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Femtosecond Spectroscopic Investigation of the Carrier Lifetimes in Digenite Quantum Dots and Discrimination of the Electron and Hole Dynamics via Ultrafast Interfacial Electron Transfer

Yongbing Lou、Xiaobo Chen、Anna Cristina S. Samia 等 4 位作者2003-10-18The Journal of Physical Chemistry B

For the Cu x S system there exists several known solid phases such as Cu 2 S (chalcocite), Cu 1.8 S (digenite), Cu 1.96 S (djurleite), and CuS (covellite). All of these phases have been identified as p-type semiconducting materials due to copper vacancies within the lattice, which is responsible for their usefulness a…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

One-Step Water-Assisted Synthesis of High-Quality Carbon Nanotubes Directly from Graphite

Zhenhui Kang、Enbo Wang、Lei Gao 等 7 位作者2003-10-18Journal of the American Chemical Society

At 1 atm pressure, high-quality multiwall carbon nanotubes were synthesized directly from graphite in the absence of catalyst by a one-step water-assisted method.

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Effects of Yam Starch Films on Storability and Quality of Fresh Strawberries (Fragaria ananassa)

Suzana Mali、Maria Victória Eiras Grossmann2003-10-18Journal of Agricultural and Food Chemistry

Yam starch films, formulated with yam starch (4.00 g/100 g of solution) and glycerol (1.30 and 2.00 g/100 g of solution) in filmogenic solution, were employed as packaging to extend storage life of strawberries stored at 4 degrees C and 85% RH. The effects of yam starch films on fruits were compared to the effect of P…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingPlant Physiology and Cultivation Studies

Experimental study of weak antilocalization effect in a high mobility InGaAs/InP quantum well

S. A. Studenikin、P. T. Coleridge、N. Ahmed 等 5 位作者2003-10-18arXiv

The magnetoresistance associated with quantum interference corrections in a high mobility, gated InGaAs/InP quantum well structure is studied as a function of temperature, gate voltage, and angle of the tilted magnetic field. Particular attention is paid to the experimental extraction of phase-breaking and spin-orbit…

Mesoscale and Nanoscale PhysicsMaterials Science

Fucoxanthin-Chlorophyll Proteins in Diatoms: 18 and 19 kDa Subunits Assemble into Different Oligomeric States

Claudia Büchel2003-10-18Biochemistry

Fucoxanthin-chlorophyll proteins were purified from the centric diatom Cyclotella meneghiniana. Two major fractions were observed that differed in their polypeptide composition and oligomeric state. Trimers consist of mainly 18 kDa polypeptides. Higher oligomers are tightly assembled from different trimers, which cont…

Marine and coastal ecosystemsProtist diversity and phylogenyDiatoms and Algae Research

“Pulling” Nanoparticles into Water: Phase Transfer of Oleic Acid Stabilized Monodisperse Nanoparticles into Aqueous Solutions of α-Cyclodextrin

Yong Wang、Jian Feng Wong、Xiaowei Teng 等 5 位作者2003-10-18OpenAlex

This paper describes a general method to drastically improve the dispersity of oleic acid stabilized nanoparticles in aqueous solutions. We use oleic acid stabilized monodisperse nanoparticles of iron oxides and silver as model systems, and have modified the surface properties of these nanoparticles through the format…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsSurfactants and Colloidal Systems

Supramolecular Hydrogels Respond to Ligand−Receptor Interaction

Yan Zhang、Hongwei Gu、Zhimou Yang 等 4 位作者2003-10-18OpenAlex

N-(Fluorenyl-9-Methoxycarbonyl) dipeptides form supramolecular hydrogels via hydrogen bonding and hydrophobic interactions. These hydrogels respond to a ligand-receptor interaction as well as to thermal or pH perturbation and also exhibit chiral recognition.

Supramolecular Chemistry and ComplexesLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Tunneling in a single-molecule magnet via anisotropic exchange interactions

Gwang-Hee Kim2003-10-17Physical review. B, Condensed matter

The model describing two coupled single-molecule magnets is considered by including anisotropic exchange interaction in the spin Hamiltonian. The tunnel splittings are calculated perturbationally for arbitrary spin in several selected cases and estimated numerically by using a ${\mathrm{Mn}}_{4}$-dbm as a model system…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Modelling by percolation theory of the behaviour of natural coral used as bone substitute

Y. Barbotteau、J.L. Irigaray、J.-F. Mathiot2003-10-17Physics in Medicine and Biology

We investigate the relevance of site-bond percolation theory to model the resorption and ossification of natural coral implanted in bones. The first step of the process is the vascularization of the implant seen here as a percolation threshold. The resorption and ossification can thus take place by activation of unocc…

Polymer Surface Interaction StudiesIchthyology and Marine BiologyUnderwater Acoustics Research

Annealing effects on optical properties of natural alexandrite

Rosa Maria Fernandes Scalvi、Máximo Siu Li、Luis V. A. Scalvi2003-10-17Journal of Physics Condensed Matter

Natural alexandrite (BeAl 2 O 4 :Cr 3+ ) crystals are investigated as regards the effects of annealing on their optical properties. Optical absorption spectra are measured from the ultraviolet (190 nm) to the near infrared (900 nm), for a sample subjected to consecutive annealing processes, where time and temperature…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMineralogy and Gemology Studies

The Electronic Structure of the Photoexcited Triplet State of Free-Base (Tetraphenyl)porphyrin by Time-Resolved Electron−Nuclear Double Resonance and Density Functional Theory

Christopher W. M. Kay2003-10-17Journal of the American Chemical Society

The photoexcited triplet states of free-base porphyrin (H(2)P) and free-base tetraphenylporphyrin (H(2)TPP) have been investigated by time-resolved electron paramagnetic resonance and electron-nuclear double resonance in a toluene glass at 80 K. Both the zero-field splitting parameters, D and E, and the proton A(zz) h…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Multicomponent Interposed Carbon Nanotube Micropatterns by Region-Specific Contact Transfer and Self-Assembling

Junbing Yang、Liming Dai、Richard A. Vaia2003-10-17The Journal of Physical Chemistry B

In our further investigation on the microfabrication of carbon nanotubes, we found that micropatterns of perpendicular ly a ligned carbon nanotubes can be prepared by simply pressing an adhesively sticky tape (e.g., Scotch tape) prepatterned with a nonadhesive layer onto a nonpatterned aligned carbon nanotube film, fo…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsAdvanced Materials and Mechanics

Surface and Bulk Elasticity Determined Fluctuation Regimes in Smectic Membranes

Irakli Sikharulidze、B. Farago、Igor P. Dolbnya 等 5 位作者2003-10-17Physical Review Letters

We report combined x-ray photon correlation spectroscopy (XPCS) and neutron spin echo (NSE) measurements of the layer-displacement fluctuations in smectic liquid-crystal membranes in the range from 10 ns to 10 micros. NSE reveals a new regime, determined by bulk elasticity, in which relaxation times decrease with the…

Liquid Crystal Research AdvancementsSpectroscopy and Quantum Chemical StudiesRandom lasers and scattering media

Reconfigurable hydrophobic/hydrophilic surfaces in microelectromechanical systems (MEMS)

Joanne Deval、Teodoro A. Umali、Esther H. Lan 等 5 位作者2003-10-17Journal of Micromechanics and Microengineering

Fully reconfigurable hydrophobic–hydrophilic surfaces were achieved by reversibly adsorbing and removing avidin from a hydrophobic self-assembled monolayer. The adsorption process was characterized using surface plasmon resonance, while contact angle measurements were used to monitor the resulting wetting behavior. Th…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrowetting and Microfluidic Technologies

Brownian dynamics simulations of glycolytic enzyme subsets with F‐actin

Stephen L. Lowe、Charlotte L. Adrian、I. V. Uporov 等 5 位作者2003-10-17Biopolymers

Previous Brownian dynamics (BD) simulations identified specific basic residues on fructose-1,6-bisphophate aldolase (aldolase) (I. V. Ouporov et al., Biophysical Journal, 1999, Vol. 76, pp. 17-27) and glyceraldehyde-3-phosphate dehydrogenase (GAPDH) (I. V. Ouporov et al., Journal of Molecular Recognition, 2001, Vol. 1…

Protein Structure and DynamicsAdvanced Proteomics Techniques and ApplicationsEnzyme Structure and Function

Nanoparticle-enhanced thermoluminescence in silica gels

D. Mendoza-Anaya、C. Ángeles、P. Salas 等 5 位作者2003-10-17Nanotechnology

The results of transmission electron microscopy and thermoluminescence (TL) studies in silica samples containing Fe and Cu nanosized particles show an important enhancement of their TL response when compared with known reports for pure silica samples. The effect of surface electronic states in the nanoparticles, inter…

Luminescence Properties of Advanced MaterialsCatalytic Processes in Materials ScienceQuantum Dots Synthesis And Properties

Surface Modification Chemistry Based on the Electrostatic Adsorption of Poly-l-arginine onto Alkanethiol Modified Gold Surfaces

Sérgio V. P. Barreira、Fernando Silva2003-10-17Langmuir

The reaction between the arginine's guanidino group and α-dicarbonyl functionalities was used to develop a novel surface modification chemistry. The first modification step consists of the electrostatic adsorption of a poly- l -arginine layer onto ionizable alkanethiol modified gold surfaces. The strongly basic charac…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresNanofabrication and Lithography Techniques

Impressive Structural Diversity and Polymorphism in the Modular Compounds ABi3Q5 (A = Rb, Cs; Q = S, Se, Te)

Lykourgos Iordanidis、Daniel Bilc、S. D. Mahanti 等 4 位作者2003-10-17Journal of the American Chemical Society

An outstanding example of structural diversity and complexity is found in the compounds with the general formula ABi(3)Q(5) (A = alkali metal; Q = chalcogen). gamma-RbBi(3)S(5) (I), alpha-RbBi(3)Se(5) (II), beta-RbBi(3)Se(5) (III), gamma-RbBi(3)Se(5) (IV), CsBi(3)Se(5) (V), RbBi(3)Se(4)Te (VI), and RbBi(3)Se(3)Te(2) (…

Crystal Structures and PropertiesIron-based superconductors researchInorganic Chemistry and Materials

Electron paramagnetic resonance investigation of polycrystalline CaCu3Ti4O12

Maria Cristina Mozzati、Carlo B. Azzoni、Doretta Capsoni 等 5 位作者2003-10-17Journal of Physics Condensed Matter

Electron paramagnetic resonance (EPR) measurements on pure polycrystalline CaCu 3 Ti 4 O 12 have been performed and are discussed within a crystal-field approach. A symmetric signal centred at g = 2.15 is observed for T >25 K, with no evidence of hyperfine structure. At this temperature an antiferromagnetic transition…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Synthesis and Characterization of Bis(S-acetylthio)-Derivatized Europium Triple-Decker Monomers and Oligomers

Karl‐Heinz Schweikart、Vladimir L. Malinovskii、Amir A. Yasseri 等 7 位作者2003-10-17Inorganic Chemistry

We report the synthesis of monomers, dimers, trimers, and oligomers of triple-decker (TD) complexes bearing S-acetylthio groups at the termini: AcS-(TD)(n)()-SAc. Each TD was of type (Pc)Eu(Pc)Eu(Por), where H(2)Pc = tetra-tert-butylphthalocyanine and H(2)Por is a meso-tetraarylporphyrin bearing functional groups at t…

Porphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal ComplexesSynthetic Organic Chemistry Methods