConducting polymers and applications

Methane and water soluble iron production under controlled soil pH and redox conditions

A. Jugsujinda、W. H. Patrick1996-05-01Communications in Soil Science and Plant Analysis

When a soil is flooded, iron (Fe) reduction and methane (CH4) production occurred in sequence as predicted by thermodynamics. The dissolution and precipitation of Fe reflected both soil pH and soil redox potential (Eh). The objective of our experiment was to determine both CH4 production and Fe reduction as measured b…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Dissociation of intra/inter-molecular hydrogen bonds of cellulose molecules in the dissolution process: a mini review

Xingya Kang、Shigenori Kuga、Limei Wang 等 5 位作者1996-05-01Journal of Bioresources and Bioproducts

Cellulose is abundant in nature, with the advantages of low-cost, biodegradable and biocompatible, low density and high strength. However, the development and application of cellulose has been lagging behind its potential due to its unique properties. Cellulose has a large quantity of hydroxyl groups which can easily…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Wettability and Adhesion Characteristics of Plasma-Treated Carbon Fibers

Kazuo Tsutsumi、Kazutaka Ban、Kaori Shibata 等 5 位作者1996-05-01The Journal of Adhesion

The surface free energy (γ s ) of modified carbon fibers was determined by tensiometry and effects of CF4-O2 plasma treatment were evaluated. The treatment with the gas mixture in which oxygen was above 40% accelerated preferentially the oxidation of fiber surfaces and the nondispersive component of the surface free e…

Graphene research and applicationsSurface Modification and SuperhydrophobicityFiber-reinforced polymer composites

Goldstone mode and domain mode relaxation in ferroelectric phases of 4′-[(S,S) - 2,3 - epoxyhexyloxy] phenyl 4-(decyloxy)benzoate (EHPDB)

Monika Marzec、R. Dąbrowski、Alicja Fąfara 等 6 位作者1996-05-01Ferroelectrics

Dielectric and electrooptic studies of 4′-[(S,S)-2,3-epoxyhexyloxy] phenyl 4-(decyloxy) benzoate (in short EHPDB) have been done and Goldstone mode (GM) and domain mode (DM) relaxation have been observed. The dielectric measurements have been done in the temperature range between 57˚C and 80˚C covering the N*, SmA*, S…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Parameters of the tip arrays covered by low work function layers

А.А. Еvtukh、В. Г. Литовченко、R.I. Marchenko 等 6 位作者1996-05-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Silicon field emitter arrays have been fabricated and investigated. Four different field emission enhancement layers were studied: (1) porous silicon layers, (2) carbon films, (3) hydrogen implanted layers, (4) Cs-enriched layers. Scanning electron microscopy was used to study the morphology of the tips. Comparison of…

Silicon and Solar Cell TechnologiesSilicon Nanostructures and PhotoluminescenceNear-Field Optical Microscopy

Electron emission observations from as-grown and vacuum-coated chemical vapor deposited diamond

A. Lamouri、Yaxin Wang、G. T. Mearini 等 6 位作者1996-05-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Field emission has been observed from chemical vapor deposited diamond grown on Mo and Si substrates. Emission was observed at fields as low as 20 kV/cm. The samples were tested in the as-grown form, and after coating with thin films of Au, CsI, and Ni. The emission current was typically maximum at the onset of the ap…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Adhesion of Styrene-Butadiene Rubbers with Different Silica Content

Ana M. Torró‐Palau、Juan C. Fernández-Garcı́a、A. César Orgilés-Barceló 等 4 位作者1996-05-01The Journal of Adhesion

The influence of silica content of four styrene-butadiene rubbers on their adhesion to polyurethane adhesives was studied. Untreated rubber shows no adhesion due to a weak boundary layer of zinc stearate. Roughening removed zinc stearate from the rubber surface, increased the surface energy and produced surface roughn…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

A-Pr2S3, D-Ho2S3 und E-Yb2S3:Synthese und Einkristallstrukturuntersuchungen / A-Pr2S3, D-Ho2S3 and E-Yb2S3:Synthesis and Single Crystal Structure Investigations

Thomas Schleid、Falk Lissner1996-05-01Zeitschrift für Naturforschung B

The oxidation of reduced chlorides (MCl 2 ) or chloride-hydrides (MClH x ) of the lanthanides with sulfur (700-850 °C, 7 d, sealed tantalum capsules or evacuated silica vessels) usually results in the formation of the sesquisulfides M 2 S 3 as the main products. In the presence of appropriate fluxes (e.g., alkali hali…

Crystal Structures and PropertiesIron-based superconductors researchInorganic Chemistry and Materials

A freely expanding ring technique for measuring the tensile properties of polymers

N. Al‐Maliky、David Parry1996-05-01Measurement Science and Technology

The measurement of the stress - strain properties of materials at high strain rates is principally carried out using the split Hopkinson pressure bar (SHPB) technique, in which high compressive strain rates, typically in the range , are achievable with small solid discs as the test materials. Torsional SHPB systems ha…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Dielectric properties of ferroelectric liquid crystals

S. Markscheffel、Antal Jákli、A. Saupe1996-05-01Ferroelectrics

We performed dielectric- and electrooptical measurements of a ferroelectric liquid crystal film as a function of temperature, frequency and bias field. Starting with the homeotropic texture, obtained with a silane coating, we measured the dielectric properties in the direction of the helical axis. After realigning to…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation

Inorganic crystal structure database (ICSD) and standardized data and crystal chemical characterization of inorganic structure types (TYPIX) - Two tools for inorganic chemists

E. Fluck1996-05-01Journal of Research of the National Institute of Standards and Technology

The two databases ICSD and TYPIX are described. ICSD is a comprehensive compilation of crystal structure data of inorganic compounds (about 39 000 entries). TYPIX contains 3600 critically evaluated data sets representative of structure types formed by inorganic compounds.

Radioactive element chemistry and processingThermal and Kinetic AnalysisX-ray Diffraction in Crystallography