Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthetic Principles for Bandgap Control in Linear π-Conjugated SystemsJean RoncaliView Author Information Ingénierie Moléculaire et Matériaux Organiques, CNRS UMR 6501, Université d'Angers, 49045 Angers, France Cite this: Chem. Rev. 1997, 97, 1, 173–206Publication Date (Web…
Data on the physical properties of diamond as a solid state electronics material are briefly discussed with particular emphasis placed on synthetic crystals and plasma-precipitated films.
Pellets of poly(ethylene terephthalate) (PET; 0.48–1.92 g) were heated in anhydrous ethylene glycol (EG; 5 mL) with 2-equivs of NaOH at 150°C for 80 min or 180°C for 15 min to convert them quantitatively to disodium terephthalate (Na2-TPA) and EG. The disodium salt was precipitated quantitatively in pure state from th…
The uncatalyzed edge growth of carbon nanotubes was investigated by first-principles molecular dynamics simulations. At experimental temperatures the open end of single-walled nanotubes closed spontaneously into a graphitic dome, which may explain why these nanotubes do not grow in the absence of transition metal cata…
First-principles full potential linearized augmented plane wave (FLAPW) calculations have been performed for lattice-mismatched common-atom III-V interfaces. In particular, we have examined the effects of epitaxial strain and ordering direction on the valence band offset in [001] and [111] GaSb/InSb and InAs/InSb supe…
The modelling analysis herein and corresponding VLEED calculations suggest that the formation of the O -1 and the hybridised- O -1 effects in nature the c(2×2)-O and subsequently the [Formula: see text] phase on the O-Cu(001) surface.
Three series of aromatic, thermotropic copolyesters, based on terephthalic acid (TA), ethylene glycol (EG), and another diol were prepared. The third monomer was selected from three different hydroquinones including, ethoxyhydroquinone (EHQ), phenylhydroquinone (PHQ), and hydroquinone itself (HQ). The amounts of the d…
The experimentally estimated ‘normalized’ rate constants of the bulk crystallization of poly(L-lactic acid) and natural rubber at different temperatures have been used in order to test different equations describing the temperature dependence of the normalized crystallization rate constants. Ten of these expressions a…
The epoxy resin containing a typical mesogenic group such as biphenol was cured with catechol novolak and aromatic diamines which have neighboring active hydrogens. In the biphenol-type epoxy resin cured with catechol novolak, 4,4′ diaminodiphenylmethane, and p-phenylenediamine (PPD), the glass-rubber transition almos…
Crosslinkable alkyl-substituted poly(aryl ether ketone)s (PEKs) bearing a styryl group at both chain ends were synthesized by nucleophilic substitution reaction of 1,1′-(p-phenyl-enedioxy)bis[2-methyl-4-(4-fluorobenzoyl)benzene] with an excess aromatic diol in the presence of a base, followed by the reaction of the te…
Nominal stress-strain curves of a series of random ethylene-hexene copolymers having narrow composition and most probable molecular weight distributions were investigated. A series of such molecular weight copolymers with a constant concentration of branches were crystallized under a variety of conditions. In each mol…
The reaction mechanisms of thermal crosslinking of polyethylene with dicumyl peroxide (DCP) at high temperatures were investigated by electron spin resonance (ESR). The crosslinking reactions were induced by the alkyl radicals formed by the thermal decomposition of DCP above 120°C. The kinetics of the free radical rea…
Since poly(lactic acid) is the biodegradable polyester having low immunogenicity and good biocompatibility, it is utilized as a medical material. However, poly(lactic acid) is a water-insoluble crystalline polymer having no reactive side-chain group. Thus, the use of poly(lactic acid) is limited. To modify the propert…
The morphological stability of polystyrene high-density polyethylene (PS/PE) blend is investigated in the region of dual-phase continuity. The effect of the addition of a triblock SEBS copolymer to the blends on the stability of these morphologies, is examined. The results show that the morphology of the unmodified bl…
AB block copolymers of ϵ-caprolactone and (L)-lactide could be prepared by ring-opening polymerization in the melt at 110°C using stannous octoate as a catalyst and ethanol as an initiator provided ϵ-caprolactone was polymerized first. Ethanol initiated the polymerization of ϵ-caprolactone producing a polymer with ϵ-c…
Empirical force field parameters for nicotinamide (NIC+) and 1,4-dihydronicotinamide (NICH) were developed for use in modeling of the coenzymes nicotinamide adenine dinucleotide (NAD+) and NAD hydride (NADH). The parametrization follows the methodology used in the development of the CHARMM22 all-hydrogen parameters fo…
The structural and electronic properties in common anion (GaSb)_1/(InSb)_1 and common cation (InAs)_1/(InSb)_1 [111] ordered superlattices have been determined using the local density total energy full potential linearized augmented plane wave method. The influence of the ordering direction, strain conditions and atom…
A preceding article referred to the processing of various grades of isotactic polypropylene (iPP) and propylene/ethylene copolymers by conventional and shear-controlled orientation injection molding (SCORIM), and considered the mechanical properties of the molded polymers in relation to the processing conditions appli…
1. Separation Properties 2. Industrial Applications 3. Trends in Polyimide Membrane Development 4. Relationship Between Structure and Polyimide Properties 5. Preparation Techniques 6. Conversion of Polyamic Acids into Polyimides
The first edition of this book was widely praised as an excellent introduction to electron microscopy for materials scientists, physicists, earth and biological scientists. This completely revised new edition contains expanded coverage of existing topics and much new material. The author presents the subject of electr…