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Effect of crystal structure on magnetic-field-induced strain in Ni-Mn-Ga

A. Sozinov、Alexander A. Likhachev、Nataliya Lanska 等 6 位作者2003-08-12Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Magnetic shape memory materials are expected to have a high potential in practical applications. Several ferromagnetic materials exhibiting the large magnetic-field-induced strain have been found in recent years. The largest field-induced strain is observed in Ni-Mn-Ga system. The most important experimental results o…

Shape Memory Alloy TransformationsMagnetic Properties and Applications

Poly(dimethylsiloxane) coatings for controlled drug release. I. Preparation and characterization of pharmaceutically acceptable materials

Zongming Gao、Julia Schulze Nahrup、James E. Mark 等 4 位作者2003-08-12Journal of Applied Polymer Science

Abstract The basic technology for forming crosslinked elastomers by the end linking of low molecular weight hydroxyl‐terminated poly(dimethylsiloxane) (PDMS) with tetraethoxysilane (TEOS) was modified to make it suitable for preparing coatings for controlled drug release. The requirements for this application included…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry

Glass transition of hard sphere systems: Molecular dynamics and density functional theory

Kang Kim、Toyonori Munakata2003-08-12Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The glass transition of a hard sphere system is investigated within the framework of the density functional theory (DFT). Molecular dynamics (MD) simulations are performed to study the dynamical behavior of the system on the one hand and to provide the data to produce the density field for the DFT on the other hand. E…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Fatigue life characterization of shape memory alloys undergoing thermomechanical cyclic loading

Olivier W. Bertacchini、Dimitris C. Lagoudas、Étienne Patoor2003-08-12Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

This paper presents a study on the fatigue life of shape memory alloy actuators undergoing thermally induced martensitic phase transformation under various stress levels. A microstructural study characterizing specific damage patterns is conducted in the current work. A highly stressed state with formation of differen…

Shape Memory Alloy TransformationsTopology Optimization in EngineeringTitanium Alloys Microstructure and Properties

Changes in dynamic crossover with temperature and pressure in glass-forming diethyl phthalate

Sebastian Pawlus、Marian Paluch、M. Sekuła 等 6 位作者2003-08-12Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Dielectric relaxation measurements have been used to study the crossover in dynamics with temperature and pressure, onset of breakdown of the Debye-Stokes-Einstein law, and the relation between the \ensuremath{\alpha} and the \ensuremath{\beta} relaxations in diethyl phthalate. The measurements made over 10 decades in…

Material Dynamics and PropertiesIonic liquids properties and applicationsThermodynamic properties of mixtures

Thermogravimetric analysis of blends of low‐density polyethylene and poly(dimethyl siloxane) rubber: The effects of compatibilizers

R. N. Jana、Golok B. Nando2003-08-12Journal of Applied Polymer Science

Abstract The thermal stability of vulcanizates of low‐density polyethylene (LDPE), poly(dimethyl siloxane) (PDMS) rubber, and their blends was studied by nonisothermal thermogravimetry. Four ethylene copolymers [ethylene methyl acrylate (EMA), ethylene vinyl acetate, ethylene acrylic acid, and a zinc‐salt‐based ionome…

Polymer Nanocomposites and PropertiesThermal and Kinetic AnalysisPolymer Science and PVC

Temperature-Dependent Transition of Deformation Mode in Poly(1,4-cyclohexylenedimethylene terephthalate)/Poly(ethylene terephthalate) Copolymers

Sang‐Soo Lee、Albert F. Yee2003-08-12Macromolecules

The temperature-dependent deformation behavior of amorphous thin films of poly(1,4-cyclohexylenedimethylene terephthalate) (PCT), poly(ethylene terephthalate) (PET), and their copolymers was examined with variation of temperature and cyclohexylene linkage content by transmission electron microscopy. When subject to un…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Supertoughness and critical interparticle distance dependence in poly(butylene terephthalate) and poly(ethylene‐co‐glycidyl methacrylate) blends

Asier Aróstegui、J. Nazábal2003-08-12Journal of Polymer Science Part B Polymer Physics

Abstract Supertough poly(butylene terephthalate) (PBT)‐based blends were obtained by the melt blending of PBT with 0–30 wt % poly(ethylene‐ co ‐glycidyl methacrylate) (EGMA). The reaction between PBT and EGMA was detected by torque measurements. The particle size was almost constant with increasing EGMA content, and t…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Synthesis and Characterization of Superparamagnetic Ni−Pt Nanoalloy

Madhuri Mandal、Subrata Kundu、Tapan K. Sau 等 5 位作者2003-08-12Chemistry of Materials

A room-temperature wet chemical method of synthesis for sphere- and rod-shaped magnetic “solid solution” type Ni−Pt nanoparticles in cetyltrimethylammonium bromide (CTAB) micelle is reported. The particles have been found to be moderately monodispersed without adopting any further size-selection procedure. The composi…

Magnetic properties of thin filmsGold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And Properties

Complementary C3-Symmetric Donor−Acceptor Components: Cocrystal Structure and Control of Mesophase Stability

Lee Y. Park、Darren G. Hamilton、Edward A. McGehee 等 4 位作者2003-08-12Journal of the American Chemical Society

The overlap of pi-complementary planar organic frameworks is used to direct the assembly of extended columns of alternating donor and acceptor units. The electron-rich partner, hexaalkoxytriphenylene, is a familiar mesogen, while the electron-accepting complement is mellitic triimide, a new C(3)-symmetric building blo…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

UV Photostability of Metal Phthalocyanines in Organic Solvents

Rudolf Słota、Gabriela Dyrda2003-08-12Inorganic Chemistry

Kinetic studies of photochemical reactions induced by UV radiation in solutions of metal phthalocyanines have been carried out to determine the factors which might have influenced the stability of photosensitized phthalocyanines. Complexes of the molecular type Mpc, M'(2)pc, and Lnpc(2) (where M = Li, Mg, Fe, Co, Zn,…

TiO2 Photocatalysis and Solar CellsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

A Three-Dimensional Manganese(II) Complex Exhibiting Ferrimagnetic and Metamagnetic Behaviors

Ruihu Wang、En‐Qing Gao、Maochun Hong 等 8 位作者2003-08-12Inorganic Chemistry

A three-dimensional complex, [Mn(3)(4-aba)(6)](n) (1) (4-Haba = 4-aminobenzoic acid), consisting of manganese(II) chains and 4-aba bridging ligands, has been synthesized and characterized. Magnetic studies show that the compound behaves as a three-dimensional metamagnet built of homometallic ferrimagnetic chains. The…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Te-free, Sb-based phase-change materials for high-speed rewritable optical recording

L. van Pieterson、M. van Schijndel、J. C. N. Rijpers 等 4 位作者2003-08-12Applied Physics Letters

High-speed rewritable optical disks based on conventional (eutectic) Sb–Te phase-change materials have low archival life stability and high media noise. We propose Te-free, Sb-based phase-change materials for recording at linear velocities over 28 m/s. These materials combine good optical contrast, rapid crystallizati…

Liquid Crystal Research AdvancementsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Femtosecond study of the interplay between excitons, trions, and carriers in (Cd,Mn)Te quantum wells

P. Plochocka、P. Kossacki、W. Maslana 等 7 位作者2003-08-12arXiv

We present an absorption study of the neutral and positively charged exciton (trion) under the influence of a femtosecond, circularly polarized, resonant pump pulse. Three populations are involved: free holes, excitons, and trions, all exhibiting transient spin polarization. In particular, a polarization of the hole g…

Materials Science

A Graphitized-Carbon Monolithic Column

Chengdu Liang、Sheng Dai、Georges Guiochon2003-08-12Analytical Chemistry

The preparation of a novel carbon monolithic column for high performance liquid chromatography is described. A phenolic resin rod with embedded 10-microm silica beads was prepared by acid-catalyzed polymerization of a resorcinol/iron(III) complex and formaldehyde. This rod was carbonized and graphitized under inert at…

Microfluidic and Capillary Electrophoresis ApplicationsMesoporous Materials and CatalysisAnalytical Chemistry and Chromatography

First principles simulations of direct coexistence of solid and liquid aluminium

Dario Alfè2003-08-12arXiv

First principles calculations based on density functional theory, with generalised gradient corrections and ultrasoft pseudopotentials, have been used to simulate solid and liquid aluminium in direct coexistence at zero pressure. Simulations have been carried out on systems containing up to 1000 atoms for 15 ps. The p…

Materials Science

Reversible Tuning of Wetting Behavior of Polymer Surface with Responsive Polymer Brushes

Michail Motornov、Sergiy Minko、Klaus‐Jochen Eichhorn 等 6 位作者2003-08-12Langmuir

We develop the route to fabricate mixed brushlike layers on polyamide substrates (PA-6, PA-6I, PA-66) by the “grafting from” approach. The PA substrates were functionalized by NH 3 plasma. The azo initiator of radical polymerization was covalently bound to the functionalized PA surface. A two-step grafting procedure w…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

Circularly polarized electroluminescence in spin-LED structures

Z. G. Yu、W. H. Lau、M. E. Flatte'2003-08-12arXiv

We calculate circularly polarized luminescence emitted parallel (vertical emission) and perpendicular (edge emission) to the growth direction from a quantum well in a spin light-emitting diode (spin-LED) when either the holes or electrons are spin polarized. It is essential to account for the orbital coherence of the…

Mesoscale and Nanoscale PhysicsMaterials Science

Electromechanical Properties of Multi-Domain Ferroelectrics

Rajeev Ahluwalia、Turab Lookman、Avadh Saxena 等 4 位作者2003-08-12arXiv

We study theoretically the influence of the underlying domain microstructure on the electromechanical properties of ferroelectrics. Our calculations are based on a continuum approach that incorporates the long-range elastic and electrostatic interactions. The theory is used to simulate the piezoelectric properties of…

Materials Science

Imaging of the [Mn2+(3d5) + hole] complex in GaAs by Cross-sectional Scanning Tunneling Microscopy

A. M. Yakunin、A. Yu. Silov、P. M. Koenraad 等 6 位作者2003-08-12arXiv

We present results on the direct spatial mapping of the wave-function of a hole bound to a Mn acceptor in GaAs. To investigate individual Mn dopants at the atomic scale in both ionized and neutral configurations, we used a room temperature cross-sectional scanning tunneling microscope (X-STM). We found that in the neu…

Materials Science