Materials Literature
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The wide-bandgap semiconducting material, zinc sulfide, has been coated on indium phosphide nanoclusters to a 1-2-Å thickness. The resulting InP-ZnS core-shell particle (as shown in the TEM image; scale 1 cm=5 nm) exhibits bright luminescence at room temperature with quantum efficiencies as high as 23 %.
Hollow polyelectrolyte capsules in micro- and submicrometer size were prepared. Their interior was functionalized by a "ship in bottle" synthesis of copolymers. While the monomers permeated the capsule wall easily, the formed polymers remained in the capsule cage. The physicochemical properties of the capsule interior…
We discuss the design of a Ni−Au nanoparticle catalyst system, which is based on the detailed experimental and theoretical understanding of the alloying and the chemical reaction processes on single-crystal surfaces. The alloy formation and structure of Ni−Au catalysts supported on SiO 2 and on MgAl 2 O 4 are simulate…
Corner-sharing Co3(μ3-OH) triangles make up the framework of two novel compounds obtained by hydrothermal synthesis from CoCl2, NaOH, and benzene-1,2,3-tricarboxylic acid. In the structure (see picture) of one of these—[Co2(OH){1,2,3-(O2C)3C6H3}(H2O)]⋅H2O—octahedral (crosshatched) and tetrahedral (dotted) Co sites alt…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTCoordination Metallacycles of an Achiral Dendron Self-Assemble via Metal−Metal Interaction To Form Luminescent Superhelical FibersMasashi Enomoto, Akihiro Kishimura, and Takuzo AidaView Author Information Department of Chemistry and Biotechnology Graduate School of Eng…
Dendrimers are well-defined hyperbranched macromolecules with characteristic globular structures for the larger systems. These novel polymers have inspired many chemists to develop new materials and several applications have been explored, catalysis being one of them. The recent impressive strides in synthetic procedu…
A series of perylene tetracarboxylic acid bisimides 3a-e bearing 3,4,5-tridodecyloxyphenyl substituents on the imide N atoms and zero, two, or four phenoxy-type substituents in the bay positions of the perylene core were synthesized. From investigations of their spectroscopic properties and aggregation behavior in low…
[see reaction]. A new triphase catalyst has been developed. When an aqueous solution of H3PW12O40 (1) was added to a solution of the amphiphilic chain copolymer 2, a new self-assembled and macroporous complex 3 was formed. This complex was effective as a catalyst in the epoxidation of allylic alcohols. Even in the use…
Nylon-6 polymerization in a VK tube (vertical column) reactor is largely not understood because of the complex internal structure of the reactor and the unavailability of essential industrial data on polymerization. In the present study, the hydrolytic polymerization of nylon-6 has been simulated in an industrial VK t…
Treatment of [Ti(C 5 H 5 )Cl 3 ] with 4-allyl-2,6-dimethoxyphenol ( II ) gave the corresponding aryloxy complex [Ti(C 5 H 5 ){OC 6 H 2 (OMe) 2 (C 3 H 5 )}Cl 2 ] ( 2 ), while hydrosilylation reactions of the allyl group of 4-allyl-2-methoxyphenol (eugenol; I ) or 4-allyl-2,6-dimethoxyphenol ( II ) with HSiEt 3 and subs…
Abstract A mechanistic study of the trans⇆cis isomerization of the azobenzene moiety in a side‐chain liquid‐crystal polymer system was carried out with six liquid‐crystalline polymethacrylates in which different electron‐withdrawing substituents were attached to the para‐positions of the azobenzene chromophores. Compa…
Na- and Ca-exchanged smectite in aqueous suspension have been studied using the polarized attenuated total reflectance (ATR)-FTIR technique. These spectra correspond to the first reported use of polarization methods to study smectite particles in aqueous suspension. Similar to the behavior of hydrous metal oxides, a t…
We calculate ab initio the NMR relaxation rates and the Knight shifts in MgB_2. We show that the dominant relaxation mechanism at the B nucleus is the interaction with the electronic orbital moment, and we give a simple explanation of that using a simple $sp$ tight binding model. When Stoner enhancement (also calculat…
The transverse magnetoresistance of the Bechgaard salt (TMTSF)$_2$PF$_6$ has been measured for various pressures, with the field up to 24 T parallel to the lowest conductivity direction c$^{\ast}$. A quadratic behavior is observed in the magnetic field dependence of the spin-density-wave (SDW) transition temperature $…
The possibility to induce ferromagnetism and insulator to metal transitions in small A site cation manganites Ln_{1-x}Ca_xMnO_3 by rhodium doping is shown for the first time. Colossal magnetoresistance (CMR) properties are evidenced for a large compositional range (0.35 \leq x < 0.60). The ability of rhodium to induce…
We present a detailed study of the exchange-correlation hole and exchange-correlation energy per particle in the Si crystal as calculated by the Variational Monte Carlo method and predicted by various density functional models. Nonlocal density averaging methods prove to be successful in correcting severe errors in th…
The reaction of LiGaMe 4 with diphenysilanediol in THF at 50 °C leads to the formation of the title gallosiloxane Li 2 (Li(THF) 2 ) 2 [Ph 2 SiO 2 GaMe 2 ] 2 [Ph 2 SiO 2 GaMe(OH)] 2 ·2THF ( 1 ), which is made up of a central tetraanionic Ga 4 Si 4 O 8 16-membered macrocyclic core. The cavity that is created by this tet…
A novel synthesis of 3-fold symmetric, homochiral tris(2-alkyl-2-aminoethyl)amine (TREN) derivatives is presented. The synthesis is general in scope, starting from readily prepared chiral alpha-amino aldehydes. The optical purity of the N-BOC protected derivatives of tris(2-methyl-2-aminoethyl)amine and tris(2-hydroxy…
Delta5-3-ketosteroid isomerase (KSI) from Pseudomonas putida Biotype B catalyzes the allylic isomerization of Delta5-3-ketosteroids to their conjugated Delta4-isomers via a dienolate intermediate. Two electrophilic catalysts, Tyr-14 and Asp-99, are involved in a hydrogen bond network that comprises Asp-99 Odelta2...O…
Abstract A series of poly( o ‐hydroxy amide)s having both ether and sulfone linkages in the main chain were synthesized via the low‐temperature solution polycondensation of 4,4′‐[sulfonylbis(1,4‐phenylene)dioxy]dibenzoyl chloride and 4,4′‐[sulfonylbis(2,6‐dimethyl‐1,4‐phenylene)dioxy]dibenzoyl chloride with three bis(…