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Photochemical Degradation Study of Polyurethanes as Relic Protection Materials by FTIR‐ATR

Liqin Wang、Guozheng Liang、Gaochao Dang 等 6 位作者2005-09-01Chinese Journal of Chemistry

Abstract Polyurethanes are one kind of relic protection materials commonly used. During artificial photo‐ageing, three polyurethanes, HDI‐based polyurethane, MDI‐based polyurethane and TDI‐based polyurethane, have been considered to undergo UV radiation. Photochemical degradation of the polyurethanes has been monitore…

Polymer composites and self-healingBuilding materials and conservationPhotopolymerization techniques and applications

Assessment of Soil Potassium Sufficiency as Related to Quantity‐Intensity in Montmorillonitic Soils

Frank V. Schindler、Howard J. Woodard、James J. Doolittle2005-09-01Communications in Soil Science and Plant Analysis

No studies have been conducted to evaluate the potassium (K) quantity‐intensity (Q/I) relationships that exist in eastern South Dakota soils and how that may affect K fertility interpretations. The objectives of this study were to i) evaluate the K status of smectite‐dominant soils through quantity‐intensity relations…

Analytical Chemistry and SensorsClay minerals and soil interactionsIron oxide chemistry and applications

Phase properties and interaction force of acoustically interacting bubbles: A complementary study of the transition frequency

Masato Ida2005-09-01Physics of Fluids

The transition frequencies of multibubble systems in a sound field are reexamined to confirm their existence and further clarify their physical properties. We have recently suggested that a gas bubble interacting with a neighboring bubble in a sound field has up to three transition frequencies which invert the pulsati…

Fluid Dynamics and MixingUltrasound and Cavitation PhenomenaNuclear Physics and Applications

Voltage-Tunable Dielectric Properties of Pyrochlore Bi–Zn–Nb–Ti–O Solid-Solution Thin Films

Jin Young Kim、Dong‐Wan Kim、Hyun Suk Jung 等 4 位作者2005-09-01Japanese Journal of Applied Physics

The structural and dielectric properties of Bi 2 Ti 2 O 7 –Zn 2 Nb 2 O 7 solid-solution thin films were investigated using (Bi 2- x Zn x )(Nb x Ti 2- x )O 7 (BZNT, 0.05≤ x ≤1.0) pyrochlore thin films prepared on platinized Si substrates by metalorganic decomposition (MOD) process. Thermal analysis and X-ray diffractio…

Ferroelectric and Piezoelectric MaterialsInfectious Diseases and TuberculosisNuclear materials and radiation effects

Switching of chirality from racemic to homochiral state in new liquid crystalline monomers with bent‐core molecules

Vladimı́ra Novotná、Věra Hamplová、Miroslav Kašpar 等 5 位作者2005-09-01Liquid Crystals

The synthesis and physical properties of bent‐shaped molecules with ester linkages and methoxy substitution on a non‐central ring are presented. Terminal chains of most mesogens contain a group with double bond, which promotes polymerization. In all the compounds studied a B2 phase just below the isotropic phase has b…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsMolecular spectroscopy and chirality

Syntheses of boronic-acid-appended metalloporphyrins as potential colorimetric sensors for sugars and carbohydrates

Chen Zhang、Kenneth S. Suslick2005-09-01Journal of Porphyrins and Phthalocyanines

Boronic-acid-based dyes have been widely studied in the past decade as potential sensors for sugars and carbohydrates, owing to the strong interaction of boronic acid and diols. In this work, two boronic-acid-appended metalloporphyrins were synthesized by new routes and tested as potential sugar and carbohydrate senso…

Electrochemical sensors and biosensorsMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry

Three extant species ofParalia(Bacillariophyceae) along the coast of Japan

Yuki Sawai、Tamotsu Nagumo、Kensuke Toyoda2005-09-01Phycologia

Abstract Three extant species of the genus Paralia (Bacillariophyceae) occur along the coast of Japan, two of them are new species. Observations of living populations suggested that significant characters for separating Paralia species are (1) structure of the mantle of the separation valve; (2) shape of the linking s…

Marine and coastal ecosystemsAdvanced biosensing and bioanalysis techniquesDiatoms and Algae Research

Phase transformation analysis in titanium at nanosecond time resolution

Harald Kleinschmidt、Alexander Ziegler、G. H. Campbell 等 5 位作者2005-09-01Journal of Applied Physics

Polycrystalline and mosaic bicrystalline titanium films were subjected to steep heating/cooling rate of 1011∕108Ks−1 by laser pulsing. The induced phase transformations were followed by imaging and diffraction with a dynamic transmission electron microscope on the time scale of nanoseconds. On heating the film up to n…

Metal and Thin Film MechanicsAdditive Manufacturing Materials and ProcessesTitanium Alloys Microstructure and Properties

Effect of interface strength on electromigration-induced inlaid copper interconnect degradation: Experiment and simulation

Ehrenfried Zschech、H. Engelmann、Moritz Andreas Meyer 等 10 位作者2005-09-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract Both in situ microscopy experiments at embedded inlaid copper interconnect structures and numerical simulations based on a physical model provide information about electromigration-induced degradation mechanisms in on-chip interconnects. It is shown that the modification of the bonding strength of the weakest…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

Radiation-induced bond switching in mixed Ge–As sulphide glasses

R. Golovchak、O. Shpotyuk2005-09-01The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

A mechanism for γ-ray-induced changes in the optical properties of ternary Ge–As sulphide glasses is analysed at the microstructural level. It is shown, using IR FFT spectroscopy, that these changes are associated with chemical bond switching accompanied by coordination topological defect formation.

Glass properties and applicationsPhase-change materials and chalcogenidesMineralogy and Gemology Studies

Strong Excitonic Emission from (001)-Oriented Diamond P–N Junction

Toshiharu Makino、Hiromitsu Kato、Masahiko Ogura 等 7 位作者2005-09-01Japanese Journal of Applied Physics

We have succeeded in fabricating (001)-oriented diamond p – n junctions with good diode characteristics and realized UV light emission by current-injection at room temperature. As p – n junctions, a phosphorus-doped n -type layer was formed on (001)-oriented boron-doped p -type one by applying an optimized homoepitaxi…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Quantum Chemical Study of Three Polymorphs of the Mononuclear Spin-Transition Complex [Fe(DPPA)(NCS)2]

Samir Zein、G.S. Matouzenko、Serguei A. Borshch2005-09-01The Journal of Physical Chemistry A

The calculations of the high spin (HS) and low spin (LS) states of the [Fe(II)(DPPA)(NCS)(2)] complex have been performed at three experimentally observed geometries corresponding to three synthesized polymorphs with different spin-transition behavior. The structure optimization leads to a single molecular structure,…

Advanced Chemical Physics StudiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Effects of Ag Addition on the Resistivity, Texture and Surface Morphology of Cu Metallization

Bin Zhao、Hoon Kim、Yukihiro Shimogaki2005-09-01Japanese Journal of Applied Physics

Doping Cu with some elements has been proved to be a promising method to improve the reliability of Cu interconnects. In this paper, Ag was chosen as the alloying element because of its low bulk resistivity and low solubility in Cu. Cu–Ag alloy film was prepared by layered evaporation and postdeposition annealing in v…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

Estudo termoanalítico de comprimidos revestidos contendo captopril através de termogravimetria (TG) e calorimetria exploratória diferencial (DSC)

Giovana Carolina Bazzo、Marcos Antônio Segatto Silva2005-09-01Revista Brasileira De Ciencias Farmaceuticas

No presente trabalho foram desenvolvidos comprimidos de captopril revestidos com hidroxipropilmetilcelulose (HPMC), Opadry®, polivinilpirrolidona (PVP), Eudragit® E e goma laca. Foi realizado estudo termoanalítico do fármaco e das formulações através de termogravimetria (TG) e calorimetria exploratória diferencial (DS…

biodegradable polymer synthesis and propertiesThermal and Kinetic AnalysisPolymer Science and PVC

Enhanced Small-Molecule Assembly through Directional Intramolecular Forces

Andrew J. Lampkins、Osama Abdul-Rahim、Hengfeng Li 等 4 位作者2005-09-01Organic Letters

[reaction: see text] Directional intramolecular interactions play a critical role in the self-assembly of donor-sigma-acceptor molecules in solution. Amide functions on the periphery of the tricyclic core stabilize a C3-symmetric monomer conformation by intramolecular hydrogen bonding and dipole-dipole interactions. T…

Lipid Membrane Structure and BehaviorChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials

Study of Optical Property in ZnO Thin Film Implanted with Eu by Combinatorial Ion Implantation Techniques

Isao Sakaguchi、Yoshiyuki Satô、Haruki Ryoken 等 6 位作者2005-09-01Japanese Journal of Applied Physics

Combinatorial ion implantation techniques with mask and digital scanning systems were applied to optimize conditions of the optimal Eu dose for the orange luminescence originating from Eu phosphor in ZnO thin films. Eu ions accelerated to 150 keV were implanted continuously in the range of 1×10 16 to 2×10 17 ions/cm 2…

ZnO doping and propertiesLuminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and Sensors

Structural and optical properties of WO3 electrochromic layers prepared by the sol-gel method

Abdoljavad Novinrooz、Masoomeh Sharbatdaran、Hassan Noorkojouri2005-09-01Open Physics

Abstract Thin layers of tungsten trioxide have been prepared from an aqueous solution of peroxotungstic acid (PTA) using the sol-gel method. Compositional, structural and optical characteristics of WO3 coated on indium tin oxide (ITO) conductive glass substrates were studied using X-ray diffractometery (XRD), cyclic v…

Gas Sensing Nanomaterials and SensorsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

A STUDY OF THE DEGREE OF BREAKAGE OF GLASS FILAMENT YARNS DURING THE WEFT KNITTING PROCESS

Hong Hu、Mei Fang Zhu2005-09-01Autex Research Journal

Abstract In this paper, the degree of breakage of glass filament yarns during the weft knitting process is studied. A quantitative method used for assessing the degree of glass filament breakage is proposed, and the effects of different factors such as cam setting, knitted structures and yarn parameters are analysed.…

3D Shape Modeling and AnalysisDyeing and Modifying Textile FibersTextile materials and evaluations

New non‐synthetic method to modify properties of liquid crystals using micro‐ and nano‐particles

Oleksandr Buchnev、Chae Il Cheon、Anatoliy Glushchenko 等 5 位作者2005-09-01Journal of the Society for Information Display

Abstract— The modification of the properties of existing LCs by doping them with ferroelectric micro‐ and nano‐particles will be reported. This approach, in contrast to the conventional time‐consuming and expensive chemical synthetic methods, enriches and enhances the electro‐optical performance of many liquid‐crystal…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Graft Copolymerization of Methyl Methacrylate onto Chitosan Initiated by Potassium Ditelluratocuprate(III)

Yinghai Liu、Yanxiang Li、Juan Lv 等 5 位作者2005-09-01Journal of Macromolecular Science Part A

A novel redox system, potassium ditelluratocuprate(III) (DTC)–chitosan, was employed to initiate the graft copolymerization of methyl methacrylate (MMA) onto chitosan in alkali medium. The effects of reaction variables, such as the initiator concentration, ratio of monomer to chitosan, the pH value, as well as reactio…

Advanced Polymer Synthesis and CharacterizationConducting polymers and applicationsbiodegradable polymer synthesis and properties