Materials Literature
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We report the shape and size control of polyhedral gold nanocrystals by a modified polyol process. The rapid reduction of gold precursors in refluxing 1,5-pentanediol has successfully provided a series of gold nanocrystals in the shape of octahedra, truncated octahedra, cuboctahedra, cubes, and higher polygons by incr…
Abstract IR‐to‐visible up‐conversion fluorescent nanocrystals of hexagonal‐phase NaYF 4 :20 %Yb,2 %Er and NaYF 4 :20 %Yb,2 %Tm have been synthesized by decomposition of multiprecursors of CF 3 COONa, (CF 3 COO) 3 Y, (CF 3 COO) 3 Yb, and (CF 3 COO) 3 Er/(CF 3 COO) 3 Tm in oleylamine at 330 °C. The average particle size…
Abstract The ability to pattern materials in three dimensions is critical for several technological applications, including composites, microfluidics, photonics, and tissue engineering. Direct‐write assembly allows one to design and rapidly fabricate materials in complex 3D shapes without the need for expensive toolin…
Abstract Polyurethane (PU) with lactate structures in its conformation can be used as a biological and biodegradable polymer. Polyurethane lactate (PUL) was doped with small quantities of an erbium (Er 3+ ) complex, which hindered the NN group. 2,2′‐Dihydroxyazobenzene was used as a ligand for the Er 3+ complex. PUL…
We present a new wave separation method to enable the split Hopkinson pressure bar (SHPB) technique to break through the limitation of the length of the incident bar and greatly to increase its measurable maximum strain. At the same time the dispersion effect of the elastic wave is significantly reduced. The fundament…
Boron-doped amorphous graphite-like carbon (GLC) films have been prepared with different boron concentrations. Electrical transport measurements in the temperature range 1.3–300 K on the films shows a doping-induced metal–insulator (MI) transition. On the metallic side of the transition, the experimental data are inte…
Comparison of the collision cross-section of the [Fe(III)-protoporphyrin IX]+ ion, hemin+, measured by means of ion-mobility experiments and the cross-sections calculated from theoretical structures based on density functional theory reveals that hemin+, in the gas phase, contains intramolecular hydrogen bonding betwe…
First-principles density functional studies of the dynamical properties of the conjugated polymers polyaniline and poly($p$-pyridyl vinyline) are presented in this work. We have employed linear response within density functional perturbation theory, as implemented in the CASTEP code, to investigate the Born effective…
Abstract The kinetics of the thermal degradation of polyurethane (PU) elastomers based on poly(ether polyol) soft segments and an aromatic type of diisocyanate were investigated by thermogravimetric analysis (TGA) under a nitrogen atmosphere employing four heating rates. The corresponding kinetic parameters of the two…
Extraordinary effects of the hydrostatic pressure on the crystallographic and magnetic properties of the ${\mathrm{Er}}_{5}{\mathrm{Si}}_{4}$ alloy have been examined by means of macroscopic (magnetization and linear thermal expansion) and microscopic (neutron powder diffraction) techniques. The high-temperature $O(\m…
Abstract Core–shell poly(butadiene‐ graft ‐styrene) (PB‐ g ‐PS) rubber particles were synthesized with different initiation systems by emulsion grafting polymerization. These initiation systems included the redox initiators and an oil‐soluble initiator, 1,2‐azobisisobutyronitrile (AIBN). Then the PB‐ g ‐PS impact modi…
Abstract A miscible blend of 85.5 wt % atactic polystyrene and 9.5 wt % poly(phenylene ether) containing 5.0 wt % expanded graphite nanoparticles was melt‐spun and stretched up to 25 times. The structure and electrical and mechanical properties of the fibers were investigated. Characterized by a Hermans orientation fa…
Abstract Porous poly(2‐hydroxyethyl methacrylate‐methyl methacrylate) particles crosslinked with ethylene glycol dimethacrylate were synthesized by free‐radical suspension copolymerization in an aqueous phase initiated by an oil‐soluble initiator, 2,2‐azobisisobutyronitrile. 1‐octanol was used as a pore forming agent…
The universality of the frequency-dependent (AC) conduction of many disordered solids in the extreme-disorder limit has been demonstrated experimentally. Theoretically, this universality has been established with different techniques and for various models. A popular model that has been extensively investigated and fo…
Volume 2 presents the fundamental principles related to polymer processign operations including the processing of thermoplastic polymers and thermosets. The objective of this volume is not to provide recipies that necessarily guarantee better product quality. Rather, emphasis is placed on presenting a fundamental appr…
Copper-rich precipitates can nucleate and grow in ferritic steels containing small amounts of copper in solution and this affects mechanical properties. Growth kinetics, composition and structure of precipitates under irradiation are different from those under thermal ageing, and also vary with type of radiation. This…
By controlling the morphology of holographic polymer-dispersed ferroelectric liquid crystals (FLCs), highly aligned FLC domains are obtained for diffractive optical applications. Rapid, thresholdless switching is observed for various grating pitch sizes between approximately 3 and approximately 12 microm. A simple phe…
Density functional theory (DFT) in connection with ultrasoft pseudopotential (USP) and generalized gradient spin-polarized approximations (GGSA) is applied to calculate the adsorption energies and structures of monolayer-adsorbed InN on the TiO(2) anatase (101) surface and the corresponding electronic properties, that…
The near-field coupling interactions between surface plasmon modes of neighboring metal nanoparticles (NPs) are investigated in thin films of oligothiophene-linked Au NPs. The oligothiophene linker facilitates near-field coupling between adjacent NPs, and disruption of the conjugation in the oligothiophene by chemical…
Abstract Ethylene propylene diene terpolymer (EPDM)/MgAl layered double hydroxide (LDH) nanocomposites have been synthesized by solution intercalation using organically modified LDH (DS-LDH). The molecular level dispersion of LDH nanolayers has been verified by the disappearance of basal XRD peak of DS-LDH in the comp…